GB622999A - Improvements relating to the production of high quality aviation fuels - Google Patents
Improvements relating to the production of high quality aviation fuelsInfo
- Publication number
- GB622999A GB622999A GB1602245A GB1602245A GB622999A GB 622999 A GB622999 A GB 622999A GB 1602245 A GB1602245 A GB 1602245A GB 1602245 A GB1602245 A GB 1602245A GB 622999 A GB622999 A GB 622999A
- Authority
- GB
- United Kingdom
- Prior art keywords
- isopentane
- produced
- cut
- alkylate
- tetraethyl lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aviation fuel is obtained by fractionating an alkylate produced by condensing isobutane or isopentane with one or more of the lower olefines, except ethylene, in the presence of an alkylation catalyst, such as concentrated sulphuric acid or hydrofluoric acid, and blending one or more of the fractions boiling within the ranges 45-69 DEG , 95-106 DEG and 106-120 DEG C. with at least one diluent consisting of a hydrocarbon fuel boiling in the aviation fuel range so that the resulting blend contains not more than 30 per cent of diluent and about 10-40 per cent of components boiling below 70 DEG C. Diluents mentioned are (a) paraffinic or naphthenic straight-run gasoline, (b) isoheptane, isohexane or isopentane, (c) catalytically cracked gasoline produced by the Houdry or the fluid catalyst process, (d) hydroformed naphtha, (e) benzene, toluene, mixed xylenes or cumene, (f) alkylate produced by the interaction of isobutane and butenes or pentenes in the presence of a catalyst, (g) alkylate (mainly diisopropyl) produced by the interaction of isobutane and ethylene by thermal or catalytic means, (h) hydrocodimer produced by catalytic dimerisation of butylenes and hydrogenation of the dimer, (i) hot acid iso-octane produced by polymerization of butylenes in the presence of sulphuric acid followed by hydrogenation of the iso-octenes thus formed and (j) neohexane. The blend should not contain more than 25 per cent of isopentane, which may be an alkylate fraction or more than 15 per cent of aromatics which may be added in the form of an aromatic extract obtained by the solvent extraction of a petroleum distillate with a polar solvent. Tetraethyl lead may be added to the aviation fuel. In the examples, aviation fuel is produced by blending (1) the 45-69 DEG , 95-106 DEG and 106-120 DEG C. cuts with (a) cumene, (b) cyclopentane, neohexane, diisopropyl and isopentane, (c) toluene, isopentane and tetraethyl lead, or (d) cyclopentane, neohexane, diisopropyl, xylenes, isopentane and tetraethyl lead; (2) the 106-120 DEG C. cut with triptane and (3) the 95-120 DEG C. cut with (a) toluene, cyclopentane, isohexane, isopentane and tetraethyl lead, (b) toluene, neohexane, isopentane and tetraethyl lead, (c) aromatic extract, cyclopentane, neohexane, diisopropyl, isopentane and tetraethyl lead or (d) aromatic extract, isopentane and tetraethyl lead. The 95-120 DEG C. cut of examples (3) (c) and (3) (d) is obtained from alkylate produced by condensing isobutane with C4 olefins in the presence of sulphuric acid while the 106-120 DEG C. cut of example (2) is obtained from alkylate produced by condensing an impure isobutane containing small amounts of propane and n-butane with an olefin mixture containing propylene, isobutene, normal butenes, butadiene, pentenes, propane, isobutene, normal butane and pentanes in the presence of sulphuric acid. The 45-69 DEG C. cut of the latter alkylate consists of diisopropyl and 2-methyl pentane, the 95-106 DEG cut of 2,2,4-trimethyl pentane and the 106-120 DEG C. cut of 2,3,3-, 2,3,4- and 2,2,3-trimethyl pentanes and some dimethyl hexanes. For comparison purposes, blends of these cuts without the addition of diluents are described. Specification 479,345 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1602245A GB622999A (en) | 1945-06-22 | 1945-06-22 | Improvements relating to the production of high quality aviation fuels |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1602245A GB622999A (en) | 1945-06-22 | 1945-06-22 | Improvements relating to the production of high quality aviation fuels |
Publications (1)
Publication Number | Publication Date |
---|---|
GB622999A true GB622999A (en) | 1949-05-11 |
Family
ID=10069749
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1602245A Expired GB622999A (en) | 1945-06-22 | 1945-06-22 | Improvements relating to the production of high quality aviation fuels |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB622999A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008072039A1 (en) * | 2006-12-12 | 2008-06-19 | Rosario Rocco Tulino | Tetra-component additive for the octaning and oxygenating reformulation of ecological petrol for motor-traction |
-
1945
- 1945-06-22 GB GB1602245A patent/GB622999A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008072039A1 (en) * | 2006-12-12 | 2008-06-19 | Rosario Rocco Tulino | Tetra-component additive for the octaning and oxygenating reformulation of ecological petrol for motor-traction |
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