GB738589A - Improved waxes and compositions containing them - Google Patents
Improved waxes and compositions containing themInfo
- Publication number
- GB738589A GB738589A GB20508/52A GB2050852A GB738589A GB 738589 A GB738589 A GB 738589A GB 20508/52 A GB20508/52 A GB 20508/52A GB 2050852 A GB2050852 A GB 2050852A GB 738589 A GB738589 A GB 738589A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicon
- alcohol
- organo
- wax
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
- C09G1/12—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin mixtures of wax and silicon-containing polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Polymers (AREA)
- Cosmetics (AREA)
Abstract
Wax compositions comprise a mixture of a wax and a polymeric hydrocarbon-substituted organo-silicon compound which contains aliphatic radicals having at least 14 carbon atoms, which may contain ether linkages and which are bound to silicon through an -O- or -OCO-bridge. The compounds may be hydrocarbon-substituted organo-silicon compounds, e.g. silicone derivatives, in which have been introduced the residues of higher fatty alcohols or higher fatty acids. The organo-silicon compounds may be prepared by heating a siloxane oil containing alkyl, aryl or aralkyl radicals, silicon-bonded hydrogen or alkoxy or acyloxy groups with a higher alcohol or a higher fatty acid. In examples, an alkyl-siloxane oil containing one SiH group for every two silicon atoms and a methyl-siloxane oil having every eleventh silicon atom bound to a hydrogen atom are heated at 150-250 DEG C. with cetyl alcohol, octadecyl alcohol or a polyethylene oxide containing hydroxyl groups. A catalyst or substance of alkaline or acid reaction may be present, e.g. a sodium alcoholate, zinc chloride or an ansolvo acid. In further examples, an alkyl-silicone oil containing the group -SiOC2H5 and another containing the group -SiOCOCH3 are reacted with cetyl alcohol or octadecyl alcohol. Other organo-silicon compounds may be used, such as silmethylenes or silphenylenes or polysilanes, containing residues of higher alcohols or higher acids.ALSO:Silanes containing the residues of aliphatic alcohols or acids having at least 14 carbon atoms may be prepared by reacting an alkoxysilane or a silane containing a silicon-bonded hydrogen atom with the appropriate alcohol or acid. In an example, cetyl alcohol is refluxed with trimethylbutoxysilane to interchange the butoxy and cetyloxy groups.ALSO:Wax compositions comprise a mixture of a wax and a monomeric or polymeric hydrocarbon-substituted organo-silicon compound which contains aliphatic radicals having at least 14 carbon atoms, which may contain ether linkages and which are bound to silicon through an -O- or -OCO-bridge. The compounds may be hydrocarbon-substituted organo-silicon compounds, e.g. silicone derivatives, in which have been introduced the residues of higher fatty alcohols or higher fatty acids. The waxes specified comprise paraffin wax, ceresin wax, carnauba, candellila, montan and brown wax. The organo-silicon compounds may be prepared by heating a siloxane oil containing alkyl, aryl or aralkyl radicals with a higher alcohol or a higher fatty acid. Hydrogen is evolved and SiH groups are converted into SiOR1 or SiOCOR1 groups, in which R1 represents the residue of the higher alcohol or higher acid. In examples, an alkyl-siloxane oil containing one SiH-group for every two silicon atoms and a methyl-siloxane oil having every eleventh silicon atom bound to a hydrogen atom are reacted with cetyl alcohol, octadecyl alcohol or a polyethylene oxide containing hydroxyl groups. A catalyst or substance of alkaline or acid reaction may be present, e.g. a sodium alcoholate, zinc chloride or an ansolvo acid. Temperatures of 150-250 DEG C. are exemplified. The organo-silicon compounds may also be prepared from silicones containing lower alkoxy groups by reetherification with higher alcohols, or from silicones containing lower acyloxy groups by reaction with higher fatty alcohols, or from alkoxy-silicones by reaction with higher fatty acids. In examples, an alkyl-silicone oil containing the group -SiOC2H5 and another containing the group p -SiOCOCH3 are reacted with cetyl alcohol or octadecyl alcohol. Other organo silicon compounds may be used, such as silmethylenes or silphenylenes or polysilanes, containing residues of higher alcohols or higher acids. The wax compositions may also contain modifying additions such as resins, fatty oils, fatty acids or emulsifying agents. The compositions may be used alone or with other materials as polishes or coating compositions.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1061446X | 1951-08-18 | ||
