GB679871A - Improvements in and relating to lubricating compositions - Google Patents

Improvements in and relating to lubricating compositions

Info

Publication number
GB679871A
GB679871A GB3980/50A GB398050A GB679871A GB 679871 A GB679871 A GB 679871A GB 3980/50 A GB3980/50 A GB 3980/50A GB 398050 A GB398050 A GB 398050A GB 679871 A GB679871 A GB 679871A
Authority
GB
United Kingdom
Prior art keywords
lubricating oil
per cent
mineral lubricating
weight
agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3980/50A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Refining and Marketing Co Ltd
Original Assignee
Shell Refining and Marketing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Refining and Marketing Co Ltd filed Critical Shell Refining and Marketing Co Ltd
Priority to GB3980/50A priority Critical patent/GB679871A/en
Priority to US210788A priority patent/US2653910A/en
Publication of GB679871A publication Critical patent/GB679871A/en
Expired legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
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    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
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    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
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    • C10M2201/10Compounds containing silicon
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    • C10M2201/103Clays; Mica; Zeolites
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    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10M2223/04Phosphate esters
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/042Metal salts thereof
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    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
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    • C10M2227/02Esters of silicic acids
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    • C10M2229/02Unspecified siloxanes; Silicones
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    • C10M2229/04Siloxanes with specific structure
    • C10M2229/05Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
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    • C10N2010/00Metal present as such or in compounds
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    • C10N2040/02Bearings
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)

Abstract

A lubricating composition comprises a mineral lubricating oil or grease and a minor proportion of one or more trithiones free from water-solubilizing substituents, of general formula <FORM:0679871/III/1> where R and R1 represent hydrogen, or aliphatic, cyclo-aliphatic or aromatic radicles or may together form a ring structure. R and R1 may be substituted by halogen atoms, alkoxy, aryloxy, keto, carbalkoxy, nitro or acylamino groups, and free from carboxy or sulphonic acid groups. Suitable compounds include 2- or 3-phenyl trithione, 3-(41methoxyphenyl) trithione, and benztrithione (also known as 2.3-dithiosulphindene). They may be used as solutions or suspensions in mineral lubricating oil (solubilizing agents being added if necessary) in amounts from 0.05-5.0 per cent by weight of the mineral lubricating oil or grease. Generally less than 1.0 per cent is sufficient, and preferably between 0.2-0.6 per cent by weight of the lubricating oil or grease. The final composition possesses extreme pressure properties. The mineral lubricating oil may be derived from paraffinic or asphaltic residues and refined by any known process such as solvent extraction, solvent de-waxing, or treatment with sulphuric acid and/or activated earth. Other additives such as pour point depressors (alkylated naphthalenes), thickeners (soaps and inorganic gels), oxidation inhibitors (2, 4 dimethyl-6-tertiary-butyl phenol and 2, 6 ditertiary butyl-4-methyl phenol), sludge dispersers (oil soluble metal soaps and oil-soluble metal phenates), anti-corrosion agents (polycarboxylic acids formed by condensing alkenes with maleic acid), viscosity index improvers (polyisobutylenes and methyl methacrylate polymers), foam preventing agents (polymeric organic silicones and metasilicates), and anti-ring sticking agents (metal soaps of alkylated salicylic acids) may be present. Also other extreme pressure additives such as chlorinated paraffin wax, calcium dichlorostearate, tricresylphosphate, bichlorophenylphosphate and 2, 4-di(trichloromethyl)-6-nitro-1, 3-benzodioxane may be added. Examples describe the performance of compositions comprising 0.26 per cent by weight of 3-(41-methoxyphenyl) trithione (equivalent to 0.1 per cent sulphur increment by weight), and conventional additives added to a high viscosity index solvent refined mineral lubricating oil.
GB3980/50A 1950-02-16 1950-02-16 Improvements in and relating to lubricating compositions Expired GB679871A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB3980/50A GB679871A (en) 1950-02-16 1950-02-16 Improvements in and relating to lubricating compositions
US210788A US2653910A (en) 1950-02-16 1951-02-13 Extreme pressure lubricants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3980/50A GB679871A (en) 1950-02-16 1950-02-16 Improvements in and relating to lubricating compositions

Publications (1)

Publication Number Publication Date
GB679871A true GB679871A (en) 1952-09-24

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB3980/50A Expired GB679871A (en) 1950-02-16 1950-02-16 Improvements in and relating to lubricating compositions

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US (1) US2653910A (en)
GB (1) GB679871A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3968123A (en) * 1973-06-19 1976-07-06 Ciba-Geigy Corporation (3-Thioxo-1,2-dithiol-4-yl) substituted triaryl phosphates and thiophosphates

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816075A (en) * 1954-06-01 1957-12-10 Standard Oil Co Lubricating oil compositions
US2897153A (en) * 1955-01-11 1959-07-28 Standard Oil Co Lubricant compositions containing thiopyrones
US2995569A (en) * 1957-05-02 1961-08-08 Socony Mobil Oil Co Inc Process for preparation of alkyl-1, 2-dithiole-3-thiones
US3120543A (en) * 1960-11-18 1964-02-04 American Cyanamid Co Intermediates and process for dithiolium compounds
US3225062A (en) * 1963-02-11 1965-12-21 American Cyanamid Co Process for 1,2-dithiole-3-thiones
US3345380A (en) * 1965-03-29 1967-10-03 Shell Oil Co Trithione production
US3364232A (en) * 1966-01-05 1968-01-16 Chevron Res Sulfur containing pseudoaromatic detergents
GB1419481A (en) * 1973-06-20 1975-12-31 Ciba Geigy Ag Dithiole derivatives useful as additives for lubricating oils and other organic materials
FR2300793A1 (en) * 1975-02-17 1976-09-10 Orogil NEW LUBRICATING COMPOSITIONS
US5962380A (en) * 1995-06-06 1999-10-05 Chevron Chemical Company Llc Fluorocarbon elastomer compatibility improving agent having wear inhibition effect
US5641735A (en) * 1995-06-06 1997-06-24 Chevron Chemical Company Bis(thio)ethylene ashless wear inhibitors and lubricating oils
US5807814A (en) * 1996-07-05 1998-09-15 Chevron Chemical Company Bis(thio)ethylene ashless wear inhibitors and lubricating oils and greases
CN115651748B (en) * 2022-09-23 2023-05-26 东莞市颖兴金属表面处理材料有限公司 Saponified lubricant and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2292456A (en) * 1938-02-23 1942-08-11 Continental Oil Co Lubricating oil
US2535705A (en) * 1947-03-07 1950-12-26 Gulf Research Development Co 4-neopentyl-1,2-dithia-4-cyclopentene-3-thione and 4-methyl-5-tertiary-butyl-1,2-dithia-4-cyclopentene-3-thione

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3968123A (en) * 1973-06-19 1976-07-06 Ciba-Geigy Corporation (3-Thioxo-1,2-dithiol-4-yl) substituted triaryl phosphates and thiophosphates

Also Published As

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US2653910A (en) 1953-09-29

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