GB595290A - Adhesive compositions - Google Patents

Adhesive compositions

Info

Publication number
GB595290A
GB595290A GB16762/45A GB1676245A GB595290A GB 595290 A GB595290 A GB 595290A GB 16762/45 A GB16762/45 A GB 16762/45A GB 1676245 A GB1676245 A GB 1676245A GB 595290 A GB595290 A GB 595290A
Authority
GB
United Kingdom
Prior art keywords
vinyl
sodium
alpha
phenol
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16762/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB595290A publication Critical patent/GB595290A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J139/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Adhesives based on derivatives of such polymers
    • C09J139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C09J139/08—Homopolymers or copolymers of vinyl-pyridine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L11/00—Compositions of homopolymers or copolymers of chloroprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/16—Addition or condensation polymers of aldehydes or ketones according to C08L59/00 - C08L61/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C08L39/08—Homopolymers or copolymers of vinyl-pyridine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

An adhesive comprises a diene/vinyl pyridine copolymer and from 10-90 per cent of a phenol-aldehyde resole. Dienes specified are butadiene 1 : 3, isoprene, dimethyl butadiene and piperylene and vinyl pyridines specified are alpha and gamma vinyl pyridines and homologues thereof. The resole may be prepared from formaldehyde, paraformaldehyde, hexamethylenetetramine, acetaldehyde, butyraldehyde, chloral or furfural, and phenol, cresols, xylenols, naphthols, diphenylolmethane, diphenylolpropane, chlorophenols, tertiary butyl phenol, tertiary amyl phenol, catechol, resorcinol, phloroglucinol, orcinol, hydroquinone or quebracho extract, and in the presence of the copolymer. Butadiene or isoprene and alpha vinyl pyridine are copolymerized in bulk, solvent or aqueous dispersion, and in the latter sodium or potassium oleate, sodium resinate, formaldehyde/sodium naphthalene-sulphonate product, potassium persulphate, benzoyl peroxide, potassium ferricyanide, sodium bisulphite or hydrosulphite, lauryl, octyl or decyl mercaptans and xanthogen disulphides may be present. The copolymer may also contain other vinyl monomers such as styrene, vinylidene chloride, methyl vinyl ketone, vinyl naphthalene, methyl methacrylate, acrylonitrile or diethyl fumarate. The copolymer latex may be stabilized with a phenyl - alpha - naphthylamine/diphenylamine mixture. The adhesive may also contain water, toluene, toluene/ethyl alcohol, chlorinated hydrocarbons, sodium butyl thiocarbonate, sulphur, carbon black, and zinc oxide. Rubber and synthetic rubbers are bonded to metal or fibrous material by applying the composition and heating. Vulcanization, which may be simultaneous with the bonding is achieved with zinc oxide, channel black, phenyl alpha-and beta-naphthylamine, sulphur, stearic acid, pine tar, light process oil, mercaptobenzothiazole and N-cyclohexyl benzthiazyl sulphenamide. Specification 339,255, [Class 2 (iii)], is referred to.
GB16762/45A 1944-07-01 1945-07-02 Adhesive compositions Expired GB595290A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US595290XA 1944-07-01 1944-07-01

Publications (1)

Publication Number Publication Date
GB595290A true GB595290A (en) 1947-12-01

Family

ID=22023552

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16762/45A Expired GB595290A (en) 1944-07-01 1945-07-02 Adhesive compositions

Country Status (1)

