GB592670A - Improvements in or relating to the proofing against insects of absorbent articles and to compositions therefor - Google Patents
Improvements in or relating to the proofing against insects of absorbent articles and to compositions thereforInfo
- Publication number
- GB592670A GB592670A GB343645A GB343645A GB592670A GB 592670 A GB592670 A GB 592670A GB 343645 A GB343645 A GB 343645A GB 343645 A GB343645 A GB 343645A GB 592670 A GB592670 A GB 592670A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resin
- benzene hexachloride
- water
- dispersion
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 230000002745 absorbent Effects 0.000 title abstract 5
- 239000002250 absorbent Substances 0.000 title abstract 5
- 241000238631 Hexapoda Species 0.000 title abstract 3
- CKAPSXZOOQJIBF-UHFFFAOYSA-N Hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 abstract 15
- 239000006185 dispersion Substances 0.000 abstract 11
- 229920005989 resin Polymers 0.000 abstract 10
- 239000011347 resin Substances 0.000 abstract 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 8
- 239000003995 emulsifying agent Substances 0.000 abstract 6
- -1 vinyl halides Chemical class 0.000 abstract 6
- 238000001035 drying Methods 0.000 abstract 4
- 239000004744 fabric Substances 0.000 abstract 4
- 238000005470 impregnation Methods 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- 239000004014 plasticizer Substances 0.000 abstract 4
- 229920003002 synthetic resin Polymers 0.000 abstract 4
- 239000000057 synthetic resin Substances 0.000 abstract 4
- 239000007787 solid Substances 0.000 abstract 3
- 229920000180 Alkyd Polymers 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 2
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 2
- ODGAOXROABLFNM-UHFFFAOYSA-N Polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 abstract 2
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 238000011065 in-situ storage Methods 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920001568 phenolic resin Polymers 0.000 abstract 2
- 229920002647 polyamide Polymers 0.000 abstract 2
- 239000011528 polyamide (building material) Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 229920001187 thermosetting polymer Polymers 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- 240000000218 Cannabis sativa Species 0.000 abstract 1
- 240000000491 Corchorus aestuans Species 0.000 abstract 1
- 235000011777 Corchorus aestuans Nutrition 0.000 abstract 1
- 235000010862 Corchorus capsularis Nutrition 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 240000006962 Gossypium hirsutum Species 0.000 abstract 1
- 210000002268 Wool Anatomy 0.000 abstract 1
- 230000001680 brushing Effects 0.000 abstract 1
- 235000009120 camo Nutrition 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 235000005607 chanvre indien Nutrition 0.000 abstract 1
- 239000007799 cork Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000011487 hemp Substances 0.000 abstract 1
- 235000012765 hemp Nutrition 0.000 abstract 1
- 235000012766 marijuana Nutrition 0.000 abstract 1
- 239000011087 paperboard Substances 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002965 rope Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C23/00—Compounds containing at least one halogen atom bound to a ring other than a six-membered aromatic ring
- C07C23/02—Monocyclic halogenated hydrocarbons
- C07C23/10—Monocyclic halogenated hydrocarbons with a six-membered ring
- C07C23/12—Hexachlorocyclohexanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Paper (AREA)
Abstract
Solid absorbent articles are proofed against attack by insects by impregnation with a solution in a volatile organic solvent or an aqueous dispersion of a benzene hexachloride and a synthetic resin or a synthetic resin-forming material, drying and then if necessary heating to a temperature sufficient to produce the polymerized or further condensed resin in situ. The impregnation may increase the weight of the dry absorbent article from 1 to 10 per cent. The benzene hexachloride may be a mixture containing at least 8 per cent by weight of the gamma-isomer, and may be deodorised. The benzene hexachloride may form from 1 to 20 per cent by weight of the total solids in the impregnating composition. The articles treated may be wool, silk, linen, cotton, jute, or hemp fabrics, carpets, curtains, blankets, upholstery, timber, pulp or paper boards and containers, sacking, canvas, ropes, cork, fibre board, wood, or book covers. The synthetic resin may be one produced by the polymerization or interpolymerization of ethylene, vinyl halides, vinyl alcohol, vinyl carboxylic esters such as vinyl acetate, acrylic acid, a -chloroacrylic acid, or methacrylic acid or esters or other polymerizable derivatives thereof, or may be a polyamide, an urea-, acetone-, melamine- or phenol-formaldehyde, a phenol-, furfural- or methylol-urea, or an alkyd resin. Mixtures of two or more such resins may be used. Plasticisers may be added. The benzene hexachloride and resin may be ground with water, plasticisers and emulsifying agent, and the dispersion diluted with water or violently agitated with water containing further emulsifying agent, or the benzene hexachloride may be ground with water and emulsifier and the dispersion mixed with an aqueous dispersion of resin or resin-forming material. The dispersion may be applied to a fabric by spraying or brushing, or by passage through a bath and then between rollers. The dispersion may also comprise benzene hexachloride and a monomeric or partially polymerized vinyl compound, methacrylate, or a -chloroacrylate, together with a polymerization