GB736165A - Improvements in or relating to methods of purifying materials - Google Patents
Improvements in or relating to methods of purifying materialsInfo
- Publication number
- GB736165A GB736165A GB12032/53A GB1203253A GB736165A GB 736165 A GB736165 A GB 736165A GB 12032/53 A GB12032/53 A GB 12032/53A GB 1203253 A GB1203253 A GB 1203253A GB 736165 A GB736165 A GB 736165A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zone
- trough
- frozen
- liquid
- gallium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/02—Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action including acoustic waves
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
A material having at least one impurity displaying differential solubility in solid and liquid phases of the material is refined by preparing a quantity of the impure material in the liquid phase, freezing a zone of the material and causing the frozen zone to traverse the liquid for a distance appreciably greater than the zone thickness whilst ensuring that at no time is the whole of the material returned to the liquid phase. According to Provisional Specification phosphorus is purified by melting it in a long glass trough within a chamber containing an inert atmosphere, e.g. nitrogen. A frozen zone is formed in the phosphorus by passing a cooling fluid, e.g. brine, through a tubing coil surrounding the trough and mounted within the chamber. The thickness of the frozen zone is preferably one tenth of the trough length and the trough is passed longitudinally through the coil to cause the frozen zone to traverse the phosphorus. When the frozen zone approaches the far end of the trough the impure liquid at that end may be drained off and the frozen zone remelted, or the frozen zone may be passed to the extreme end to freeze in the impurities and the solid material then separated from the remaining pure liquid phosphorus. The pure phosphorus may be frozen to provide a solid ingot or subjected to further refining treatments.ALSO:A material having at least one impurity displaying differential solubility in solid and liquid phases of the material is purified by preparing a quantity of impure material in the liquid phase, freezing a zone of the material and causing the frozen zone to traverse the liquid for a distance appreciably greater than the zone thickness whilst ensuring that at no time is the whole of the material returned to a solid phase. Gallium is purified by melting it in a long glass trough within a chamber containing an inert atmosphere, e.g. nitrogen. A number of separate frozen zones are formed in the gallium by passing a cooling fluid, e.g. brine, through a number of tubing coils surrounding the trough and spaced apart within the chamber. The size of the coils and their spacing is such that the length of each frozen zone and of each liquid region between them is one-tenth of the trough length. The trough is then passed longitudinally through successive coils to cause the frozen zones to traverse the gallium, and the process is finally halted before the last frozen zone has traversed the whole length of the trough. The purified gallium may be obtained by freezing the remaining zone rapidly and then cutting off one or both ends of the bar containing the impurity, or by draining away one or more of the regions of the liquid gallium remaining, the pure gallium either being obtained from that drained away or from that left in the trough according to the type of impurity present. Whilst traversing the trough the gallium may be kept molten by heating coils on either side of each cooling coil and the liquid may be agitated mechanically or by ultrasonic waves. In the case of high melting-point materials the frozen zone may be produced by allowing the material to lose heat by radiation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB12032/53A GB736165A (en) | 1953-04-30 | 1953-04-30 | Improvements in or relating to methods of purifying materials |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB12032/53A GB736165A (en) | 1953-04-30 | 1953-04-30 | Improvements in or relating to methods of purifying materials |
Publications (1)
Publication Number | Publication Date |
---|---|
GB736165A true GB736165A (en) | 1955-09-07 |
Family
ID=9997188
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12032/53A Expired GB736165A (en) | 1953-04-30 | 1953-04-30 | Improvements in or relating to methods of purifying materials |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB736165A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2359210A1 (en) * | 1976-07-19 | 1978-02-17 | Commw Scient Ind Res Org | PROCESS AND APPARATUS FOR PROMOTING THE CIRCULATION OF SOLID MATERIALS IN A LIQUID, IN PARTICULAR FOR THE REFINING OF METALS |
US4888051A (en) * | 1988-08-19 | 1989-12-19 | Cominco Ltd. | Method for the zone refining of gallium |
-
1953
- 1953-04-30 GB GB12032/53A patent/GB736165A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2359210A1 (en) * | 1976-07-19 | 1978-02-17 | Commw Scient Ind Res Org | PROCESS AND APPARATUS FOR PROMOTING THE CIRCULATION OF SOLID MATERIALS IN A LIQUID, IN PARTICULAR FOR THE REFINING OF METALS |
US4888051A (en) * | 1988-08-19 | 1989-12-19 | Cominco Ltd. | Method for the zone refining of gallium |
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