GB685294A - Improved process for the chlorination of benzene and benzene derivatives - Google Patents
Improved process for the chlorination of benzene and benzene derivativesInfo
- Publication number
- GB685294A GB685294A GB13026/49A GB1302649A GB685294A GB 685294 A GB685294 A GB 685294A GB 13026/49 A GB13026/49 A GB 13026/49A GB 1302649 A GB1302649 A GB 1302649A GB 685294 A GB685294 A GB 685294A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzene
- chlorination
- hypochlorite
- improved process
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
- C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1 : 2 : 3 : 4 : 5 : 6 - Hexachlorocyclohexane is prepared by the chlorination of benzene without the need for illumination in which benzene and chlorine are contacted in a vessel in the presence of water and a hypochlorite and in which at least 50 per cent of the water is introduced in the form of ice. If desired the hypochlorite may be present initially or it may be formed in situ by the action of a small portion of the chlorine on a material selected from the group consisting of mercuric oxide, calcium carbonate, chalk, marl, sodium carbonate, and benzoyl peroxides. It is preferred to carry out the reaction at a low temperature to produce a pure product. Specifications 447,058 and 649,428 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL685294X | 1948-12-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB685294A true GB685294A (en) | 1952-12-31 |
Family
ID=19805639
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13026/49A Expired GB685294A (en) | 1948-12-20 | 1949-05-16 | Improved process for the chlorination of benzene and benzene derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB685294A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3041384A (en) * | 1958-07-26 | 1962-06-26 | Basf Ag | Production of hexachlorcyclohexane |
-
1949
- 1949-05-16 GB GB13026/49A patent/GB685294A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3041384A (en) * | 1958-07-26 | 1962-06-26 | Basf Ag | Production of hexachlorcyclohexane |
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