GB565371A - Improvements in or relating to photocatalytic processes and apparatus therefor - Google Patents
Improvements in or relating to photocatalytic processes and apparatus thereforInfo
- Publication number
- GB565371A GB565371A GB1715/43A GB171543A GB565371A GB 565371 A GB565371 A GB 565371A GB 1715/43 A GB1715/43 A GB 1715/43A GB 171543 A GB171543 A GB 171543A GB 565371 A GB565371 A GB 565371A
- Authority
- GB
- United Kingdom
- Prior art keywords
- discharge
- chlorine
- tubes
- reactants
- vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000001699 photocatalysis Effects 0.000 title 1
- 208000028659 discharge Diseases 0.000 abstract 14
- 239000000376 reactant Substances 0.000 abstract 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 7
- 238000006243 chemical reaction Methods 0.000 abstract 7
- 239000000460 chlorine Substances 0.000 abstract 7
- 229910052801 chlorine Inorganic materials 0.000 abstract 7
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 6
- 239000007789 gas Substances 0.000 abstract 6
- 229910052751 metal Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 6
- 239000000463 material Substances 0.000 abstract 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- -1 for example Substances 0.000 abstract 3
- 239000011521 glass Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 3
- 239000004291 sulphur dioxide Substances 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 239000011888 foil Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 230000005855 radiation Effects 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 abstract 2
- CXQSCYIVCSCSES-UHFFFAOYSA-N 3-chloropentane Chemical class CCC(Cl)CC CXQSCYIVCSCSES-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 abstract 1
- 229920005479 Lucite® Polymers 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 230000004913 activation Effects 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000007824 aliphatic compounds Chemical class 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical class ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 230000026030 halogenation Effects 0.000 abstract 1
- 238000005658 halogenation reaction Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004020 luminiscence type Methods 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 238000013032 photocatalytic reaction Methods 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000005315 stained glass Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
- B01J19/124—Ultraviolet light generated by microwave irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/302—Basic shape of the elements
- B01J2219/30207—Sphere
- B01J2219/30211—Egg, ovoid or ellipse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/304—Composition or microstructure of the elements
- B01J2219/30433—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Thermal Sciences (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
<PICT:0565371/IV/1> <PICT:0565371/IV/2> Photocatalytic reactions are effected by submitting the reactants to the action of electric discharges passing through a multiplicity of transparent discharge vessels, packed closely in the space occupied by the said reactants in the reaction chamber, under conditions such as to produce luminescence. In continuous operation, the reactants are passed through the chamber between the discharge vessels which fill substantially the entire cross-section of the reactant stream. The apparatus may comprise a receptacle made of a dielectric having electrodes at the ends and containing a plurality of small discharge tubes containing one or more gases or vapours at reduced pressure, generally below 20 mm. mercury. The application of a high frequency and/or high voltage fluctuating or alternating current induces a discharge glow. Voltages from about 50,000 down to 100 or less may be used, the product of frequency and voltage preferably being about 20,000-100,000,000 or more. Radiations of the desired wavelength are produced by choice of the gas or vapour in the tubes. This may be the same as one of the reactants, for example, chlorine in chlorination reactions. Different gases may be used to catalyse different reactions in different parts of the reaction vessel. The small discharge tubes are conveniently of 1/2 -1\ba1/2 " diameter, of spherical or elongated shape, and may have focal discharge areas comprising metal nodes or spots on the inner walls, preferably at opposite points, metal wires or rods passing through the walls, or external metal caps or coatings. They may be connected by wires, metal foils or the like. The reaction vessel has metal ends 3, 4 fitted with gas and liquid inlets and outlets and connected to a source of high tension alternating current, and is filled with glass vessels 10 containing the desired gas which gives the discharge glow. Reactants are admitted and products removed in batch or continuous operation. In a modification, Fig. 2 (not shown) adapted for continuous operation the vessel may be of plastic material with metal foil on the ends to form electrodes. A liquid reactant flows downwardly around the discharge tubes and a gaseous reactant, admitted part-way up the vessel, passes upwardly in counter-current. A selective solvent for the product may also be admitted at the top. The discharge tubes are of material selected according to the wavelength of the light transmitted. Glass, quartz, fluorte, silica and "Lucite" are materials specified. The tubes