catalyst. Benzene hexachloride may also be dispersed in an aqueous solution of a water-soluble thermosetting urea-formaldehyde resin, and the impregnated fabric heated to insolubilise the resin after drying, Specifications 573,689, 578,206, [Group VI]. and 592,674, [Group VIII], are referred to.ALSO:Solid absorbent articles are proofed against attack by insects by impregnation with a solution in a volatile organic solvent or an aqueous dispersion of a benzene hexachloride and a synthetic resin or a synthetic resin-forming material, drying, and then if necessary heating to a temperature sufficient to produce the polymerised or further condensed resin in situ. The impregnation may increase the weight of the dry absorbent article from 1 to 10 per cent. The benzene hexachloride may be a mixture containing at least 8 per cent. by weight of the gammaisomer (i.e., may be crude benzene hexachloride or benzene hexachloride containing an enhanced proportion of the gamma-isomer), and may be deodorised. The synthetic resin may be one produced by the polymerisation or interpolymerisation of ethylene, vinyl halides, vinyl alcohol, vinyl carboxylic esters such as vinyl acetate, acrylic acid, a -chloroacrylic acid, or methacrylic acid or esters or other polymerisable derivatives thereof, or may be a polyamide, an urea-, acetone-, melamine-, or phenol-formaldehyde, a phenol-, furfural-, or methylol-urea, or an alkyd resin. Mixtures of two or more such resins may be used. Plasticisers may be added. The benzene hexachloride and resin may be ground with water, plasticisers, and emulsifying agent, and the dispersion diluted with water or violently agitated with water containing further emulsifying agent, or the benzene hexachloride may be ground with water and emulsifier, and the dispersion mixed with an aqueous dispersion of resin or resin-forming material. The dispersion may also comprise benzene hexachloride and a monomeric or partially polymerised vinyl compound, methacrylate, or a -chloroacrylate, together with a polymerisation catalyst. Benzene hexachloride may also be dispersed in an aqueous solution of a water-soluble thermosetting urea-formaldehyde resin, and the impregnated fabric heated to insolubilise the resin after drying. Specifications 573,689, 578,206 and 592,674, [Group VIII], are referred to.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB592670A true GB592670A (en) | 1947-09-25 |
Family
ID=1627679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB343645A Expired GB592670A (en) | 1945-02-12 | Improvements in or relating to the proofing against insects of absorbent articles and to compositions therefor |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB592670A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2652322A (en) * | 1951-01-03 | 1953-09-15 | Monsanto Chemicals | Herbicides |
| US2740818A (en) * | 1952-12-23 | 1956-04-03 | Olin Mathieson | Production of finely divided benzene hexachloride |
| US2750252A (en) * | 1951-06-26 | 1956-06-12 | William N Sullivan | Method of applying lindane |
| US2759903A (en) * | 1952-04-22 | 1956-08-21 | Epstein | Resinous fungicide |
| US2809147A (en) * | 1954-06-15 | 1957-10-08 | Hornstein Irwin | Insecticidal film-forming composition and method of making same |
| US2916414A (en) * | 1951-08-02 | 1959-12-08 | Henkel & Cie Gmbh | Urea-hexachlorocyclohexane insecticide |
| US3035970A (en) * | 1957-12-02 | 1962-05-22 | Ici Ltd | Compositions comprising solid solutions of chlorinated paraffin and gamma benzene hexachloride |
| US3156661A (en) * | 1961-11-13 | 1964-11-10 | Chemical Corp Of America | Insecticidal water-based, self-polishing coating compositions |
| US3212967A (en) * | 1962-11-05 | 1965-10-19 | Dow Chemical Co | Biocidally-active mixed phosphorothioate ester-containing and mixed phosphoramidate ester-containing polymeric materials |
| US3228830A (en) * | 1962-11-05 | 1966-01-11 | Dow Chemical Co | Biocidally-active phenoxarsine-containing polymeric materials |
| US3400093A (en) * | 1966-03-11 | 1968-09-03 | Feinberg Irving | Process for preparing a stable polymer latex containing an insecticide |
-
1945
- 1945-02-12 GB GB343645A patent/GB592670A/en not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2652322A (en) * | 1951-01-03 | 1953-09-15 | Monsanto Chemicals | Herbicides |
| US2750252A (en) * | 1951-06-26 | 1956-06-12 | William N Sullivan | Method of applying lindane |
| US2916414A (en) * | 1951-08-02 | 1959-12-08 | Henkel & Cie Gmbh | Urea-hexachlorocyclohexane insecticide |
| US2759903A (en) * | 1952-04-22 | 1956-08-21 | Epstein | Resinous fungicide |
| US2740818A (en) * | 1952-12-23 | 1956-04-03 | Olin Mathieson | Production of finely divided benzene hexachloride |
| US2809147A (en) * | 1954-06-15 | 1957-10-08 | Hornstein Irwin | Insecticidal film-forming composition and method of making same |
| US3035970A (en) * | 1957-12-02 | 1962-05-22 | Ici Ltd | Compositions comprising solid solutions of chlorinated paraffin and gamma benzene hexachloride |
| US3156661A (en) * | 1961-11-13 | 1964-11-10 | Chemical Corp Of America | Insecticidal water-based, self-polishing coating compositions |
| US3212967A (en) * | 1962-11-05 | 1965-10-19 | Dow Chemical Co | Biocidally-active mixed phosphorothioate ester-containing and mixed phosphoramidate ester-containing polymeric materials |
| US3228830A (en) * | 1962-11-05 | 1966-01-11 | Dow Chemical Co | Biocidally-active phenoxarsine-containing polymeric materials |
| US3400093A (en) * | 1966-03-11 | 1968-09-03 | Feinberg Irving | Process for preparing a stable polymer latex containing an insecticide |
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