GB529399A - Improvements in or relating to coating film forming and sealing compositions obtained from polymeric derivatives of methacrylic acid - Google Patents
Improvements in or relating to coating film forming and sealing compositions obtained from polymeric derivatives of methacrylic acidInfo
- Publication number
- GB529399A GB529399A GB14767/39A GB1476739A GB529399A GB 529399 A GB529399 A GB 529399A GB 14767/39 A GB14767/39 A GB 14767/39A GB 1476739 A GB1476739 A GB 1476739A GB 529399 A GB529399 A GB 529399A
- Authority
- GB
- United Kingdom
- Prior art keywords
- wax
- polymer
- esters
- methacrylic acid
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
529,399. Synthetic resin compositions. DU PONT DE NEMOURS & CO., E. I. May 17, 1939, No. 14767. Convention date, May 20, 1938. [Class 2 (iii)] Coating, film forming, sealing compositions &c. are obtained by blending together a wax and a polymeric methacrylic acid amide, imide or ester, the wax and the polymer being heated together above the melting point of the wax, and the polymer when it is an ester, being such that the alkyl radical thereof contains more than two carbonatoms. Waxes include those of animal; vegetable, or mineral origin such as carnauba candellila, montan, lanoline, cocabutter, cotton seed, stearin, Japan wax, bayberry, myrtle, mace, palm kernel, beeswax, spermaceti, Chinese insect, mutton tallow, hydrogenated coconut oils, soy bean, paraffin, ceresin, montan, ozokerite. Of the esters of methacrylic acid n-propyl and higher esters are suitable e.g. butyl, cyclohexyl, amino alcohol esters, esters of mixtures of alcohols obtained by the catalytic hydrogenation of carbon oxides at elevated pressure, methacrylic acid esters of alcohols derived by carboxyl hydrogenation of vegetable oils eg. lauryl, myristyl, cetyl and stearyl alcohols. Polymeric amides and imides specified comprise the laurylimide, octylimide, monobutyl amide, dibutyl amide and the mono- and di-higher-alkylamides. Interpolymers or polymeric mixtures may also be used provided the average of the number of carbon atoms in the alkyl groups is greater than 2. Additional components specified comprise natural or synthetic rubbers or their halogen compounds, gutta percha, asphalt, natural and synthetic resins and plasticizers e.g. dicyclohexyl phthalate, phthalates of higher alcohols, cresyl phosphates para toluene sulphonamide, dibutyl phthalates, octadecanediol monocarbamate, stearyl carbamate. The temperatures specified are from 75‹C. upwards but preferably temperatures above the " solution temperature " of the ester, i.e. the temperature at which the paraffinpolymer solution becomes cloudy on cooling. This decreases with increasing molecular weight of the esterified alcohol radical e.g. the solution " temperature for a 40 per cent. polymer solution of propyl methacrylate in paraffin wax is 240‹C. and 170‹C. for butyl methacrylate. 40 parts of n-butyl methacrylate monomer (containing 0.5 per cent. benzoyl peroxide) is mixed with 60 parts of melted paraffin wax (m.p. 57-60‹C. ) and the mixture placed in an oven heated to 100‹C. After three days the layers of polymer and paraffin are heated to 180‹C. and complete solution is obtained. A table of blends of paraffin wax, polymer and additional ingredients is given. The products obtained may be used (1) as coating compositions for cloth, paper, leather, cellulose films, linoleum oil cloth, wall board, stone, cement, bricks &c. wood, glass, metals, wire screens (2) in the form of films and filaments which may be used for wrapping foodstuffs &c. Alternatively the food stuffs may be dipped in the molten products (3) for spraying wood, metal, cans for preserving food &c. and for electric insulation purposes (4) as adhesives or polishes (5) for sizing paper.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US529399XA | 1938-05-20 | 1938-05-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB529399A true GB529399A (en) | 1940-11-20 |
Family
ID=21980896
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14767/39A Expired GB529399A (en) | 1938-05-20 | 1939-05-17 | Improvements in or relating to coating film forming and sealing compositions obtained from polymeric derivatives of methacrylic acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB529399A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3171825A (en) * | 1959-06-11 | 1965-03-02 | Western Petrochemical Corp | Novel polymerized compositions of a wax, hydrocarbon polymer and a polymeric polar organic compound |
US3246963A (en) * | 1963-02-01 | 1966-04-19 | Exxon Research Engineering Co | Compositions containing wax and either a wax-naphthalene condensation product or certain fumarate ester containing polymers |
US4990561A (en) * | 1989-01-20 | 1991-02-05 | Shin-Etsu Chemical Co., Ltd. | Wax composition and preparation method thereof |
-
1939
- 1939-05-17 GB GB14767/39A patent/GB529399A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3171825A (en) * | 1959-06-11 | 1965-03-02 | Western Petrochemical Corp | Novel polymerized compositions of a wax, hydrocarbon polymer and a polymeric polar organic compound |
US3246963A (en) * | 1963-02-01 | 1966-04-19 | Exxon Research Engineering Co | Compositions containing wax and either a wax-naphthalene condensation product or certain fumarate ester containing polymers |
US4990561A (en) * | 1989-01-20 | 1991-02-05 | Shin-Etsu Chemical Co., Ltd. | Wax composition and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4714496A (en) | Wax compositions | |
US4759709A (en) | Wax compositions | |
US3914131A (en) | Useful wax compositions | |
US2232595A (en) | Coating and film forming compositions | |
US3745033A (en) | Useful wax compositions | |
GB529399A (en) | Improvements in or relating to coating film forming and sealing compositions obtained from polymeric derivatives of methacrylic acid | |
US3979345A (en) | Friable composition and process | |
US2394833A (en) | Wax composition | |
EP0365335A3 (en) | Coating compositions and emulsions | |
US2613162A (en) | Coating compositions containing | |
US2448621A (en) | Composition containing tall oil resins | |
US2560773A (en) | Synthetic wax of the carnauba type | |
US2384730A (en) | Method of preparing cast explosive charges | |
US2288351A (en) | Wax emulsion | |
US2118521A (en) | Polishing composition | |
US2969340A (en) | Process of preventing the separation of polyethylene and wax comprising the addition of water | |
US2187334A (en) | Condensation products of higher fatty acid compounds with boric acid | |
US2397805A (en) | Base coat for launching grease | |
US4434260A (en) | Thermoplastic resin shaping with olefin/maleimide copolymer lubricant | |
CA1133155A (en) | Method of preparing dry mixtures in powder form from polyvinylchloride, lubricating agents and stabilisers | |
US3660128A (en) | Wax-in-water emulsions | |
CA1041076A (en) | Friable composition and process | |
US2025612A (en) | Resinous composition and process for making the same | |
US2126096A (en) | Polishing composition | |
US3414421A (en) | Sealing wax |