GB712278A - Norcamphor hydrazone, nortricyclene and processes for preparing the same - Google Patents

Norcamphor hydrazone, nortricyclene and processes for preparing the same

Info

Publication number
GB712278A
GB712278A GB18226/52A GB1822652A GB712278A GB 712278 A GB712278 A GB 712278A GB 18226/52 A GB18226/52 A GB 18226/52A GB 1822652 A GB1822652 A GB 1822652A GB 712278 A GB712278 A GB 712278A
Authority
GB
United Kingdom
Prior art keywords
hydrazone
camphor
nortricyclene
norcamphor
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18226/52A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB712278A publication Critical patent/GB712278A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72Hydrazones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/323Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00Systems containing at least three condensed rings
    • C07C2603/56Ring systems containing bridged rings
    • C07C2603/58Ring systems containing bridged rings containing three rings
    • C07C2603/60Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises nor-camphor hydrazone, C7H12N2, its preparation by reacting nor-camphor with hydrazine, and the conversion of nor-camphor hydrazone to nor-tricyclene [tricyclo - (2.2.1.02,6) - heptane] by mild oxidation, especially in alkaline medium. In examples: (1) nor-camphor, ethanol and anhydrous hydrazine are refluxed, and nor-camphor hydrazone isolated by distillation; (2) nor-camphor hydrazone, calcium oxide and mercuric oxide in alcohol are refluxed, the distillate treated with water and pentane, and nor-tricyclene obtained from the organic layer by distillation.
GB18226/52A 1951-07-20 1952-07-18 Norcamphor hydrazone, nortricyclene and processes for preparing the same Expired GB712278A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US712278XA 1951-07-20 1951-07-20

Publications (1)

Publication Number Publication Date
GB712278A true GB712278A (en) 1954-07-21

Family

ID=22100043

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18226/52A Expired GB712278A (en) 1951-07-20 1952-07-18 Norcamphor hydrazone, nortricyclene and processes for preparing the same

Country Status (1)

Country Link
GB (1) GB712278A (en)

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