GB598532A - Improvements in or relating to apparatus for conducting reactions in liquid phase - Google Patents
Improvements in or relating to apparatus for conducting reactions in liquid phaseInfo
- Publication number
- GB598532A GB598532A GB9764/43A GB976443A GB598532A GB 598532 A GB598532 A GB 598532A GB 9764/43 A GB9764/43 A GB 9764/43A GB 976443 A GB976443 A GB 976443A GB 598532 A GB598532 A GB 598532A
- Authority
- GB
- United Kingdom
- Prior art keywords
- melamine
- tank
- vessel
- pump
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
- B01J3/042—Pressure vessels, e.g. autoclaves in the form of a tube
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00085—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/0009—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Apparatus for conducting chemical reactions under pressure in the liquid phase which reactions result in the production of a solid reaction product which comprises, connected together in the following sequence, a closed vessel provided with a pump for circulating liquid therethrough and means for admitting solid thereinto, a second pump for forcing liquid from the closed vessel and at the desired pressure through a closed reaction zone having associated means for maintaining the zone at a predetermined temperature and temperatures, heat exchange means for cooling the liquid, an enclosed filter for separating the solid reaction product from the attendant liquor, a conduit for returning the liquor to the closed vessel, and a reducing valve between the closed reaction zone and the return conduit. The apparatus may be employed in carrying out reactions in liquid ammonia, liquid sulphur dioxide or liquid carbon dioxide. As employed in the production of melamine by heating dicyandiamide dissolved in liquid ammonia, dicyandiamide is introduced into a vessel 2 through a cover 20, and after closing the cover and setting the valves, mother liquor or ammonia is circulated through the vessel from mother liquor tank 1 by a pump 46. When the solution reaches the required strength, by manipulating the valves the solution is pumped into the mother liquor tank and from thence to a storage tank 3. The solution is then withdrawn by a high pressure pump 4 and forced through steam-jacketed stainless-steel reaction tubes 6 heated to a temperature of 110-160 DEG F. The liquor is discharged into a water-cooler auto <PICT:0598532/III/1> clave 7 through a pressure reducing valve 70. The melamine crystals are removed by one or other of the alternately employed filters 8, 9, the mother liquor being returned through a line 14 to the tank 1. The melamine in the filter not in the circuit is washed with liquid ammonia, and discharged from the filter into water in a tank 120. After washing with water, the melamine slurry is forced by a pump 123 into a filter press 127. Deposition of melamine in the reaction tubes 6 brought about by a failure of the valve 70 to close and consequent reduction in pressure is prevented by the provision of a vessel 80 containing liquid ammonia under pressure and connected to the tubes 6 by a line 83.ALSO:In the production of melamine by heating dicyandiamide dissolved in liquid ammonia, the dicyandiamide is introduced into a vessel 2 through a cover 20, and after closing the cover and setting the valves mother liquor or ammonia is circulated through the vessel from a mother liquor tank 1 by a pump 46. When the solution reaches the required strength, by manipulating the valves the solution is pumped into the mother liquor tank and from thence to a storage tank 3. The solution is then withdrawn by a high pressure pump 4 and forced through steam-jacketed stainless-steel reaction tubes 6 heated to a temperature of 110-116 DEG C. The liquor is discharged into a water-cooled <PICT:0598532/IV/1> autoclave 7 through a pressure reducing valve 70. The melamine crystals are removed by one or other of the alternately employed filters 8, 9, the mother liquor being returned through a line 14 to the tank 1. The melamine in the filter not in the circuit is washed with liquid ammonia and discharged from the filter into water in a tank 120. After washing with water, the melamine slurry is forced by a pump 123 into a filter press 127. Deposition of melamine in the reaction tubes 6 brought about by a failure of the valve 70 to close and consequent reduction in pressure is prevented by the provision of a vessel 80 containing liquid ammonia under pressure and connected to the tubes 6 by a line 83. Such apparatus may also be used in the manufacture of guanidine nitrate by heating ammonium nitrate with dicyandiamide o cyanamide in water or aqueous ammonia.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US598532XA | 1942-06-06 | 1942-06-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB598532A true GB598532A (en) | 1948-02-20 |
Family
ID=22025693
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9764/43A Expired GB598532A (en) | 1942-06-06 | 1943-06-17 | Improvements in or relating to apparatus for conducting reactions in liquid phase |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB598532A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107089904A (en) * | 2017-06-22 | 2017-08-25 | 中山致安化工科技有限公司 | Device for producing 2, 3, 5, 6-4-methoxymethyl-tetrafluorobenzyl alcohol |
-
1943
- 1943-06-17 GB GB9764/43A patent/GB598532A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107089904A (en) * | 2017-06-22 | 2017-08-25 | 中山致安化工科技有限公司 | Device for producing 2, 3, 5, 6-4-methoxymethyl-tetrafluorobenzyl alcohol |
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