GB611700A - Improved manufacture of organo-siloxanes - Google Patents
Improved manufacture of organo-siloxanesInfo
- Publication number
- GB611700A GB611700A GB14108/46A GB1410846A GB611700A GB 611700 A GB611700 A GB 611700A GB 14108/46 A GB14108/46 A GB 14108/46A GB 1410846 A GB1410846 A GB 1410846A GB 611700 A GB611700 A GB 611700A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oc2h5
- radicals
- mixture
- heating
- dioxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 125000005375 organosiloxane group Chemical group 0.000 title 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 8
- -1 hydrocarbon radicals Chemical class 0.000 abstract 6
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 5
- 239000000047 product Substances 0.000 abstract 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- 238000010438 heat treatment Methods 0.000 abstract 4
- BUMGIEFFCMBQDG-UHFFFAOYSA-N dichlorosilicon Chemical compound Cl[Si]Cl BUMGIEFFCMBQDG-UHFFFAOYSA-N 0.000 abstract 3
- 235000019441 ethanol Nutrition 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 230000007062 hydrolysis Effects 0.000 abstract 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract 2
- 150000004756 silanes Chemical class 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000005037 alkyl phenyl group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 125000005394 methallyl group Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 125000001712 tetrahydronaphthyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 abstract 1
- 229920005992 thermoplastic resin Polymers 0.000 abstract 1
- 238000010792 warming Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Silicon Polymers (AREA)
Abstract
A process of preparing new synthetic products from silanes having two mono-valent hydrocarbon radicals, which need not be the same, attached to each silicon atom through carbon-silicon linkages, the remaining valences of the silicon atoms being satisfied by hydrolysable radicals which are attached to the carbon atoms through other than carbon-silicon linkages is characterized by co-hydrolysing a mixture of at least two of said silanes which differ with respect to the chemical composition of that portion of their molecules exclusive of said hydrolysable radicals and condensing the hydrolysis product to obtain a copolymer thereof. The hydrocarbon radicals may be alkyl radicals; alicyclic radicals such as phenyl and mono- and poly-alkyl phenyls; naphthyl and poly-alkyl naphthyl; tetrahydronaphthyl and anthracyl; aralkyl radicals such as benzyl and phenylethyl; and alkenyl such as methallyl and allyl; and may be substituted by inorganic constituents such as halogen. Where all the hydrolysable radicals are halogen, dioxane is the preferred solvent, and where all are alkoxy, dilute acid or alkali is used. The products in some cases are hardened on heating. In examples: (1) aqueous dioxane is added to a mixture of (C6H5), SiCl2 and (C6H5) (C2H5)SiCl2. The liquid product hardens on heating; (2) a dioxane solution of (C6H5)(C2H5)S SiCl2 and (CH3)2Si(OC2H5)2 is hydrolysed by warming with aqueous dioxane; (3) (CH3)2Si(OC2H5) and (C6H5)2SiCl2 are hydrolysed and inter-condensed in dioxane solution; (4) a mixture of (C6H5.CH2)2SiCl2 and (CH3)2Si(OC2H5)2 is hydrolysed with 95 per cent ethyl alcohol followed by addition of water. The oily product forms a thermoplastic resin on heating; (5) a product prepared from (C6H5.CH2) (CH3) Si(OC2H5)2 and ( (CH3)2Si(OC2H5)2 by hydrolysis with alcohol and HCl is a viscous oil forming a waxy resin on heating; (6) a viscous liquid is obtained by hydrolysing with alcohol and HCl a mixture of (C6H5)(CH3) Si(OC2H5)2 and (CH3)2 Si(OC2H5)2.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US611700XA | 1942-02-26 | 1942-02-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB611700A true GB611700A (en) | 1948-11-02 |
Family
ID=22034089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14108/46A Expired GB611700A (en) | 1942-02-26 | 1946-05-09 | Improved manufacture of organo-siloxanes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB611700A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014112584A1 (en) * | 2013-01-21 | 2014-07-24 | セントラル硝子株式会社 | Silicon compound containing hexafluoroisopropanol groups, method for producing same, and polymer compound obtained by polymerizing same |
-
1946
- 1946-05-09 GB GB14108/46A patent/GB611700A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014112584A1 (en) * | 2013-01-21 | 2014-07-24 | セントラル硝子株式会社 | Silicon compound containing hexafluoroisopropanol groups, method for producing same, and polymer compound obtained by polymerizing same |
| JP2014156461A (en) * | 2013-01-21 | 2014-08-28 | Central Glass Co Ltd | Silicon compound containing hexafluoroisopropanol groups, method for producing the same, and polymer compound obtained by polymerizing the same |
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