GB692433A - Improvements in and relating to the production of artificial fibres of polymeric materials - Google Patents

Improvements in and relating to the production of artificial fibres of polymeric materials

Info

Publication number
GB692433A
GB692433A GB11896/50A GB1189650A GB692433A GB 692433 A GB692433 A GB 692433A GB 11896/50 A GB11896/50 A GB 11896/50A GB 1189650 A GB1189650 A GB 1189650A GB 692433 A GB692433 A GB 692433A
Authority
GB
United Kingdom
Prior art keywords
acid
fibres
treatment
water
polypeptide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11896/50A
Inventor
Clement Henry Bamford
William Edward Hanby
Frank Happey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel UK PLC
Original Assignee
Courtaulds PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL76193D priority Critical patent/NL76193C/xx
Application filed by Courtaulds PLC filed Critical Courtaulds PLC
Priority to GB11896/50A priority patent/GB692433A/en
Priority to US220732A priority patent/US2628886A/en
Priority to DEC4129A priority patent/DE926270C/en
Priority to FR1037034D priority patent/FR1037034A/en
Publication of GB692433A publication Critical patent/GB692433A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/68—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyaminoacids or polypeptides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/76—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polyamides (AREA)
  • Artificial Filaments (AREA)

Abstract

Fibres are produced from synthetic polypeptides, of the kind described in Specification 675,298, by extruding through a jet into a setting medium a solution of the polypeptide in benzene, methylene chloride, meta-cresol, dichloracetic acid or trichloracetic acid, whereby the fibres so formed have an a molecular configuration, and then treating the fibres in a bath comprising an aliphatic mono-carboxylic acid containing from one to six carbon atoms per molecule or a like acid containing, on the a carbon atom, a bromine atom or a phenyl or mercaptan group, so that at least part of the fibres is converted into the b -molecular configuration. The synthetic polypeptides are made by polymerizing anhydro-carboxyamino-acids of the formula <FORM:0692433/IV (a)/1> R1, R2 and R3 being hydrogen or alkyl, aryl or aralkyl groups, which may be substituted or unsubstituted. Formic, acetic, propionic, normal or iso-butyric acid, normal or iso-caproic acid or crotonic acid; a -bromo acetic, propionic, butyric or n-valeric acid; phenylacetic acid or thioglycollic acid, may be used for treating the synthetic polypeptide fibres. If desired, the extruded fibres may be stretched, e.g. in steam, before the acid treatment. The polypeptide solutions may be dry or wet spun. Specified coagulants are water, methyl alcohol, ethyl alcohol and aqueous alcohols. The treatment may be carried out at room temperature for a period of 1-3 minutes. In an example, a copolymer of dl-b -phenylalanine and dl-leucine is dissolved in trichloracetic acid containing 10 per cent of water and the solution is extruded into water. The fibres so formed are passed through a bath of formic acid and then dried. The fibres obtained have a b -configuration and are insoluble in benzene or carbon tetrachloride. Other examples describe the production and treatment of fibres of copolymers of dl-b -phenylalanine with g -methyl-l-glutamate or with dl-leucine and g -benzyl-dl-glutamate. Specification 675,299 also is referred to.
GB11896/50A 1950-05-12 1950-05-12 Improvements in and relating to the production of artificial fibres of polymeric materials Expired GB692433A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NL76193D NL76193C (en) 1950-05-12
GB11896/50A GB692433A (en) 1950-05-12 1950-05-12 Improvements in and relating to the production of artificial fibres of polymeric materials
US220732A US2628886A (en) 1950-05-12 1951-04-12 Production of artificial fibers of polymeric materials
DEC4129A DE926270C (en) 1950-05-12 1951-04-29 Process for the production of threads from synthetic polypeptides
FR1037034D FR1037034A (en) 1950-05-12 1951-05-11 Process for manufacturing artificial fibers from polymerized materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB11896/50A GB692433A (en) 1950-05-12 1950-05-12 Improvements in and relating to the production of artificial fibres of polymeric materials

Publications (1)

Publication Number Publication Date
GB692433A true GB692433A (en) 1953-06-03

Family

ID=9994640

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11896/50A Expired GB692433A (en) 1950-05-12 1950-05-12 Improvements in and relating to the production of artificial fibres of polymeric materials

Country Status (5)

Country Link
US (1) US2628886A (en)
DE (1) DE926270C (en)
FR (1) FR1037034A (en)
GB (1) GB692433A (en)
NL (1) NL76193C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3227793A (en) * 1961-01-23 1966-01-04 Celanese Corp Spinning of a poly(polymethylene) terephthalamide
US3227792A (en) * 1960-06-07 1966-01-04 Celanese Corp Solution spinning of polyhexamethylene terephthalamide
US3387070A (en) * 1963-04-15 1968-06-04 Asahi Chemical Ind Method for producing shaped articles of water-insoluble poly-dl-alanine

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2318704A (en) * 1940-04-02 1943-05-11 Celanese Corp Production of artificial filaments, foils, and like shaped articles
US2516162A (en) * 1947-10-07 1950-07-25 Du Pont Polymeric materials

Also Published As

Publication number Publication date
DE926270C (en) 1955-04-14
US2628886A (en) 1953-02-17
FR1037034A (en) 1953-09-14
NL76193C (en)

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