GB587914A - Production of phenolic resins - Google Patents
Production of phenolic resinsInfo
- Publication number
- GB587914A GB587914A GB23017/44A GB2301744A GB587914A GB 587914 A GB587914 A GB 587914A GB 23017/44 A GB23017/44 A GB 23017/44A GB 2301744 A GB2301744 A GB 2301744A GB 587914 A GB587914 A GB 587914A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- methyl
- xylenol
- catalyst
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Cured resins are produced by partially condensing a phenol with a compound containing an active methylene group, adding 3,5-xylenol to the resulting partial condensate and completing the condensation by heating. The phenol may be phenol, 3-methyl phenol, 2-methyl phenol, 2,3-dimethyl phenol, 2,3,5-trimethyl phenol, 2-tolyl phenol, 2-methyl, 3-ethyl phenol, 2,5-dimethyl phenol, 2-isopropyl phenol, 2-tertiary butyl-, 2-secondary amyl-, 4 - methyl-, 3,4 - dimethyl-, 3 - methyl, 4- isopropyl - phenols, long chain hydrocarbon substituted phenols, such as cardanol, best results being obtained from phenols boiling below 225 DEG C., phenol itself being preferred. The compound containing an active methylene group may be formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, valeraldehyde, acrolein, furfural, benzaldehyde, although formaldehyde, paraformaldehyde or formalin are preferred. The reactants, preferably in the presence of a catalyst, are mixed, in the fusible state, with 3,5-xylenol and cured. The catalyst may be acidic or basic, examples being hydrochloric, sulphuric, phosphoric, acetic, lactic, phthalic acids, or ammonia, ammonium hydroxide, hexamethylene tetramine and amines, more than one catalyst may be used and the preferred pH range is 5-10. The reaction may be carried out in an inert atmosphere of, e.g. nitrogen or carbon dioxide, to minimise coloration due to oxidation, and under any pressure. The amount of 3,5-xylenol used as a hardening agent is preferably 0.5-5 per cent of the weight of phenol used in the resin. Shaping is carried out before curing, or the resin composition may be applied as a coating to paper, cloth, glass, wood, brick, stone, cement, plaster, &c., or as a sizing composition for woven or felted textiles; it may be moulded or extruded, with or without admixed plasticisers, solvents, pigments, fillers, dyes, stabilisers lubricants and other synthetic or natural resins.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US587914XA | 1943-11-16 | 1943-11-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB587914A true GB587914A (en) | 1947-05-08 |
Family
ID=22018951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23017/44A Expired GB587914A (en) | 1943-11-16 | 1944-11-20 | Production of phenolic resins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB587914A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2168992A (en) * | 1984-10-26 | 1986-07-02 | Tohoku Chemical Ind Ltd | Grinding wheel |
CN106380576A (en) * | 2016-08-29 | 2017-02-08 | 湖北绿色家园精细化工股份有限公司 | Novel Mannich base epoxy curing agent |
-
1944
- 1944-11-20 GB GB23017/44A patent/GB587914A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2168992A (en) * | 1984-10-26 | 1986-07-02 | Tohoku Chemical Ind Ltd | Grinding wheel |
CN106380576A (en) * | 2016-08-29 | 2017-02-08 | 湖北绿色家园精细化工股份有限公司 | Novel Mannich base epoxy curing agent |
CN106380576B (en) * | 2016-08-29 | 2018-06-26 | 湖北绿色家园材料技术股份有限公司 | A kind of Mannich base epoxy curing agent |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2441860A (en) | Accelerated curing of phenol-form-aldehyde resins to the infusible state with 3, 5-xyenol | |
US2566851A (en) | Phenolic intercondensation resins and methods of making same | |
FI57775C (en) | FOERFARANDE FOER FRAMSTAELLNING AV ETT VAEDERBESTAENDIGT TRAELIM | |
GB587914A (en) | Production of phenolic resins | |
GB576995A (en) | Hardenable compositions containing urea-aldehyde resins | |
US2489145A (en) | Synthetic resin compositions employing curing catalysts | |
US3044973A (en) | Molding composition comprising melamine formaldehyde resin and monomethylol melamine, and cured product thereof | |
US2427512A (en) | Dicyandiamide-aldehyde product | |
US1756252A (en) | Synthetic product and process of making same | |
US2517128A (en) | Urea-formaldehyde-oxazolidine co-reaction resin | |
GB626645A (en) | Improvements in or relating to methods of preparing an artificial resin and the improved artificial resin resulting therefrom | |
US3631152A (en) | Ethylene urea terminated phenolic resins and method of curing same | |
US2221511A (en) | Resinous composition and method of making the same | |
US2265688A (en) | Phenol-aldehyde-benzoylsulphimide condensation product | |
US2260006A (en) | Condensation product of a phenol, an aliphatic aldehyde, and a partly amidated polycarboxylic acid | |
US3096226A (en) | Aqueous composition of phenol-aldehyde condensate and method of bonding materials with same | |
US1996087A (en) | Process of making molded articles from urea or its derivatives, solid polymeric aldehydes, and filling bodies | |
US3663503A (en) | Colorless,cold cure phenolic resin containing sulfur stabilizers | |
US2263290A (en) | Nitrourea-phenol-aldehyde condensation products | |
DE2548476A1 (en) | REINFORCED PLASTIC MATERIAL | |
GB582448A (en) | Improvements relating to the manufacture of synthetic resins | |
GB963786A (en) | Improved method of making phenol modified amino condensation resins | |
US2084314A (en) | Urea resins | |
GB389441A (en) | Improvements in and relating to methods of manufacturing artificial resins | |
GB576745A (en) | Improvements in or relating to resinous compositions |