GB721713A - Resinous ethers of alkenyl-phenol/aldehyde condensates - Google Patents
Resinous ethers of alkenyl-phenol/aldehyde condensatesInfo
- Publication number
- GB721713A GB721713A GB20023/52A GB2002352A GB721713A GB 721713 A GB721713 A GB 721713A GB 20023/52 A GB20023/52 A GB 20023/52A GB 2002352 A GB2002352 A GB 2002352A GB 721713 A GB721713 A GB 721713A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- drying
- blown
- alkyl
- chain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
- C08G8/36—Chemically modified polycondensates by etherifying
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
A resin is made by etherifying a condensation product derived from an aldehyde and a phenol having an ethylenically unsaturated hydrocarbon chain containing 14-28 carbon atoms attached to its aromatic nucleus. The Specification contains a list of aldehydes and a list of anacardic phenols having the formula (R.C6H3OH.X)n, where R is a hydrocarbon radical of 14-28 carbon atoms containing one or more double bonds, n is 1 or more and X is a hydrogen atom or a hydroxyl, aryloxy, alkoxy, alkenyl, alkyl, acyl, aryl, aralkyl, halogen, sulphhydryl, carboxy, amino, alkamino, dialkamino, acetamino, methylol, cycloalkyl, carbalkoxy, alkenoxy, alkenecarboxy or thiocarboxy group. The etherifying agents (many specified) are alkyl, alkenyl, aralkyl, cycloalkyl, and aryl halides; alkyl and aralkyl sulphates; alkyl and aralkyl benzene sulphonates; and diazomethane. The resinous ethers dissolved in naphtha, or in the case of the low condensates (dimers-tetramers) without a solvent, are used as coating compositions after addition of manganese, lead or cobalt driers. The flexibility of the dried coating may be increased (a) by replacing part of the alkenyl phenol with a long-chain alkyl phenol (e.g. hydrogenated cardanol or wax phenols) containing 14-30 carbon atoms in the alkyl chain; (b) by using a long-chain aldehyde for all or part of the aldehyde in the condensation reaction; or (c) by using a long-chain etherifying agent. The hardness of these films may be increased (a) by replacing part of the alkenyl phenol with phenol or cresols; (b) by using a short-chain etherifying agent; or (c) using 1-2 mols. of aldehyde per mol. of phenol in the condensation reaction along with increased reaction times and temperatures. Skinning of the varnishes is prevented by adding 1 per cent or less of free phenols. The ethers may be plasticized with blown or unblown drying or non-drying oils, e.g. soya bean, linseed, oiticica, perilla, sardine, tung, cotton seed or dehydrated castor. They may be added to semi-drying oils to upgrade them and may be co-blown with semi-drying or drying oils (see Group III). The ethers may be used as plasticizers for phenolformaldehyde resins or natural or synthetic rubbers and may be cross-vulcanized with natural or synthetic rubbers using sulphur or sulphur-containing compounds. They may be co-polymerized with butadiene, styrene, chloroprene, acrylonitrile, isoprene or any combination of these in presence of peroxide or peroxide-redox systems, or sodium to give internally plasticized rubbers. In examples (1) cardanol is condensed with formalin in presence of ammonia to give a low molecular weight condensate which is etherified with diethyl sulphate in presence of sodium hydroxide, toluol and xylol; (2) the condensate of example (1) is etherified with a mixture of allyl chloride and diethyl sulphate in presence of potassium hydroxide, ethanol and butanol; (3) cardanol is condensed with formalin in presence of ammonia and xylol to give a higher molecular weight condensate which is etherified with diethyl sulphate in presence of sodium hydroxide, xylol and butanol; (4) the condensate of example (3) is etherified with a mixture of allyl chloride and diethyl sulphate in presence of potassium hydroxide, ethanol and butanol; (5) and (6) the ether of example (3) is mixed with linseed or soya