GB706781A - Mixed condensates of polymeric polyanhydride structure - Google Patents

Mixed condensates of polymeric polyanhydride structure

Info

Publication number
GB706781A
GB706781A GB7355/51A GB735551A GB706781A GB 706781 A GB706781 A GB 706781A GB 7355/51 A GB7355/51 A GB 7355/51A GB 735551 A GB735551 A GB 735551A GB 706781 A GB706781 A GB 706781A
Authority
GB
United Kingdom
Prior art keywords
reactants
silane
alkoxy
alkoxy compound
silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7355/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB706781A publication Critical patent/GB706781A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/56Boron-containing linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/60Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Silicon Polymers (AREA)
  • Polyethers (AREA)

Abstract

Polymers suitable as hydraulic liquids, lubricants, lacquers or anti-foaming agents and containing two of the elements phosphorus, boron and silicon are prepared by splitting out an ether from an alkoxy compound of one of the elements with an alkoxy compound of another of them. The alkoxy groups are saturated and contain up to four carbon atoms each. Suitable reactants are dimethyl diethoxy silane; methyl triethoxy silane; diphenyl dimethoxy silane; phenyl trimethoxy silane; trimethyl phosphate; trimethyl borate. The reactants are preferably employed in stoichiometric proportions. The products are linear, cyclic or cross-linked depending on the functionality of the reactants. Mono-functional alkoxy compounds or a tetra-functional alkoxy compound of silicon, e.g. ethyl-o-silicate may be used in the reaction. In the example trimethyl phosphate is heated with tetra methyl silicate in a bomb tube for 8 hours at 200 DEG C. and 8 hours at 250 DEG C. Volatile products were removed by distillation and a white polymer remained.ALSO:Polymers suitable as hydraulic liquids, lubricants, lacquers or anti-foaming agents and containing two of the elements phosphorus, boron and silicon are prepared by splitting out an ether from an alkoxy compound of one of the elements with an alkoxy compound of another of them. The alkoxy groups are saturated and contain up to four carbon atoms each. Suitable reactants are dimethyl diethoxy silane; methyl triethoxysilane; diphenyl dimethoxy silane; phenyl trimethoxy silane; trimethyl phosphate; trimethyl borate. The reactants are preferably employed in stoiochiometric proportions. The products are linear, cyclic or cross-linked depending on the functionality of the reactants. Mono-functional alkoxy compounds or a tetra-functional alkoxy compound of silicon, e.g. ethyl-o-silicate, may be used in the reaction. In the example trimethyl phosphate is heated with tetra methyl silicate in a bomb tube for 8 hours at 100 DEG C. and 8 hours at 250 DEG C. Volatile products were removed by distillation and a white polymer remained.
GB7355/51A 1950-03-29 1951-03-29 Mixed condensates of polymeric polyanhydride structure Expired GB706781A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE706781X 1950-03-29

Publications (1)

Publication Number Publication Date
GB706781A true GB706781A (en) 1954-04-07

Family

ID=6617239

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7355/51A Expired GB706781A (en) 1950-03-29 1951-03-29 Mixed condensates of polymeric polyanhydride structure

Country Status (1)

Country Link
GB (1) GB706781A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3422027A (en) * 1967-02-15 1969-01-14 Nalco Chemical Co Novel compositions and their use in preventing and inhibiting foam

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3422027A (en) * 1967-02-15 1969-01-14 Nalco Chemical Co Novel compositions and their use in preventing and inhibiting foam

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