may be of coloured glass or lacquered to filter out undesired radiations, and may be lined with fluorescent materials which emit visible light on activation by ultra-violet light or X-rays. Reactions to which the invention is applicable include halogenations, cracking, hydrogenation and dehydrogenation of hydrocarbons, oil hardening and reactions with sulphur dioxide and chlorine or with sulphuryl chloride of organic compounds, especially aliphatic compounds, e.g. hydrocarbons, alcohols, acids and their chlorinated or other derivatives, of from 8-26, preferably 12-20, carbon atoms. In examples: (1) the apparatus of Fig. 1 contains discharge tubes filled with chlorine at 5-10 mm. It is filled with toluene, and current at 20,000 volts and 1,000 cycles applied. Air is removed and chlorine passed in to form benzyl, benzal and benzenyl chlorides; (2) pentane and chlorine are continuously passed into the apparatus at about 40 DEG C. to form monochlorpentanes; (3) the apparatus of Fig. 2 is used to react a paraffinic mineral oil with a mixture by volume of 3 parts of sulphur dioxide being added as a solvent for the sulphonyl chlorides produced. The product can be hydrolysed with caustic soda at about 90 DEG C., extracted to remove unsulphonated material and the solid sulphonate recovered. The sulphonation may also be effected in liquid phase, and the discharge tubes may be filled with gases other than chlorine, or part may contain chlorine and others sulphur dioxide or argon. The Specification as open to inspection under Sect. 91 comprises also the use of the reaction vessel itself as a discharge tube, the small tubes being dispensed with. The glass vessel 21, Fig. 3 (cancelled), has point electrodes 29, cooling jacket 22 and connection 25 to a vacuum pump. In a further example (4), quinoline and part of the required bromine are drawn into this apparatus which is cooled to - 25 DEG C., giving a pressure below 10 mm. More bromine is admitted as necessary to produce bromquinoline hydrobromide. In place of the multiplicity of discharge tubes, a single vessel of an undulate shape may be used over which the reactants flow in a film. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US565371XA | 1942-02-03 | 1942-02-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB565371A true GB565371A (en) | 1944-11-08 |
Family
ID=22005058
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1715/43A Expired GB565371A (en) | 1942-02-03 | 1943-02-02 | Improvements in or relating to photocatalytic processes and apparatus therefor |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB565371A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002062465A1 (en) * | 2001-02-07 | 2002-08-15 | Dieter Meissner | Photochemical reactor |
CN113501779A (en) * | 2021-07-01 | 2021-10-15 | 云南大学 | Method for selectively removing benzyl, allyl and propargyl protecting groups initiated by visible light or near visible light |
-
1943
- 1943-02-02 GB GB1715/43A patent/GB565371A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002062465A1 (en) * | 2001-02-07 | 2002-08-15 | Dieter Meissner | Photochemical reactor |
CN113501779A (en) * | 2021-07-01 | 2021-10-15 | 云南大学 | Method for selectively removing benzyl, allyl and propargyl protecting groups initiated by visible light or near visible light |
CN113501779B (en) * | 2021-07-01 | 2023-06-23 | 云南大学 | Method for selectively removing benzyl, allyl and propargyl protecting groups by visible light or near visible light |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2400732T3 (en) | Method for the production of fluorinated organic compounds | |
Kharasch et al. | Carboxylation. 1 I. The Photochemical and Peroxide-catalyzed Reactions of Oxalyl Chloride with Paraffin Hydrocarbons2 | |
US2393509A (en) | Chlorination of saturated hydrocarbons | |
GB565371A (en) | Improvements in or relating to photocatalytic processes and apparatus therefor | |
US2398481A (en) | Process for catalyzed abnormal addition reactions | |
US3357907A (en) | Process for preparing 1, 1, 1-trichloroethane | |
US2462669A (en) | Process and apparatus for photocatalytic reactions | |
US2398480A (en) | Production of halogenated mercaptans and thio-ethers | |
Birchall et al. | Cyclopropane chemistry. Part 5 [1, 2]. Hexafluorocyclopropane as a source of difluorocarbene | |
US2459767A (en) | Manufacture of chlorofluoro methanes | |
JPH10120604A (en) | Purification of hydrochlorofluoroethane | |
US2335259A (en) | Process for the production of acid halides | |
US2683688A (en) | Preparation of alkyl monochlorides | |
US2649485A (en) | Production of methyl acetylene | |
US2019015A (en) | Halogenation of diphenyl | |
Gow et al. | Stability and Catalytic Activity of Platinum Ethylene Chloride | |
US2436366A (en) | Processes for chlorination of hydrocarbons | |
US5750010A (en) | Process for photochlorination | |
US2566163A (en) | Manufacture of tetrachlorodifluoroethane | |
KR940018339A (en) | New Photochemical Gas-Liquid Method for Alkylbenzene Halogenation | |
GB1280990A (en) | Improvements in mercury vapour discharge lamps and their use in photo-chemical processes | |
US4242187A (en) | Preparation of alkanes substituted by chlorine atoms and/or sulfochloride groups | |
Fields et al. | 366. Carbene chemistry. Part I. Reactions of fluoroalkyldiazo-compounds | |
US2174492A (en) | Preparation of alkane sulphonyl chlorides | |
NO141937B (en) | PROCEDURE FOR THE MANUFACTURING OF A LACCOPHERIC COMPONENT FOR INBURN PAINTING |