DE738589X | 1951-08-18 | ||
DEW6533A DE897158C (en) | 1951-08-18 | 1951-08-19 | Process for improving waxes, paraffins and mixtures of waxy substances |
Publications (1)
Publication Number | Publication Date |
---|---|
GB738589A true GB738589A (en) | 1955-10-19 |
Family
ID=31191548
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20508/52A Expired GB738589A (en) | 1951-08-18 | 1952-08-14 | Improved waxes and compositions containing them |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1061446A (en) |
GB (1) | GB738589A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3222200A (en) * | 1960-01-08 | 1965-12-07 | Emblem Harold Garton | Compositions for imparting water-repellent properties to fibrous materials |
US3271305A (en) * | 1961-09-01 | 1966-09-06 | Dan River Mills Inc | Textile treatments and treated textiles |
EP0274100A2 (en) * | 1986-12-22 | 1988-07-13 | Wacker Silicones Corporation | Sulfur containing organopolysiloxane waxes and a method for preparing the same |
-
1952
- 1952-08-13 FR FR1061446D patent/FR1061446A/en not_active Expired
- 1952-08-14 GB GB20508/52A patent/GB738589A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3222200A (en) * | 1960-01-08 | 1965-12-07 | Emblem Harold Garton | Compositions for imparting water-repellent properties to fibrous materials |
US3271305A (en) * | 1961-09-01 | 1966-09-06 | Dan River Mills Inc | Textile treatments and treated textiles |
EP0274100A2 (en) * | 1986-12-22 | 1988-07-13 | Wacker Silicones Corporation | Sulfur containing organopolysiloxane waxes and a method for preparing the same |
EP0274100A3 (en) * | 1986-12-22 | 1990-09-12 | Wacker Silicones Corporation | Sulfur containing organopolysiloxane waxes and a method for preparing the same |
Also Published As
Publication number | Publication date |
---|---|
FR1061446A (en) | 1954-04-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3544498A (en) | Detergent resistant silicone polish | |
US3576779A (en) | Amine-functional organopolysiloxane, salt thereof and polish composition therefrom | |
US3419593A (en) | Catalysts for the reaction of = sih with organic compounds containing aliphatic unsaturation | |
US2868824A (en) | Polymeric organosiloxanes | |
US3989666A (en) | Crosslinker-platinum catalyst-inhibitor and method of preparation thereof | |
US2846458A (en) | Organosiloxane ethers | |
US3172899A (en) | Or")noe | |
US3960575A (en) | Detergent resistant polish compositions | |
US4529752A (en) | Solvent resistant vulcanizable silicone rubber composition | |
US3364160A (en) | Organo-polysiloxane composition convertible at room temperature | |
US5221339A (en) | Heat-conductive silicone oil compound | |
US4618689A (en) | Novel aminofunctional silicone compositions | |
US3471541A (en) | N,n-disubstituted aminoalkoxyalkylsilicon compounds and derivatives thereof | |
US2909549A (en) | Alkoxy-endblocked silicone polymers | |
GB2065153A (en) | Method for producing silanol chain-stopped fluoroalkyl poly-siloxane fluids | |
CA1253655A (en) | Stabilized blends of thiofunctional polysiloxane fluids and organopolysiloxane fluids and a process for stabilizing the same | |
US4699988A (en) | Novel aminofunctional silicone compositions | |
GB799808A (en) | Rendering fibrous materials water-repellent | |
US3563941A (en) | Silicone modified carnauba wax | |
GB738589A (en) | Improved waxes and compositions containing them | |
US3344066A (en) | Silicone greases of high mechanical and thermal stability | |
US3423445A (en) | Pentahalophenylethylsilanes and siloxanes | |
US3110601A (en) | Organic silicate materials | |
US5246703A (en) | Siloxy-functional cyclopolysiloxanes | |
US2831009A (en) | Organosilicon boranes |