GB603175A - Improvements in or relating to manufacture of aliphatic acids - Google Patents
Improvements in or relating to manufacture of aliphatic acidsInfo
- Publication number
- GB603175A GB603175A GB21734/45A GB2173445A GB603175A GB 603175 A GB603175 A GB 603175A GB 21734/45 A GB21734/45 A GB 21734/45A GB 2173445 A GB2173445 A GB 2173445A GB 603175 A GB603175 A GB 603175A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- fed
- mixture
- acetaldehyde
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
In the manufacture of aliphatic acids by the catalytic oxidation of the corresponding aldehydes in the liquid phase, the aldehyde and a gas containing less oxygen than air are fed to a mixture containing the aldehyde, the acid and a catalyst, the gas being fed at such a rate that acid is carried away from the mixture substantially as fast as it is formed, and the aldehyde being fed at such a rate that the volume of the mixture remains substantially constant. The gas may consist of air and the residual gases of the process, and these may be fed separately into the reaction mixture. In the plant shown for the production of acetic acid, air and acetaldehyde are fed through pipes 4, 5 to a vessel 1 containing acetic acid, acetaldehyde and manganese acetate, and the gaseous and vaporous reaction products are cooled in a condenser 7. The gases separated in a separator 10 are returned in part by blower 8 and pipe 9 to the vessel 1, and the condensate from the separator is passed by pipe 11 to a column 12 in which acetaldehyde is separated and returned to the vessel 1 by pipe 17. The residue of aqueous acid is passed from column 12 to column 25, in which anhydrous acid is obtained by azeotropic distillation in the presence of an entrainer such as ethyl acetate. A similar plant is described for the production of propionic acid from a mixture containing propionaldehyde, propionic acid and manganese propionate, but in this case anhydrous propionic acid is separated directly from the condensed reaction products as a distillation residue in a two-stage distillation proces. <PICT:0603175/III/1>ALSO:<PICT:0603175/IV(b)/1> In the manufacture of aliphatic acids by the catalytic oxidation of the corresponding aldehydes in the liquid phase, the aldehyde and a gas containing less oxygen than air are fed to a mixture containing the aldehyde, the acid and a catalyst, the gas being fed at such a rate that acid is carried away from the mixture substantially as fast as it is formed, and the aldehyde being fed at such a rate that the volume of the mixture remains substantially constant. The gas may consist of air and the residual gases of the process, and these may be fed separately into the reaction mixture. The reaction may be effected at 30-60 DEG C. and any convenient pressure. In the plant shown for the production of acetic acid, air and acetaldehyde are fed through pipes 4, 5 to a vessel 1 containing acetic acid, acetaldehyde and manganese acetate, and the gaseous and vaporous reaction products are cooled in a condenser 7. The gases separated in a separator 10 are returned in part by blower 8 and pipe 9 to the vessel 1, and the condensate from the separator is passed by pipe 11 to a column 12 in which acetaldehyde is separated and returned to the vessel 1 by pipe 17. The residue of aqueous acid is passed from column 12 to column 25, in which anhydrous acid is obtained by azeotropic distillation in the presence of an entrainer such as ethyl acetate. A similar plant is described for the production of propionic acid from a mixture containing propionaldehyde, propionic acid and manganese propionate, but in this case anhydrous propionic acid is separated directly from the condensed reaction products as a distillation residue in a two-stage distillation process.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR603175X | 1940-03-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB603175A true GB603175A (en) | 1948-06-10 |
Family
ID=8972492
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21734/45A Expired GB603175A (en) | 1940-03-23 | 1945-08-24 | Improvements in or relating to manufacture of aliphatic acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB603175A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992021642A1 (en) * | 1991-05-29 | 1992-12-10 | Eastman Kodak Company | Recovery of acetyl values from ethylidene diacetate |
-
1945
- 1945-08-24 GB GB21734/45A patent/GB603175A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992021642A1 (en) * | 1991-05-29 | 1992-12-10 | Eastman Kodak Company | Recovery of acetyl values from ethylidene diacetate |
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