GB734644A - Compositions suitable for use as hydraulic fluids - Google Patents

Compositions suitable for use as hydraulic fluids

Info

Publication number
GB734644A
GB734644A GB19910/53A GB1991053A GB734644A GB 734644 A GB734644 A GB 734644A GB 19910/53 A GB19910/53 A GB 19910/53A GB 1991053 A GB1991053 A GB 1991053A GB 734644 A GB734644 A GB 734644A
Authority
GB
United Kingdom
Prior art keywords
tri
disulphide
diphenyl
glycidyl
acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19910/53A
Inventor
Peter Laverock Davies
Gerald David Galvin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Refining and Marketing Co Ltd
Original Assignee
Shell Refining and Marketing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Refining and Marketing Co Ltd filed Critical Shell Refining and Marketing Co Ltd
Priority to GB19910/53A priority Critical patent/GB734644A/en
Priority to DES40033A priority patent/DE950805C/en
Priority to NL189265A priority patent/NL91745C/en
Priority to BE530437A priority patent/BE530437A/en
Priority to FR1109460D priority patent/FR1109460A/en
Priority to US505519A priority patent/US2862886A/en
Publication of GB734644A publication Critical patent/GB734644A/en
Expired legal-status Critical Current

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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/50Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen
    • C10M105/52Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen containing carbon, hydrogen and halogen only
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/74Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing phosphorus
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    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16Ethers
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    • C10M135/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/20Thiols; Sulfides; Polysulfides
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    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14Acrylate; Methacrylate
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
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    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/142Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/146Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms
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    • C10M2207/22Acids obtained from polymerised unsaturated acids
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
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    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
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    • C10M2223/10Phosphatides, e.g. lecithin, cephalin
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    • C10N2010/04Groups 2 or 12
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

Compositions suitable for use as hydraulic fluids comprise 15 to 80 per cent of a normally liquid trialkyl phosphate containing at least 12 carbon atoms in the molecule, 1 to 15 per cent of a polymer of an ester of acrylic or alkyl acrylic acid, and 10 to 70 per cent of a normally liquid chlorinated, fluorinated, or chlorofluorinated hydrocarbon having a boiling point above 75 DEG C. Trialkyl phosphates specified are tri-n-butyl, tri-n-amyl, tri-2-ethylbutyl, tri-n-hexyl, tri-2-ethylhexyl, tri-n-octyl, and tri-(3,5,5-trimethylhexyl) phosphates; in order to reduce inflammability the compositions may also contain up to 50 per cent of phosphates containing aryl groups such as tricresyl, trixylenyl, diphenyl cresyl, phenyl dicresyl, diphenyl xylenyl, diphenyl ethylphenyl, diphenyl o-chlorophenyl, octyl diphenyl, dihexyl cresyl, octyl phenyl cresyl, and butyl octyl cresyl phosphates, and also phosphates containing tolyl, cumenyl, and pseudo-cumenyl groups. Polymers of esters of acrylic and alkyl acrylic acids specified are those made from the methyl, ethyl, n-propyl, isopropyl, isobutyl, lauryl, phenyl, or benzyl esters of acrylic, methacrylic, ethylacrylic, and propylacrylic acids, alone or in admixture with one another. The polymeric esters may be used in the form of concentrated dispersions in mineral oil. Halogenated hydrocarbons specified are carbon tetrachloride, ethylene dichloride, trichloroethylene, tetrachloroethylene, hexachlorobutadiene, o-dichlorobenzene, m-dichlorobenzene, chlorinated diphenyls, 1,2,4-trichlorobenzene, chlorin, ated cumene, tetrafluorotetrachloropropane-pentachlorotrifluoropropane, perfluorochloropentanes, perfluorochlorohexanes, perfluoroheptane, perfluoro-2,2,4-trimethyl pentane, perfluorobutandiene dimer and trimer, fluorinated kerosine and light lubricating oil distillates, liquid polymers of difluorovinyl chlorides and chlortrifluoroethylene, perfluoromethylcyclohexane, the perfluoro ortho-, meta-, and para-dimethylcyclohexanes, perfluoro-1,3,5-trimethylcyclohexane, perfluoronaphthalene and its methyl and dimethyl homologues, perfluorobenzene, perfluorotoluene, chloro-1,3-bis - (trifluoromethyl) benzene, dichloro - (trifluoromethyl) benzene, dichloro-bis-(trifluoro-methyl) benzene, chloro-1-(trifluoromethyl)-4-(chlorotetrafluoroethyl) benzene, trichlorobenzotrifluoride, and tetrachlorobenzotrifluoride. Also present in the compositions as corrosion inhibitors and anti-oxidants may be epoxy compounds such as glycidyl phenyl, glycidyl benzyl, glycidyl cyclohexyl, glycidyl o-cresyl, glycidyl methyl, and glycidyl isopropyl ethers, isobutylene oxide, butadiene monoxide, styrene oxide, cyclohexylene oxide, cyclopentene oxide, decene oxide, 2,3-epoxybutane, 1,2-epoxybutane, and epichlorhydrin; these epoxy compounds may be used alone or in combination with sulphur containing organic compounds for example butyl disulphide, benzyl disulphide, wax disulphide, di-n-propyl disulphide, di-isoamyl disulphide, diphenyl disulphide, and alkyl mercaptans. Alternatively there may be used as inhibitors organic salts of Group II metals, such as the zinc and cadmium salts of alkylated salicyclic acids, alkyl malonic acids, condensation products of sulphanols with unsaturated carboxylic acids, hydrocarbon sulphonic acids, and aminophenols.
GB19910/53A 1953-07-17 1953-07-17 Compositions suitable for use as hydraulic fluids Expired GB734644A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB19910/53A GB734644A (en) 1953-07-17 1953-07-17 Compositions suitable for use as hydraulic fluids
DES40033A DE950805C (en) 1953-07-17 1954-07-16 Non-flammable hydraulic fluid
NL189265A NL91745C (en) 1953-07-17 1954-07-16 Process for preparing a hydraulic fluid
BE530437A BE530437A (en) 1953-07-17 1954-07-16 A method for the preparation of a non-flammable liquid, suitable for use as a hydraulic liquid
FR1109460D FR1109460A (en) 1953-07-17 1954-07-17 Compositions to be used as hydraulic fluids
US505519A US2862886A (en) 1953-07-17 1955-05-02 Compositions for use as hydraulic fluids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB19910/53A GB734644A (en) 1953-07-17 1953-07-17 Compositions suitable for use as hydraulic fluids
US505519A US2862886A (en) 1953-07-17 1955-05-02 Compositions for use as hydraulic fluids

