GB627549A - Improvements in and relating to the manufacture and use of insecticidal halogen-containing organic compounds and to the treatment of materials therewith - Google Patents
Improvements in and relating to the manufacture and use of insecticidal halogen-containing organic compounds and to the treatment of materials therewithInfo
- Publication number
- GB627549A GB627549A GB1256545A GB1256545A GB627549A GB 627549 A GB627549 A GB 627549A GB 1256545 A GB1256545 A GB 1256545A GB 1256545 A GB1256545 A GB 1256545A GB 627549 A GB627549 A GB 627549A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenyl
- tetrachloroethane
- compounds
- prepared
- chlorophenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/16—Preparation of halogenated hydrocarbons by replacement by halogens of hydroxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Compounds of the general formula <FORM:0627549/IV (b)/1> wherein R is a substituted or unsubstituted phenyl radicle and the X's are either three chlorine or three bromine atoms are obtained by treating the correspondingly substituted carbinol with phosphorus pentachloride. Substituents instanced for the phenyl radicle are halogens, nitro and cyano. The compounds are insecticides and for their uses (see Groups VI and VIII). In examples: (1) a -(p-chloro-phenyl); (2) a -(p-fluorophenyl)-; (3) a -phenyl-; (5) a -(p-tolyl)-, and (5) a -(p-anisyl)-a : b : b : b -tetrachloroethane and (4) a -phenyl-a -chloro-b : b : b -tribromoethane are prepared by treating the correspondingly substituted a -phenyl - a - hydroxy - b : b : b - trihaloethane in ethereal suspension with phosphorus pentachloride in ether at temperatures below 25 DEG C. Specifications 547,871, 547,874, 618,858 and 618,950, [both in Group VI], are referred to.ALSO:Insecticidal compositions, containing as an ingredient a compound of the general formula <FORM:0627549/VI/1> wherein R is a substituted or unsubstituted phenyl radicle and the X's are either three chlorine or three bromine atoms, are described. For the preparation of these compounds (see Group IV(b). The compounds may be used in the solid form admixed with such diluents as cork, wood flour, chalk, bentonite, kieselguhr, bole or talc, or in liquid solutions with e.g. hydrocarbon oils boiling within the kerosene range or in liquids boiling below room temperature, or in aqueous dispersions or emulsions. Other fungicides, bactericides, insecticides with spreaders and stickers or crytallization preventing compounds may be present. The compounds may be used in fumigants, paints, furniture waxes and creams and in soaps or other detergent or toilet or cosmetic preparations. In examples the following compositions are prepared: (7) talcum powder and a-(p-chlorophenyl)-a : b : b : b -tetrachlorethane, (8) pumicestone, charcoal or kieselguhr with a-phenyl-a : b : b : b -tetrachloroethane, (9) bole and a-(p-fluorophenyl)-a : b : b : b -tetrachlorethane, (10) magnesia with a-phenyl-a-chloro-b : b : b -tribromoethane and (14) a-phenyl-a : b : b : b -tetrachloroethane with sulphur, talcum, chalk and basic copper acetate; in (11) a 1 per cent solution of a-(p-anisyl)-a : b : b : b -tetrachloroethane is prepared in kerosene, and aqueous emulsions or dispersions or pastes for dilution with water containing conventional emulsifying agents are prepared from a-(p-tolyl)-a : b : b : b -tetrachloroethane and (12) bentonite and (15) chalk, (16), (17), (19) and (20) a-(p-chlorophenyl) - a b : b : b -tetrachloroethane and methyl cyclohexanol with such solvents as toluene, chloroform, butyl acetate or acetone, and (18) a-(p-chlorophenyl)-a : b : b : b -tetrachloroethane and toluene, in (21) a fumigant cartridge is prepared containing a(p-chlorophenyl-a : b : b : b -tetrachloroethane and in (13) an aerosol is prepared from the same compound dissolved in cyclohexanone, lubricating oil, sesame oil and difluorodichloromethane. Specifications 547,871, 547,874, 618,858 and 618,950 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1256545A GB627549A (en) | 1945-05-18 | 1945-05-18 | Improvements in and relating to the manufacture and use of insecticidal halogen-containing organic compounds and to the treatment of materials therewith |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1256545A GB627549A (en) | 1945-05-18 | 1945-05-18 | Improvements in and relating to the manufacture and use of insecticidal halogen-containing organic compounds and to the treatment of materials therewith |
Publications (1)
Publication Number | Publication Date |
---|---|
GB627549A true GB627549A (en) | 1949-08-11 |
Family
ID=10006992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1256545A Expired GB627549A (en) | 1945-05-18 | 1945-05-18 | Improvements in and relating to the manufacture and use of insecticidal halogen-containing organic compounds and to the treatment of materials therewith |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB627549A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2228934A (en) * | 1989-03-04 | 1990-09-12 | British Petroleum Co Plc | 2,3,5,6-Tetrakis(chloromethyl)-4-methyl-chlorobenzene |
-
1945
- 1945-05-18 GB GB1256545A patent/GB627549A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2228934A (en) * | 1989-03-04 | 1990-09-12 | British Petroleum Co Plc | 2,3,5,6-Tetrakis(chloromethyl)-4-methyl-chlorobenzene |
GB2228934B (en) * | 1989-03-04 | 1992-05-13 | British Petroleum Co Plc | Chloromethyl benzenes |
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