bean oil and the mixture blown with oxygen.ALSO:A resinous product obtained by etherifying a condensation product of an aldehyde and a phenol having an ethylenically unsaturated hydrocarbon chain containing 14-28 carbon atoms attached to its aromatic nucleus (especially an anacardic phenol) (see Group IV(a)) may be added to semi-drying oils to decrease their gelation and drying times and increase their resistance to soft water, alkali, organic solvents and acids. The resin may be co-blown with drying or semi-drying oils to give oils with better drying properties. In examples (5) A mixture of 14 grams of linseed oil and 6 grams of the ethyl ether of a cardanol-formaldehyde condensate was heated to 100 DEG C. and oxygen was blown through at 180 c.c. per minute. (6) Soya bean oil containing 10-13 per cent of the ethyl ether of a cardanol-formaldehyde condensate was blown with oxygen as in example (5).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US721713XA | 1951-08-23 | 1951-08-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB721713A true GB721713A (en) | 1955-01-12 |
Family
ID=22106019
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20023/52A Expired GB721713A (en) | 1951-08-23 | 1952-08-08 | Resinous ethers of alkenyl-phenol/aldehyde condensates |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB721713A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3320213A (en) * | 1964-01-27 | 1967-05-16 | Dow Chemical Co | Self-extinguishing phenol-aldehyde resins prepared by reacting phenol with halogen-substituted aromatic aldehydes |
CN102391449A (en) * | 2011-09-22 | 2012-03-28 | 华南理工大学 | Allyl para-tert-butyl phenyl ether formaldehyde tackifying resin and preparation method thereof |
CN109721697A (en) * | 2017-10-30 | 2019-05-07 | 彤程化学(中国)有限公司 | A kind of modified anacardol-phenol-formaldehyde resin and its preparation and application |
US10696838B2 (en) | 2017-10-06 | 2020-06-30 | Hexion Inc. | Rubber compositions containing tackifiers |
US10808068B2 (en) | 2018-01-26 | 2020-10-20 | Hexion Inc. | Manufacture of novolacs and resoles using lignin |
US10982034B2 (en) | 2015-10-29 | 2021-04-20 | Hexion Inc. | Alkylphenol resins and a method of preparing thereof |
CN117362560A (en) * | 2023-12-04 | 2024-01-09 | 山东永创材料科技有限公司 | Modified phenolic resin and preparation method thereof |
-
1952
- 1952-08-08 GB GB20023/52A patent/GB721713A/en not_active Expired
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3320213A (en) * | 1964-01-27 | 1967-05-16 | Dow Chemical Co | Self-extinguishing phenol-aldehyde resins prepared by reacting phenol with halogen-substituted aromatic aldehydes |
CN102391449A (en) * | 2011-09-22 | 2012-03-28 | 华南理工大学 | Allyl para-tert-butyl phenyl ether formaldehyde tackifying resin and preparation method thereof |
US10982034B2 (en) | 2015-10-29 | 2021-04-20 | Hexion Inc. | Alkylphenol resins and a method of preparing thereof |
US11518839B2 (en) | 2015-10-29 | 2022-12-06 | Bakelite UK Holding Ltd. | Alkylphenol resins and a method of preparing thereof |
US10696838B2 (en) | 2017-10-06 | 2020-06-30 | Hexion Inc. | Rubber compositions containing tackifiers |
US10982087B2 (en) | 2017-10-06 | 2021-04-20 | Hexion Inc. | Rubber compositions containing tackifiers |
CN109721697A (en) * | 2017-10-30 | 2019-05-07 | 彤程化学(中国)有限公司 | A kind of modified anacardol-phenol-formaldehyde resin and its preparation and application |
CN109721697B (en) * | 2017-10-30 | 2021-11-02 | 彤程化学(中国)有限公司 | Modified cardanol-phenol-formaldehyde resin and preparation and application thereof |
US10808068B2 (en) | 2018-01-26 | 2020-10-20 | Hexion Inc. | Manufacture of novolacs and resoles using lignin |
US11697703B2 (en) | 2018-01-26 | 2023-07-11 | Bakelite UK Holding Ltd. | Manufacture of novolacs and resoles using lignin |
CN117362560A (en) * | 2023-12-04 | 2024-01-09 | 山东永创材料科技有限公司 | Modified phenolic resin and preparation method thereof |
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