GB545193A - Polymerisation of conjugated diolefinic hydrocarbons to drying polymers - Google Patents

Polymerisation of conjugated diolefinic hydrocarbons to drying polymers

Info

Publication number
GB545193A
GB545193A GB14909/40A GB1490940A GB545193A GB 545193 A GB545193 A GB 545193A GB 14909/40 A GB14909/40 A GB 14909/40A GB 1490940 A GB1490940 A GB 1490940A GB 545193 A GB545193 A GB 545193A
Authority
GB
United Kingdom
Prior art keywords
butadiene
benzene
oct
polymerization
top coat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14909/40A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB545193A publication Critical patent/GB545193A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)

Abstract

545,193. Coating surfaces. DU PONT DE NEMOURS & CO., E. I. Oct. 5, 1940, No. 14909. Convention date, Oct. 4, 1939. [Class 95] [Also in Group IV] Drying-oils are produced by polymerization of a diolefine in an inert hydrocarbon solvent in presence of at least about 4 per cent. of an alkali or alkaline earth metal or hydride thereof at 110-170‹ C. under pressure. Examples describe the polymerization of butadiene, with benzene and of a butadiene-butylene mixture with or without benzene by means of sodium, and of butadiene with benzene by means of sodium hydride. A small proportion of a reactive unsaturated substance such as indene, dihydronaphthalene, chloroprene, styrene, viyl acetate, methyl methacrylate, cyclopentadiene and cyclohexadiene may be added to modify the properties of the product. Solutions of the polymers are suitable for coating purposes, especially those which involve baking, especially as an undercoat; when a vinyl chloride-vinyl acetate inter-polymer is employed as a top coat the butadiene polymer solution may have an addition of a small proportion of a methacrylic acid ester such as isobutyl methacrylate to promote adhesion to the top coat. The Specification as open to inspection under Sect. 91 gives the lower limit of temperature as 100‹ C. This subject-matter does not appear. in the Specification as accepted.
GB14909/40A 1939-10-04 1940-10-05 Polymerisation of conjugated diolefinic hydrocarbons to drying polymers Expired GB545193A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US545193XA 1939-10-04 1939-10-04

Publications (1)

Publication Number Publication Date
GB545193A true GB545193A (en) 1942-05-14

Family

ID=21991651

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14909/40A Expired GB545193A (en) 1939-10-04 1940-10-05 Polymerisation of conjugated diolefinic hydrocarbons to drying polymers

Country Status (1)

Country Link
GB (1) GB545193A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2543440A (en) * 1949-04-11 1951-02-27 Phillips Petroleum Co Process for treating polymers produced by alkali metal catalyzed polymerizations
US2586594A (en) * 1947-10-29 1952-02-19 Standard Oil Dev Co Preparation of drying oils from diolefins
US2631175A (en) * 1948-12-23 1953-03-10 Phillips Petroleum Co Production of liquid polybutadiene
US2636910A (en) * 1949-04-22 1953-04-28 Phillips Petroleum Co Process for treating polymers produced by alkali metal catalyzed polymerizations
US2762851A (en) * 1950-07-29 1956-09-11 Exxon Research Engineering Co Butadienoid drying oil and process for preparing same
US2768984A (en) * 1953-05-12 1956-10-30 Exxon Research Engineering Co Color improvement in preparation of drying oils
US3004012A (en) * 1958-02-05 1961-10-10 Du Pont Catalytic process for polymerizing chloroprene to a solid elastomer
US3004011A (en) * 1958-02-05 1961-10-10 Du Pont Catalytic process for polymerizing chloroprene to a solid elastomer
US3285901A (en) * 1962-10-11 1966-11-15 Firestone Tire & Rubber Co Polymerization of isoprene in the presence of lithium metal and an inert liquid hydrocarbon

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2586594A (en) * 1947-10-29 1952-02-19 Standard Oil Dev Co Preparation of drying oils from diolefins
US2631175A (en) * 1948-12-23 1953-03-10 Phillips Petroleum Co Production of liquid polybutadiene
US2543440A (en) * 1949-04-11 1951-02-27 Phillips Petroleum Co Process for treating polymers produced by alkali metal catalyzed polymerizations
US2636910A (en) * 1949-04-22 1953-04-28 Phillips Petroleum Co Process for treating polymers produced by alkali metal catalyzed polymerizations
US2762851A (en) * 1950-07-29 1956-09-11 Exxon Research Engineering Co Butadienoid drying oil and process for preparing same
US2768984A (en) * 1953-05-12 1956-10-30 Exxon Research Engineering Co Color improvement in preparation of drying oils
US3004012A (en) * 1958-02-05 1961-10-10 Du Pont Catalytic process for polymerizing chloroprene to a solid elastomer
US3004011A (en) * 1958-02-05 1961-10-10 Du Pont Catalytic process for polymerizing chloroprene to a solid elastomer
US3285901A (en) * 1962-10-11 1966-11-15 Firestone Tire & Rubber Co Polymerization of isoprene in the presence of lithium metal and an inert liquid hydrocarbon

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