GB737392A - Improvements in or relating to organic tin-containing compounds and compositions containing the same - Google Patents

Improvements in or relating to organic tin-containing compounds and compositions containing the same

Info

Publication number
GB737392A
GB737392A GB23613/52A GB2361352A GB737392A GB 737392 A GB737392 A GB 737392A GB 23613/52 A GB23613/52 A GB 23613/52A GB 2361352 A GB2361352 A GB 2361352A GB 737392 A GB737392 A GB 737392A
Authority
GB
United Kingdom
Prior art keywords
radicals
tin
sulphur
referred
organo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23613/52A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB737392A publication Critical patent/GB737392A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22Tin compounds
    • C07F7/226Compounds with one or more Sn-S linkages
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102Polyesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/08Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
    • C10M2227/083Sn compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/135Steam engines or turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/16Dielectric; Insulating oil or insulators
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/17Electric or magnetic purposes for electric contacts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • C10N2070/02Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention comprises organo-tin compounds of the general formula RwSnGy wherein G represents any of the radicals <FORM:0737392/IV (b)/1> w being 2 or 3, y being 1 or 2 so that w + y is 4, Z represents oxygen or sulphur and R, R1 and R11 represent hydrocarbon radicals, and a process for the preparation thereof by reacting an organo-tin halide of the general formula RwSnXy, wherein R, w and y have the significance indicated above and X is a reactive halogen, with at least one salt of a sulphur containing compound of the general formula GY wherein Y represents a cation and G has the significance indicated above. The R, R1 and R11 radicals preferably have 1 to 20 carbon atoms and may be alkyl, alkenyl, cycloalkyl, aryl, aralkyl and alkaryl radicals. Alkyl radicals referred to are the methyl, isopropyl, octyl, dodecyl and octadecyl radicals. Other radicals referred to are the phenyl, naphthyl, benzyl, octaphenyl and ethylcyclohexyl radicals. The process may be carried out in a substantially inert solvent. The preferred reaction temperature is in the range of 10 DEG to 100 DEG C. The cation Y may be an alkali or alkaline earth metal such as sodium, potassium or calcium, or ammonium or amine salts of the sulphur containing acid may be used. The following sulphur-containing compounds are referred to: n-butyl, isopropyl, hexadecyl and ethylcyclohexyl, xanthic acids, n-nonyl, lauryl and benzyl thioxanthic acids, dibutyl isopropyl ethyl, diamyl, didodecyl, diethyl and diphenyl ethyl dithiocarbamic acids, di-(methylcyclohexyl), di-(octylphenyl), di-(2-ethylhexyl), dilauryl, dicetyl and di(butylmercapto)dithiophosphoric acids, and dialkyl dithiophosphoric acid where the alkyl groups are derived from a mixture of alcohols obtained from coconut oil and having from 8 to 18 carbon atoms. The cation Y may be an alkali or alkaline earth metal such as sodium, potassium, lithium or barium, or ammonium or amine salts may be used. Organotin halides referred to are dibutyl- and dilauryltin dichloride, di-n-hexyl-tin dibromide, triphenyl- and tri-tert.-octyl-tin iodide and tricyclohexyltin chloride. A number of detailed examples are given.ALSO:Mineral oil fractions and polyether and polyester lubricants contain as a stabilizer an organo-tin compound of the general formula RwSnGy where G represents one of the groups <FORM:0737392/III/1> w is 2 or 3, y is 1 or 2, w plus y is 4, Z is oxygen or sulphur and R, R1 and R11 represent hydrocarbon radicals. The stabilizer may be present in a minor proportion by weight, e.g. in an amount up to 20 per cent of the whole composition such as in an amount from 0.01 to 5 per cent preferably 0.1 to 2.0 per cent by weight based on the total composition. The stabilizer may be present in sufficient quantity to form a concentrated composition having from 20 to 75 per cent by weight of stabilizer based on the whole composition. Mineral oil fractions mentioned are motor and fuel oils, lubricating oils and greases, white mineral oils, hydrogenated mineral oils and heating oils. Organo-tin stabilizers specifically referred to are dilauryltindi-isopropylxanthate, dibutyltindi - n - butylxanthate, triphenyltinlaurylthioxanthate, dilauryltindibutyldithiocarbamate, dibutyltindiamyldithiocarbamate, dilauryltindi-(di-isopropyldithiophosphate), dibutyltindi-[di-(methylcyclohexyl) - dithiophosphate] and dibutyltindi - [di - (octylphenyl) - dithiophosphate.
GB23613/52A 1951-11-15 1952-09-19 Improvements in or relating to organic tin-containing compounds and compositions containing the same Expired GB737392A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US737392XA 1951-11-15 1951-11-15

Publications (1)

Publication Number Publication Date
GB737392A true GB737392A (en) 1955-09-28

Family

ID=22115516

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23613/52A Expired GB737392A (en) 1951-11-15 1952-09-19 Improvements in or relating to organic tin-containing compounds and compositions containing the same

Country Status (1)

Country Link
GB (1) GB737392A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018899A1 (en) * 1979-05-04 1980-11-12 Societe Nationale Elf Aquitaine Process for the preparation of organotin compounds

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018899A1 (en) * 1979-05-04 1980-11-12 Societe Nationale Elf Aquitaine Process for the preparation of organotin compounds
FR2455606A1 (en) * 1979-05-04 1980-11-28 Elf Aquitaine NEW PROCESS FOR THE PREPARATION OF ORGANOETANS

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