GB566344A - Polymerization of allyl type primary alcohols and products obtainable thereby - Google Patents

Polymerization of allyl type primary alcohols and products obtainable thereby

Info

Publication number
GB566344A
GB566344A GB16988/42A GB1698842A GB566344A GB 566344 A GB566344 A GB 566344A GB 16988/42 A GB16988/42 A GB 16988/42A GB 1698842 A GB1698842 A GB 1698842A GB 566344 A GB566344 A GB 566344A
Authority
GB
United Kingdom
Prior art keywords
oxygen
phenylallyl
dimethylallyl
alcohols
acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16988/42A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Development Co
Original Assignee
Shell Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Development Co filed Critical Shell Development Co
Publication of GB566344A publication Critical patent/GB566344A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

A process for the oxy-condensation polymerization of an unsaturated primary alcohol containing an olefinic linkage between two carbon atoms, one of which is directly linked to the carbon atom of the carbinol group, comprises heating the alcohol in liquid phase in the presence of a catalyst which is an oxygen-containing gas or an oxygen-yielding substance. Alcohols specified are allyl, crotyl, b -methylallyl, b -phenylallyl, g -phenylallyl, b -ethylallyl, g -dimethylallyl and b ,g -dimethylallyl alcohols. Suitable catalysts are hydrogen, benzoyl, sodium, barium, tetralin, acetyl and acetone peroxides, alkali metal perborates and persulphates, or oxygen which may contain nitrogen, carbon dioxide or argon, e.g. air. Diluents, e.g. hexane, heptane and octane may be present. The polymer may be recovered by distillation in vacuo or by flash evaporation at low pressure. It may be purified by treating its aqueous solution with dilute sodium hydroxide, neutralizing with carbon dioxide and hydrogenating in the presence of a Raney nickel catalyst. The products may be used as adhesives, sizes, grease-proofing impregnants for paper and lubricants. They may be reacted with phthalic or maleic acids to form alkyd resins; with unsaturated drying oil acids to form drying oils; with carboxylic acids to form esters; and with nitric acid to form explosives. U.S.A. Specification 2,254,382 is referred to.
GB16988/42A 1941-11-25 1942-11-30 Polymerization of allyl type primary alcohols and products obtainable thereby Expired GB566344A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US566344XA 1941-11-25 1941-11-25

Publications (1)

Publication Number Publication Date
GB566344A true GB566344A (en) 1944-12-27

Family

ID=22005683

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16988/42A Expired GB566344A (en) 1941-11-25 1942-11-30 Polymerization of allyl type primary alcohols and products obtainable thereby

Country Status (5)

Country Link
BE (1) BE475245A (en)
DE (1) DE841505C (en)
FR (1) FR955356A (en)
GB (1) GB566344A (en)
NL (1) NL66784C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2537622A (en) * 1948-08-26 1951-01-09 Monsanto Chemicals Process of preparing substituted allyl alcohols
US2563611A (en) * 1951-08-07 Phen ylallyl alcohol
US2612492A (en) * 1945-09-12 1952-09-30 Us Rubber Co Soluble copolymers of diallylic phthalates and allylic alcohols

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2891037A (en) * 1956-12-26 1959-06-16 Monsanto Chemicals Copolymers of allyl alcohol
FR2960532B1 (en) 2010-05-31 2013-01-04 Gmt ENVIRONMENTAL SAFETY DEVICE FOR A BAC OR POT OF RETENTION OF HAZARDOUS PRODUCTS SUCH AS FLAMMABLE AND / OR TOXIC PRODUCTS, IN PARTICULAR FOR OIL RETAINING PANS OR BINS FOR ELECTRICAL TRANSFORMERS
FR2961006B1 (en) 2010-06-07 2013-07-12 Gmt MODULAR SAFETY DEVICE FOR RECOVERING AND EXTINGUISHING FLAMMABLE PRODUCTS THAT CAN LEAK FROM AN ELECTRICAL TRANSFORMER

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2563611A (en) * 1951-08-07 Phen ylallyl alcohol
US2612492A (en) * 1945-09-12 1952-09-30 Us Rubber Co Soluble copolymers of diallylic phthalates and allylic alcohols
US2537622A (en) * 1948-08-26 1951-01-09 Monsanto Chemicals Process of preparing substituted allyl alcohols

Also Published As

Publication number Publication date
FR955356A (en) 1950-01-14
DE841505C (en) 1952-06-16
BE475245A (en)
NL66784C (en)

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