GB711122A - Improvements in or relating to the production of bis(hydroxyphenyl) compounds - Google Patents
Improvements in or relating to the production of bis(hydroxyphenyl) compoundsInfo
- Publication number
- GB711122A GB711122A GB23562/52A GB2356252A GB711122A GB 711122 A GB711122 A GB 711122A GB 23562/52 A GB23562/52 A GB 23562/52A GB 2356252 A GB2356252 A GB 2356252A GB 711122 A GB711122 A GB 711122A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tert
- bis
- butyl
- hydroxyphenyl
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B11/00—Automatic controllers
- G05B11/01—Automatic controllers electric
- G05B11/012—Automatic controllers electric details of the transmission means
Abstract
Bis (hydroxyphenyl) compounds are prepared by reacting phenolic compounds with carbonyl compounds in an aqueous acidic medium containing at least twice as much water by weight as phenolic compound. The products may be represented by the formula <FORM:0711122/IV (b)/1> where each R, which may be the same or different, is hydrogen or an alkyl, cycloalkyl, aryl, alkaryl or aralkyl radical. The phenolic radicals may be further substituted by similar radicals. Examples of carbonyl compounds are formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, isobutyraldehyde, n-valeraldehyde, trimethylacetaldehyde and benzaldehyde. In addition to phenol and alkyl substituted phenols, such compounds as o- and p - phenyl phenols, naphthols, phenanthrol, cresylic acid and compounds having more than one hydroxy group in the nucleus are mentioned. Examples of acidic catalysts are sulphuric, hydrochloric, acetic, p-toluene sulphonic, alkane sulphonic, phosphoric, sulphamic and hydrofluoric acids and boron trifluoride complexes. Emulsifying agents are preferably employed. The reaction temperature may be from 20 DEG to 150 DEG C. The products are obtained in a high state of purity as fine spheroidal particles which generally become smaller as the ratio of water to phenol is increased up to about 9. They may comprise isomeric forms of a compound, and when using two or more different phenolic compounds, the resulting mixture will contain proportions of compounds wherein two different phenolic radicals are attached to a single carbon atom. The process may be batch, continuous or semi-continuous, employing one or more reactors provided with stirrers. In the examples: bis-(3-tert.-butyl-5-methyl-2-hydroxyphenyl)-methane is prepared from tert.-butyl cresol and formaldehyde; bis-(4-hydroxyphenyl) methane from phenol and formaldehyde; bis-(3,4-dimethyl-2-hydroxy-phenyl) methane from 2,3-dimethyl-phenol and formaldehyde; 1,1-bis-(3-tert.-butyl-6-methyl-4-hydroxyphenyl) propane from 2-tert.-butyl-5-methyl-phenol and propionaldehyde; 1,1-bis-(3 - tert. - butyl - 5 - methyl - 4 - hydroxyphenyl) ethane from 2-methyl-6-tert.-butylphenol and acetaldehyde; bis-(3 - tert. - octyl - 6 - methyl-4 - hydroxyphenyl) methane from 2 - tert. - octyl - 5 - methylphenol and formaldehyde; bis - (3 - tert. - butyl - 6 - methyl - 4 - hydroxy-phenyl) benzylidene from 2 - tert. - butyl - 5 - methylphenol and benzaldehyde; and bis-(3-tert. - butyl - 5 - isopropyl - 2 - hydroxyphenyl) methane from 2-tert.-butyl-4-isopropylphenol and formaldehyde.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US711122XA | 1951-09-22 | 1951-09-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB711122A true GB711122A (en) | 1954-06-23 |
Family
ID=22099321
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23562/52A Expired GB711122A (en) | 1951-09-22 | 1952-09-19 | Improvements in or relating to the production of bis(hydroxyphenyl) compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB711122A (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2773100A (en) * | 1956-12-04 | Pftepajration of | ||
US2792429A (en) * | 1953-09-22 | 1957-05-14 | Union Carbide & Carbon Corp | Production of dihydroxy diphenyl alkanes |
US2796444A (en) * | 1954-11-04 | 1957-06-18 | American Cyanamid Co | Process for preparing methylene bis phenols |
US2796445A (en) * | 1954-11-04 | 1957-06-18 | American Cyanamid Co | Process for preparing methylene bis phenols |
DE1058065B (en) * | 1954-11-04 | 1959-05-27 | American Cyanamid Co | Process for the preparation of 2, 2'-methylene-bis-4, 6-dialkyl-phenols |
US3019269A (en) * | 1962-01-30 | Stabilisation of phenols | ||
US3051760A (en) * | 1962-08-28 | Method of purification and crystalliza- | ||
DE1135488B (en) * | 1959-10-03 | 1962-08-30 | Consortium Elektrochem Ind | Process for the preparation of diphenylolalkanes |
DE1238039B (en) * | 1963-10-10 | 1967-04-06 | Us Rubber Co | Process for the preparation of bis [2-hydroxy-3- (alpha-methylxylyl) -5-methylphenyl] methane |
DE1240874B (en) * | 1963-10-10 | 1967-05-24 | Us Rubber Co | Process for the preparation of bis- [2-hydroxy-3- (alpha, alpha-dimethylbenzyl) -5-methylphenyl] methane |
DE1242237B (en) * | 1957-12-31 | 1967-06-15 | Union Carbide Corp | Process for the production of bisphenols |
EP0090787A1 (en) * | 1982-03-29 | 1983-10-05 | Monsanto Company | A process for making bis (hydroxyphenyl)-methanes |
-
1952
- 1952-09-19 GB GB23562/52A patent/GB711122A/en not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2773100A (en) * | 1956-12-04 | Pftepajration of | ||
US3019269A (en) * | 1962-01-30 | Stabilisation of phenols | ||
US3051760A (en) * | 1962-08-28 | Method of purification and crystalliza- | ||
US2792429A (en) * | 1953-09-22 | 1957-05-14 | Union Carbide & Carbon Corp | Production of dihydroxy diphenyl alkanes |
US2796444A (en) * | 1954-11-04 | 1957-06-18 | American Cyanamid Co | Process for preparing methylene bis phenols |
US2796445A (en) * | 1954-11-04 | 1957-06-18 | American Cyanamid Co | Process for preparing methylene bis phenols |
DE1058065B (en) * | 1954-11-04 | 1959-05-27 | American Cyanamid Co | Process for the preparation of 2, 2'-methylene-bis-4, 6-dialkyl-phenols |
DE1242237B (en) * | 1957-12-31 | 1967-06-15 | Union Carbide Corp | Process for the production of bisphenols |
DE1135488B (en) * | 1959-10-03 | 1962-08-30 | Consortium Elektrochem Ind | Process for the preparation of diphenylolalkanes |
DE1238039B (en) * | 1963-10-10 | 1967-04-06 | Us Rubber Co | Process for the preparation of bis [2-hydroxy-3- (alpha-methylxylyl) -5-methylphenyl] methane |
DE1240874B (en) * | 1963-10-10 | 1967-05-24 | Us Rubber Co | Process for the preparation of bis- [2-hydroxy-3- (alpha, alpha-dimethylbenzyl) -5-methylphenyl] methane |
EP0090787A1 (en) * | 1982-03-29 | 1983-10-05 | Monsanto Company | A process for making bis (hydroxyphenyl)-methanes |
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