GB698179A - Compositions comprising acid-curing thermosetting aminoplast resins - Google Patents
Compositions comprising acid-curing thermosetting aminoplast resinsInfo
- Publication number
- GB698179A GB698179A GB14333/50A GB1433350A GB698179A GB 698179 A GB698179 A GB 698179A GB 14333/50 A GB14333/50 A GB 14333/50A GB 1433350 A GB1433350 A GB 1433350A GB 698179 A GB698179 A GB 698179A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- iodide
- hexamine
- cetyl
- carbonyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
A moulding or coating composition comprises an acid-curing amino-plast condensate or resin and a curing catalyst which is the salt of a quaternary hexamethylenetetramine base having the formula (C6H12N4)mRnXp where R is an alkyl, alkylene, alkanyl, alkylidene, cycloalkyl, or aryl substituted aliphatic hydrocarbon radical, or a monosubstituted alkyl group in which the substitutent is an alkoxy, amino-carbonyl, aryl-carbonyl, alkoxy-carbonyl or aryloxy-carbonyl radical, X is the anion of an acid which will act as a curing catalyst and either p = 1, m = 1 and n = 1 or p = 1, m = 2 and n = 2 or p = 2, m = 2 and n = 1. R may be, for example, methyl, methylene, ethyl, isopropyl, hexyl, isopropyl, hexyl, heptyl, cetyl, cyclohexyl, allyl, benzyl, carbamylethyl, carbethoxymethyl, carbophenoxymethyl, benzoylmethyl and methoxymethyl, and X may be chloride, bromide, iodide, sulphate, benzene sulphonate, chromate, dichymate, thiocyanate formate and benzoate. The catalysts are stated to become active only at moulding temperatures so that the compositions are normally stable. Resins referred to are those derived from aldehydes and urea, thiourea, the reaction products obtained by the pyrolysis of dicyandiamide, melamine and other aminotriagines, and co-condensates of these resins. Fillers referred to are wood flour, asbestos, cotton linters, regenerated cellulose and clay. Pigments, lubricants such as zinc stearate, starches, gums, alginates and casein may also be incorporated. Examples: (1) 35 parts cellulose pulp filler, 65 parts urea-formaldehyde reaction product, 0.25 parts methyl hexamine iodide; (2) as (1) but with 0.5 parts cetyl hexamine iodide; (3) as (1) but with 0.25 parts ethyl hexamine iodide; (4) 30 parts cellulose pulp filler, 70 parts of a melamine-urea-formaldehyde reaction product in which the melamine to urea molar ratio was 1 to 9, and 0.5 parts cetyl hexamine iodide. 0.01 to 0.1 per cent by weight of the composition of hexamine may be added as a pH stabilizer. The curing agents are stated to produce products of improved water resistance and where R is a high molecular weight aliphatic radical, e.g. cetyl, this is stated to act as a mould lubricant.ALSO:Quaternary hexamethylenetetramine salts having the general formula (C6H12N4)mRnXp, where R is an alkyl, alkylene, alkenyl, alkylidene, cycloalkyl, or aryl-substituted aliphatic hydrocarbon radical, or a monosubstituted alkyl group in which the substituent is an alkyloxy, aminocarbonyl, arylcarbonyl, alkoxycarbonyl or aryloxycarbonyl radical, X is the anion of an acid and either p=1, m=1 and n=1, or p=1, m=2 and n=2, or p=2, m=2 and n=1, are made by mixing solutions of hexamethylenetetramine and the appropriate RX compound in correct proportions, allowing the mixture to stand for a few hours to several weeks, filtering, rinsing and drying the precipitated salt. Chloroform is a suitable solvent. Sometimes an excess of the RX compound is desirable. Examples of R are:-methyl, methylene, ethyl, isopropyl, hexyl, heptyl, cetyl, cyclohexyl, allyl, benzyl, carbamylmethyl, carbethoxymethyl, carbophenoxymethyl, benzoylmethyl and methoxymethyl. Examples of X are:-chloride, bromide, iodide, sulphate, benzene sulphonate, chromate, dichromate, thiocyanate, formate and benzoate. The Specification lists seventeen particular compounds. The salts are useful as curing catalysts for aminoplast condensates or resins.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US294027XA | 1949-06-17 | 1949-06-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB698179A true GB698179A (en) | 1953-10-07 |
Family
ID=21848815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14333/50A Expired GB698179A (en) | 1949-06-17 | 1950-06-08 | Compositions comprising acid-curing thermosetting aminoplast resins |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH294027A (en) |
FR (1) | FR1020283A (en) |
GB (1) | GB698179A (en) |
NL (1) | NL74946C (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2632312B1 (en) * | 1988-06-03 | 1992-03-27 | Norsolor Sa | NOVEL PROCESS FOR CURING AMINOPLAST RESINS |
-
0
- NL NL74946D patent/NL74946C/xx active
-
1950
- 1950-06-08 GB GB14333/50A patent/GB698179A/en not_active Expired
- 1950-06-16 FR FR1020283D patent/FR1020283A/en not_active Expired
- 1950-06-17 CH CH294027D patent/CH294027A/en unknown
Also Published As
Publication number | Publication date |
---|---|
NL74946C (en) | |
FR1020283A (en) | 1953-02-04 |
CH294027A (en) | 1953-10-31 |
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