GB667659A - Improvements in production of nickel - Google Patents
Improvements in production of nickelInfo
- Publication number
- GB667659A GB667659A GB1068950A GB1068950A GB667659A GB 667659 A GB667659 A GB 667659A GB 1068950 A GB1068950 A GB 1068950A GB 1068950 A GB1068950 A GB 1068950A GB 667659 A GB667659 A GB 667659A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nickel
- line
- electrolyte
- cobalt
- passed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
In a method of refining nickel electrolytically with a sulphate-chloride electrolyte, in which metals such as iron, copper, lead, arsenic and cobalt present in solution are removed and nickel cathodes are obtained from the purified electrolyte, a portion of the purified electrolyte is withdrawn from the main stream and is subjected to electrolysis to liberate chromium and sulphuric acid, the chrome being used to precipitate the cobalt with or without one or more of the other metals in the main stream of electrolyte, and the acid being used to extract nickel from at least one of the metal precipitates, the resulting solution of nickel sulphate being returned to the system, so that the composition of the main stream <PICT:0667659/III/1> of electrolyte is maintained constant as regards the chlorides and sulphates. In the flow sheet shown, there are three cells 10, 12, 14 provided with cathode starting sheets in cathode compartments having canvas filtering bags, and with impure nickel anodes in the anode compartments. The electrolyte is a mixed sulphate-chloride electrolyte which is conducted through a line 16 to a tank 18 where it is subjected to aeration whereby iron and some of the other metals are precipitated. The resulting slurry is passed through line 20 to a filter press 22. The filter cake containing the precipitated iron is treated in a tank 26 with mineral acid to convert nickel present (and also some iron and other metals) to a soluble salt of the acid. The solution thus formed is conducted through a line 28 to line 16, providing an opportunity for re-treating any iron in the solution. The filtrate from the filter press 22 passes through a line 30 to a copper-concentration tank 32 where the electrolyte is treated with gas-reduced nickel powder causing copper to be thrown out of solution as cement-copper. The slurry is passed to a filter press 36, the filter cake being withdrawn and treated to remove the copper. The filtrate is passed through a line 38 into a cobalt precipitation tank 40, where the electrolyte is treated with chlorine to oxidize and hence precipitate the cobalt and any lead and arsenic not yet removed. Some nickel is also precipitated. The slurry is passed to a filter press 44, the filter cake being treated with mineral acid in a nickel-extraction tank 46. The nickel in the form of a soluble salt is passed back to the system through a line 48. Cobalt residues in the tank 46 are recovered. The filtrate from the filter press 44 is divided into two portions, one portion passing into the cathode compartments of the cells 10, 12, 14 when it is subjected to electrolysis to form nickel cathodes substantially free from cobalt. The other portion of the filtrate passes through a line 58 to an electrolytic cell 60 where chlorine and sulphuric acid are formed, and nickel is deposited on cathode starting sheets. Chlorine from the cell is passed through line 62 to the iron-precipitation tank 18 and the cobalt-precipitation tank 40. Sulphuric acid from the cell 60 is passed through line 68 to nickel-extraction tanks 26 and 46 and to copper-concentration tank 32. Some of the chlorine produced in the cell 60 may be combined with hydrogen to form hydrochloric acid and re-introduced into the system, for example, to extract nickel from at least one of the metal impurities.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US667659XA | 1949-05-04 | 1949-05-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB667659A true GB667659A (en) | 1952-03-05 |
Family
ID=22071557
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1068950A Expired GB667659A (en) | 1949-05-04 | 1950-05-01 | Improvements in production of nickel |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB667659A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2839461A (en) * | 1953-10-29 | 1958-06-17 | Internat Nickel Co Inc | Electrolytic recovery of nickel |
US3085054A (en) * | 1960-02-25 | 1963-04-09 | Falconbridge Nickel Mines Ltd | Recovery of nickel |
-
1950
- 1950-05-01 GB GB1068950A patent/GB667659A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2839461A (en) * | 1953-10-29 | 1958-06-17 | Internat Nickel Co Inc | Electrolytic recovery of nickel |
US3085054A (en) * | 1960-02-25 | 1963-04-09 | Falconbridge Nickel Mines Ltd | Recovery of nickel |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2020232505A1 (en) | Production of manganese sulphate | |
US1980381A (en) | Method of making ductile electrolytic iron from sulphide ores | |
CN105274352B (en) | A kind of method that copper cobalt manganese is separated in the manganese cobalt calcium zinc mixture from copper carbonate | |
CN111471862B (en) | Treatment method of laterite-nickel ore pickle liquor | |
CN107815540A (en) | A kind of method of hydrometallurgy metal nickel cobalt and its salt product | |
US3677918A (en) | Method for directly electrochemically extracting gallium from a circulating aluminate solution in the bayer process by eliminating impurities | |
US3933976A (en) | Nickel-cobalt separation | |
US3900385A (en) | Method for continuous production of electrolytic manganese dioxide | |
US2119560A (en) | Electrolytic process for the extraction of metallic manganese | |
CN109536992B (en) | Method for purifying copper electrolyte by two-removing and two-accumulating | |
US2507476A (en) | Electrodeposition of chromium | |
GB667659A (en) | Improvements in production of nickel | |
US3630669A (en) | Process for removing impurities in the liquid of zinc refining by wet method | |
US1887037A (en) | Process of refining nickel bearing materials | |
US2766197A (en) | Production of manganese | |
Lloyd et al. | Pilot‐Plant Production of Electrolytic Chromium | |
US2771413A (en) | Electrodeposition of chromium | |
NO770818L (en) | PROCEDURES FOR ZINK EXTRACTION. | |
CA1123575A (en) | Purification of aqueous solution of potassium chloride | |
US2348742A (en) | Magnesium control in manganese electrowinning | |
US3334034A (en) | Electrolytic method for the recovery of nickel and cobalt | |
US2580681A (en) | Method of treating the electrolyte in the electrodeposition of iron | |
US1596363A (en) | Manufacture of oxide pigments | |
US3162587A (en) | Electrolytic precipitation of metal sulphides from leach slurries | |
JPS5985879A (en) | Electric refinement |