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GB734644A true GB734644A (en) 1955-08-03

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GB19910/53A Expired GB734644A (en) 1953-07-17 1953-07-17 Compositions suitable for use as hydraulic fluids

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US (1) US2862886A (en)
BE (1) BE530437A (en)
DE (1) DE950805C (en)
FR (1) FR1109460A (en)
GB (1) GB734644A (en)
NL (1) NL91745C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2992991A (en) * 1957-03-20 1961-07-18 Minnesota Mining & Mfg Thermally stable viscous composition containing a chlorfluorinated alkane oil
US2992989A (en) * 1957-03-20 1961-07-18 Minnesota Mining & Mfg Thermally stable viscous materials containing bromofluorohalogenated alkane oils

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1153546A (en) * 1966-08-30 1969-05-29 Chevron Res Hydraulic Fluids
US3637507A (en) * 1968-02-12 1972-01-25 Stauffer Chemical Co Aircraft hydraulic fluid and method of controlling acid buildup therein with acid acceptor
US3718596A (en) * 1970-02-16 1973-02-27 Monsanto Co Functional fluid compositions
US3932294A (en) * 1974-01-11 1976-01-13 Chevron Research Company Functional fluid containing a hydrolysis suppressor
US3941708A (en) * 1974-02-11 1976-03-02 Stauffer Chemical Company Hydraulic fluid antioxidant system
US3976585A (en) * 1974-03-25 1976-08-24 Monsanto Company Functional fluid compositions containing epoxide stabilizers
US6156228A (en) * 1994-11-16 2000-12-05 Houghton International, Inc. Trialkoxyalkylphosphate-based fire resistant fluid containing triglyceride
US10508203B2 (en) 2014-09-26 2019-12-17 The Boeing Company Compositions and coatings with non-chrome corrosion inhibitor particles

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2524590A (en) * 1946-04-22 1950-10-03 Carsten F Boe Emulsion containing a liquefied propellant gas under pressure and method of spraying same
FR966140A (en) * 1947-05-13 1950-09-30
US2549270A (en) * 1948-07-19 1951-04-17 Shell Dev Lubricant and hydraulic fluid composition
US2583588A (en) * 1949-06-08 1952-01-29 Mosteller James Calvin Less inflammable hydraulic fluid
US2710842A (en) * 1950-05-19 1955-06-14 Texas Co Hydraulic transmission fluid
US2707176A (en) * 1951-01-15 1955-04-26 Monsanto Chemicals Tricresyl phosphate-chlorinated biphenyl functional fluid improved by alkylated polystyrene
US2719129A (en) * 1951-06-30 1955-09-27 Colgate Palmolive Co Pressurized liquid room and air deodorant compositions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2992991A (en) * 1957-03-20 1961-07-18 Minnesota Mining & Mfg Thermally stable viscous composition containing a chlorfluorinated alkane oil
US2992989A (en) * 1957-03-20 1961-07-18 Minnesota Mining & Mfg Thermally stable viscous materials containing bromofluorohalogenated alkane oils

Also Published As

Publication number Publication date
FR1109460A (en) 1956-01-30
US2862886A (en) 1958-12-02
NL91745C (en) 1959-08-15
DE950805C (en) 1956-10-18
BE530437A (en) 1954-08-14

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