Country Link
GB (1) GB595290A (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2619445A (en) * 1949-09-16 1952-11-25 Gen Tire & Rubber Co Rubber-to-metal adhesives and method of making same and use thereof
US2634250A (en) * 1951-03-05 1953-04-07 Us Rubber Co Composition of matter comprising a butadiene-vinyl-pyriding copolymer and a novolac
US2640042A (en) * 1951-11-06 1953-05-26 Us Rubber Co Butadiene-vinylpyridene copolymer and carbon black composition
US2652353A (en) * 1948-08-27 1953-09-15 Goodrich Co B F Adhesion of rubber to fiber
US2669553A (en) * 1949-08-19 1954-02-16 Gen Tire & Rubber Co Copolymer of a diolefine and a ketone
US2902073A (en) * 1954-03-25 1959-09-01 Goodrich Co B F Tire construction
US3031431A (en) * 1956-12-06 1962-04-24 Goodyear Tire & Rubber Adhesive composition comprising a rubber latex, a phenol, an aldehyde and a dithiocarbamate, and method of preparing same
US3060070A (en) * 1960-12-02 1962-10-23 Burlington Industries Inc Bonding of chlorosulphonated polyethylene to nylon
US3060078A (en) * 1960-12-02 1962-10-23 Burlington Industries Inc Bonding of polyethylene terephthalate fibers to certain rubbers
US3240650A (en) * 1960-11-22 1966-03-15 Burlington Industries Inc Bonding of polyethylene terephthalate fibers to natural rubber and butadiene-styrenesynthetic rubber
US3240651A (en) * 1961-07-03 1966-03-15 Burlington Industries Inc Bonding of neoprene to polyamide fibers
US3240659A (en) * 1960-11-09 1966-03-15 Burlington Industries Inc Bonding of nitrile rubbers to polyethylene terephthalate
US3240649A (en) * 1960-11-21 1966-03-15 Burlington Industries Inc Bonding neoprene to polyethylene terephthalate fibers
US4285850A (en) 1979-04-23 1981-08-25 The General Tire & Rubber Company Adhesion of polyamide or polyester cords to rubber
KR100693494B1 (en) * 2005-09-30 2007-03-14 대한민국 Phenol resin adhesive using wood tar and manufacturing method thereof

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2652353A (en) * 1948-08-27 1953-09-15 Goodrich Co B F Adhesion of rubber to fiber
US2669553A (en) * 1949-08-19 1954-02-16 Gen Tire & Rubber Co Copolymer of a diolefine and a ketone
US2619445A (en) * 1949-09-16 1952-11-25 Gen Tire & Rubber Co Rubber-to-metal adhesives and method of making same and use thereof
US2634250A (en) * 1951-03-05 1953-04-07 Us Rubber Co Composition of matter comprising a butadiene-vinyl-pyriding copolymer and a novolac
US2640042A (en) * 1951-11-06 1953-05-26 Us Rubber Co Butadiene-vinylpyridene copolymer and carbon black composition
US2902073A (en) * 1954-03-25 1959-09-01 Goodrich Co B F Tire construction
US3031431A (en) * 1956-12-06 1962-04-24 Goodyear Tire & Rubber Adhesive composition comprising a rubber latex, a phenol, an aldehyde and a dithiocarbamate, and method of preparing same
US3240659A (en) * 1960-11-09 1966-03-15 Burlington Industries Inc Bonding of nitrile rubbers to polyethylene terephthalate
US3240649A (en) * 1960-11-21 1966-03-15 Burlington Industries Inc Bonding neoprene to polyethylene terephthalate fibers
US3240650A (en) * 1960-11-22 1966-03-15 Burlington Industries Inc Bonding of polyethylene terephthalate fibers to natural rubber and butadiene-styrenesynthetic rubber
US3060070A (en) * 1960-12-02 1962-10-23 Burlington Industries Inc Bonding of chlorosulphonated polyethylene to nylon
US3060078A (en) * 1960-12-02 1962-10-23 Burlington Industries Inc Bonding of polyethylene terephthalate fibers to certain rubbers
US3240651A (en) * 1961-07-03 1966-03-15 Burlington Industries Inc Bonding of neoprene to polyamide fibers
US4285850A (en) 1979-04-23 1981-08-25 The General Tire & Rubber Company Adhesion of polyamide or polyester cords to rubber
KR100693494B1 (en) * 2005-09-30 2007-03-14 대한민국 Phenol resin adhesive using wood tar and manufacturing method thereof

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