GB732005A - Foundry sand compositions and sand moulds formed therefrom - Google Patents
Foundry sand compositions and sand moulds formed therefromInfo
- Publication number
- GB732005A GB732005A GB13506/53A GB1350653A GB732005A GB 732005 A GB732005 A GB 732005A GB 13506/53 A GB13506/53 A GB 13506/53A GB 1350653 A GB1350653 A GB 1350653A GB 732005 A GB732005 A GB 732005A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- alkyl
- polymer
- copolymer
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/167—Mixtures of inorganic and organic binding agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/22—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins
- B22C1/2206—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A composition suitable for making foundry sand moulds or cores comprises sand, clay, water and a polymeric water-soluble polyelectrolyte having a weight-average molecular weight of at least 10,000 and a substantially linear continuous carbon chain obtained by the polymerization of a compound containing an aliphatic unsaturated group. The composition preferably contains from 1 to 15 parts of clay and from 0.02 to 1.0 parts of polyelectrolyte per 100 parts of sand. The polyelectrolyte may be (1) a copolymer of (a) a polycarboxylic acid or a derivative thereof such as maleic anhydride, maleic, fumaric, itaconic, citraconic and aconitic acids, the amides of these acids, the alkali metal, alkaline earth metal and ammonium salts of these acids, the partial alkyl esters, salts of the partial alkyl esters, and the substituted amides of these polycarboxylic acids and one or more of (b) acrylic acid, acrylamide, acrylic acid salts of alkali metal and ammonium, N-substituted acrylamide or a corresponding derivative of methacrylic or crotonic acid, ethylene, propylene, isobutylene, styrene, alpha-methylstyrene, vinyl acetate, vinyl chloride, vinyl formate, a vinyl alkyl ether, an alkyl acrylate or methacrylate, vinyl sulphonic acid, vinyl phosphonic acid and vinyl pyrrolidone; (2) a homopolymer of acrylic or methacrylic acid or the alkali metal or ammonium salts thereof, acrylamide, methacrylamide, an N-alkyl-substituted amide, an N-amino alkyl amide, an N-alkyl-aminoalkyl substituted amide, an amino alkyl acrylate, an aminoalkyl methacrylamide, or an N-alkyl substituted aminoalkyl acrylate or methacrylate, or a copolymer of one of the above with ethylene, propylene, isobutylene, styrene, alpha-methylstyrene, vinyl acetate, vinyl formate, a vinyl alkyl ether, acrylonitrile, methacrylonitrile, vinylidene chloride, vinyl chloride, or an alkyl acrylate, methacrylate, maleate or fumarate; (3) a polymer containing amine radicals such as a poly N-vinyl amine, a poly-N-allylamine, polyvinyl pyridine and its amine and quaternary ammonium salts, a product derived by the polymerization of an amide or imide, followed by reduction, and a product obtained by the hydrogenation of an acrylonitrile or methacrylonitrile polymer or copolymer; (4) a polymer of a vinyl-substituted amide such as vinyl pyrrolidone, vinyl piperidone, an alkyl-substituted product thereof, N - vinyl - N - methylformamide, N-vinyl formamide, and N-vinyl acetamide, or a copolymer of one of the above with vinyl acetate, acrylonitrile, isobutylene, ethylene, styrene, vinyl chloride, vinylidene chloride, vinyl formate, a vinyl alkyl ether, an alkyl acrylate or methacrylate, acrylic acid, methacrylic acid, acrylamide, methacrylamide, a monoalkyl maleate, or an aminoalkyl ester or alkali metal or ammonium salt of acrylic acid; (5) a polymer of vinyl sulphonic acid or a copolymer thereof with vinyl chloride, acrylonitrile, styrene or vinyl acetate; (6) a polymer prepared by hydrolysis of a polymer containing nitrile groups; (7) a polymer containing hydrophilic lactone groups prepared by hydrolysis of a copolymer of maleic anhydride and vinyl acetate; (8) a polymer prepared by the hydrolysis of vinyl acetate copolymers; (9) a polymer prepared by esterifying polyvinyl alcohol with a dibasic acid; (10) a polymer obtained by reacting a polymer or copolymer of vinyl chloroacetate or vinyl chloroethyl ether with an amine; (11) a polymer prepared by the ammonolysis of polyvinyl methyl ketone. Preferred polyelectrolytes are the sodium salt of a partially hydrolysed polyacrylonitrile and a copolymer of vinyl acetate and maleic anhydride. Other ingredients which may be present in the composition are natural and synthetic resins, flour, cereals, sea coal, fly ash, zirconite, and bituminous additives such as asphalt.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US732005XA | 1952-05-15 | 1952-05-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB732005A true GB732005A (en) | 1955-06-15 |
Family
ID=22112343
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13506/53A Expired GB732005A (en) | 1952-05-15 | 1953-05-14 | Foundry sand compositions and sand moulds formed therefrom |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB732005A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3005245A (en) * | 1959-01-26 | 1961-10-24 | Monsanto Chemicals | Method for making polymeric foundry core or mold |
FR2372667A1 (en) * | 1976-12-03 | 1978-06-30 | Sekisui Chemical Co Ltd | COMPOSITION FOR FOUNDRY MOLDS AND PROCESS FOR THE PRODUCTION OF MOLDS FROM THIS COMPOSITION |
EP0209906A2 (en) * | 1985-07-24 | 1987-01-28 | Nippon Petrochemicals Company, Limited | Binder for dry sand mold and method of its usage |
EP0256364A1 (en) * | 1986-08-07 | 1988-02-24 | Röhm Gmbh | Binder for foundry sands |
-
1953
- 1953-05-14 GB GB13506/53A patent/GB732005A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3005245A (en) * | 1959-01-26 | 1961-10-24 | Monsanto Chemicals | Method for making polymeric foundry core or mold |
FR2372667A1 (en) * | 1976-12-03 | 1978-06-30 | Sekisui Chemical Co Ltd | COMPOSITION FOR FOUNDRY MOLDS AND PROCESS FOR THE PRODUCTION OF MOLDS FROM THIS COMPOSITION |
EP0209906A2 (en) * | 1985-07-24 | 1987-01-28 | Nippon Petrochemicals Company, Limited | Binder for dry sand mold and method of its usage |
EP0209906A3 (en) * | 1985-07-24 | 1987-10-07 | Nippon Petrochemicals Company, Limited | Binder for dry sand mold and method of its usage |
EP0256364A1 (en) * | 1986-08-07 | 1988-02-24 | Röhm Gmbh | Binder for foundry sands |
US4847309A (en) * | 1986-08-07 | 1989-07-11 | Rohm Gmbh | Method for making foundry sand containing a resin binder |
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