GB544143A - Aryl silicone condensation products - Google Patents
Aryl silicone condensation productsInfo
- Publication number
- GB544143A GB544143A GB14533/40A GB1453340A GB544143A GB 544143 A GB544143 A GB 544143A GB 14533/40 A GB14533/40 A GB 14533/40A GB 1453340 A GB1453340 A GB 1453340A GB 544143 A GB544143 A GB 544143A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicones
- silicon
- dichloride
- aryl
- hydrolysed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/86—Vessels; Containers; Vacuum locks
- H01J29/88—Vessels; Containers; Vacuum locks provided with coatings on the walls thereof; Selection of materials for the coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
Abstract
544,143. Silicones ; synthetic resins. BRITISH THOMSON-HOUSTON CO., Ltd. Sept. 25, 1940, No. 14533. Convention date, Sept. 27, 1939. [Class 2 (iii)] [Also in Group YIII] Resinous polymeric aryl silicones of the R general formula R<SP>1</SP> > SiO, in which either or both R and R<SP>1</SP> are halogenated aryl radicals and either may be alkyl, aryl or aralkyl; are produced by hydrolysing an halogenated aryl silicon dihalide and condensing the hydrolysed product by heating ; further condensation may be effected at elevated temperature. Flame-proof products of good electrical properties are obtained. The initial condensates may be dissolved in a volatile solvent and employed as coating and impregnating compositions, e.g. for plain or wrapped conductors, woven or felted fabrics, as a binder for flaky materials, e.g. mica or for treating coherent films of clay, e.g. bentonite with which may be associated glass &c. fibres ; the fully condensed products may be associated with inorganic fibres and fillers, e.g. asbestos, mica, glass, to produce heat-resistant insulating materials. Mixtures of different halogenated aryl silicones may be employed and may be produced from mixed silicones condensed together, from a mixture of silicones advanced separately to an intermediate stage, or by mixing and grinding together fully condensed individual silicones. The silicones, simple or mixed, may be compounded with flammable materials, e.g. rubber ; tars, asphaltes and pitches ; natural and synthetic resins, and cellulose and cellulose derivatives ; they may also be compounded with plasticizers &c., e.g. dibutyl phthalate, tricresyl phosphate, chlorinated diphenyls, ethyl silicate. Cotton, wool, linen, wood &c. may be flame-proofed with the silicones which may also be used as protective coverings for glass, as semi-conducting paints and as sealing compositions for uniting glass to metal. Coating compositions may be obtained. by dissolving or dispersing initial products in drying oils, alone or mixed with solvents, pigments, plasticizers, driers &c. Laminated products and moulding compositions are also referred to. Specified halogenated silicones are the di-trichlorophenyl, dibromophenyl, methyl trichlorophenyl and dichlorotolyl silicones. Halogenated silicones derived from other aryl derivatives include those from halogen derivatives of toluene, xylenes, mono-, di- and tri-ethyl benzenes, diphenyl, diphenylene oxide, diphenyl ether, naphthalene, methyl naphthalene, tetrahydronaphthalene, indene and anthracene. In an example, (1) di-phenyl silicon dichloride is treated with chlorine at 70-120‹ C. in the presence of a catalyst until 2-10 and preferably 6-10 grain atoms of chlorine have been introduced, the chlorinated product is purified by distillation under diminished pressure and the product is hydrolysed by pouring into water and boiling, after which the flocculent silicol is separated, washed and converted to silicone by heating at 125-150‹ C. until it becomes a clear liquid which, by further heating at 175-250‹ C. is converted to a resinous product, (3) methyl phenyl silicon dichloride is similarly chlorinated and worked up, (2) di-p-fluorphenyl silicon dichloride is hydrolysed and further worked up and (4) di-pnenyl silicon dichloride is heated with iodine and iodic anhydride to form di-iodophenyl silicon dichloride which is then hydrolysed and worked up. Di-phenyl silicon dichloride is obtained by adding 1 mol of silicon tetrachlorid to an ether solution of 2“ mols. of phenyl magnesium bromide, with rapid stirring ; after filtering from magnesium salts and evaporation of the ether, the dichloride is separated from phenyl silicon trichloride and triphenyl silicon chloride by distillation under diminished pressure. Di-p-fluorphenyl silicon dichloride is similarly prepared from p-fluorphenyl magnesium bromide (obtained by the action of magnesium on p-fluorbromobenzene).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US544143XA | 1939-09-27 | 1939-09-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB544143A true GB544143A (en) | 1942-03-30 |
Family
ID=21990901
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14533/40A Expired GB544143A (en) | 1939-09-27 | 1940-09-25 | Aryl silicone condensation products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB544143A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2473887A (en) * | 1945-12-29 | 1949-06-21 | Westinghouse Electric Corp | Protecting metal surfaces during soldering and brazing processes |
EP3239243A4 (en) * | 2014-12-25 | 2018-10-10 | Shengyi Technology Co. Ltd. | Ceramized silicone resin composition and pre-preg and laminate that use the composition |
-
1940
- 1940-09-25 GB GB14533/40A patent/GB544143A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2473887A (en) * | 1945-12-29 | 1949-06-21 | Westinghouse Electric Corp | Protecting metal surfaces during soldering and brazing processes |
EP3239243A4 (en) * | 2014-12-25 | 2018-10-10 | Shengyi Technology Co. Ltd. | Ceramized silicone resin composition and pre-preg and laminate that use the composition |
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