GB684852A - Process for the purification of lower aliphatic aldehydes - Google Patents
Process for the purification of lower aliphatic aldehydesInfo
- Publication number
- GB684852A GB684852A GB442850A GB442850A GB684852A GB 684852 A GB684852 A GB 684852A GB 442850 A GB442850 A GB 442850A GB 442850 A GB442850 A GB 442850A GB 684852 A GB684852 A GB 684852A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solvent
- ether
- solution
- formaldehyde
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aqueous solutions of aliphatic aldehydes containing from 1 to 5 carbon atoms, the aldehyde solution containing unsaturated alcohols, other odour bodies, and acids, are purified by subjecting the solutions to a liquid phase extraction treatment with a solvent selected from the group consisting of ethers and esters having the formula ROR1 and RCOOR1, respectively, in which R and R1 are alkyl radicals containing not more than 5 carbon atoms, separating the solvent from the aldehyde solution and recovering an essentially purified aldehyde solution. Specified solvents are diethyl ether, diisopropyl ether, dibutyl ether, di-isobutyl ether, ethyl acetate and butyl acetate. The process is particularly suitable for the purification of formaldehyde solutions, the preferred solvent being diisopropyl ether. The extraction treatment is preferably effected at 60 DEG to 80 DEG F. and it is preferred to use four volumes of solvent per volume of formaldehyde solution. The extraction treatment may be carried out by treating the aldehyde solution with the solvent in counter-current. Where the acid values of the aldehyde solution to be purified are low the extraction may be operated essentially for odour removal and in this case solvent ratios of 0.5 : 1 to 2 : 1 by volume are suitable. After contacting the formaldehyde solution with the solvent the raffinate may be flash distilled at 190 DEG to 210 DEG F. to recover any solvent present as an overhead product for recycle to the system. In examples: (1) an aqueous solution of formaldehyde containing a small amount of formic acid and unsaturated bodies is contacted at 70 DEG F. with diisopropyl ether (4 volumes solvent per volume of aldehyde solution) in a column, the solvent passing upwards in counter-current to the aldehyde solution. The formaldehyde solution withdrawn from the bottom of the column has a reduced acid and unsaturated body content. The formaldehyde raffinate is then flash distilled at a temperature of 206 DEG F. to yield an overhead product containing isopropyl ether and a small amount of aqueous formaldehyde solution which is separated in a separator and returned to the bottoms product from the flash still. The isopropyl ether from the separator is added to the isopropyl ether recovered at the top of the contacting column and the impure isopropyl ether fractionated to recover pure isopropyl ether which is recycled to the contacting column; (2) the procedure of (1) is repeated except that the volume ratio of isopropyl ether to formaldehyde is 1 : 1, the treatment being directed essentially for odour removal. The impure isopropyl ether from the contacting column is then purified by treatment with an aqueous solution containing sodium bicarbonate and sodium carbonate and the alkaline water wash is then subjected to flash distillation at 175 DEG to 210 DEG F. to recover the ether dissolved therein. The residual acidity of the treated aldehyde solutions may be removed or reduced by treatment with ion exchange resins. The purification of aqueous acetaldehyde solutions containing acetic acid by treatment with diisopropyl ether is also referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB442850A GB684852A (en) | 1950-02-21 | 1950-02-21 | Process for the purification of lower aliphatic aldehydes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB442850A GB684852A (en) | 1950-02-21 | 1950-02-21 | Process for the purification of lower aliphatic aldehydes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB684852A true GB684852A (en) | 1952-12-24 |
Family
ID=9777000
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB442850A Expired GB684852A (en) | 1950-02-21 | 1950-02-21 | Process for the purification of lower aliphatic aldehydes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB684852A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE953606C (en) * | 1954-04-03 | 1956-12-06 | Chemische Verwertungsgesellsch | Process for purifying oxygen-containing organic compounds |
DE1160837B (en) * | 1961-11-22 | 1964-01-09 | Ruhrchemie Ag | Process for the production of acrolein or methacrolein and by-products from the reaction products contained in the catalytic oxidation of propene or isobutene with oxygen |
-
1950
- 1950-02-21 GB GB442850A patent/GB684852A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE953606C (en) * | 1954-04-03 | 1956-12-06 | Chemische Verwertungsgesellsch | Process for purifying oxygen-containing organic compounds |
DE1160837B (en) * | 1961-11-22 | 1964-01-09 | Ruhrchemie Ag | Process for the production of acrolein or methacrolein and by-products from the reaction products contained in the catalytic oxidation of propene or isobutene with oxygen |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4100189A (en) | Recovery of acetic acid from dilute aqueous solutions thereof | |
GB673768A (en) | Purification of crude aliphatic alcohols by distillation | |
JPH06287162A (en) | Production of acrylic ester or methacrylic ester | |
US2470222A (en) | Distillation of alcohols containing impurities less soluble in water | |
US2293724A (en) | Method of treating waste material of wood sugar processes or the like | |
US4935555A (en) | Purification of neopentyl glycol | |
US3076854A (en) | Recovery of trimethylolpropane | |
GB684852A (en) | Process for the purification of lower aliphatic aldehydes | |
US2178349A (en) | Method for the production of terpineol from pinene | |
US2494133A (en) | Method of neutralizing and completely removing salts before distilling crude high-boiling esters | |
US2381032A (en) | Separation of organic compounds | |
US3158649A (en) | Process for extracting organic acids produced by fermentation | |
US3437566A (en) | Organic acid separation by azeotropic distillation with toluene and subsequent chemical washing of toluene | |
US2204616A (en) | Process for dehydration of acetic acid and other lower fatty acids | |
US2545889A (en) | Recovery of oxygenated compounds | |
GB636600A (en) | Method of preparing cyanamide and polymers thereof | |
GB826801A (en) | Recovery of sucrose esters | |
US2114825A (en) | Process for partial dehydration of acetic acid and other lower fatty acids | |
GB1495481A (en) | Process for the obtaining of isobutylene of high purity | |
US3082259A (en) | Process for obtaining pure trimethylopropane | |
GB816208A (en) | Trimethylolpropane | |
US2826615A (en) | Process for producing alcohols by acid treating olefinic mineral oils | |
US1495891A (en) | Process for making fat-splitting sulphonic acids and product | |
US4065506A (en) | Continuous process for refining glyoxal | |
US2041668A (en) | Process for dehydration of acetic acid and other lower fatty acids |