GB528051A - - Google Patents
Info
- Publication number
- GB528051A GB528051A GB528051DA GB528051A GB 528051 A GB528051 A GB 528051A GB 528051D A GB528051D A GB 528051DA GB 528051 A GB528051 A GB 528051A
- Authority
- GB
- United Kingdom
- Prior art keywords
- peroxide
- sulphur dioxide
- methyl
- methacrylic
- ascaridol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 4
- 239000004291 sulphur dioxide Substances 0.000 abstract 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 3
- MGYMHQJELJYRQS-UHFFFAOYSA-N Ascaridole Chemical compound C1CC2(C)OOC1(C(C)C)C=C2 MGYMHQJELJYRQS-UHFFFAOYSA-N 0.000 abstract 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 3
- MGYMHQJELJYRQS-ZJUUUORDSA-N ascaridole Natural products C1C[C@]2(C)OO[C@@]1(C(C)C)C=C2 MGYMHQJELJYRQS-ZJUUUORDSA-N 0.000 abstract 3
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 3
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 abstract 3
- -1 ethylene, propylene Chemical group 0.000 abstract 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 abstract 2
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 abstract 2
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 abstract 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 abstract 1
- UZPWKTCMUADILM-UHFFFAOYSA-N 3-methylcyclohexene Chemical compound CC1CCCC=C1 UZPWKTCMUADILM-UHFFFAOYSA-N 0.000 abstract 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000011 acetone peroxide Substances 0.000 abstract 1
- 235000019401 acetone peroxide Nutrition 0.000 abstract 1
- PDAVOLCVHOKLEO-UHFFFAOYSA-N acetyl benzenecarboperoxoate Chemical compound CC(=O)OOC(=O)C1=CC=CC=C1 PDAVOLCVHOKLEO-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- IWTBWSGPDGPTIB-UHFFFAOYSA-N butanoyl butaneperoxoate Chemical compound CCCC(=O)OOC(=O)CCC IWTBWSGPDGPTIB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 1
- 229920002492 poly(sulfone) Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
528,051. Polymerization products. DU PONT DE NEMOURS & CO., E. I. April 19, 1939, No. 11842. Convention date, April 26, 1938. [Class 2 (iii)] Polysulphones are prepared by reacting sulphur dioxide with a mixture of at least one mono-olefine hydrocarbon, which contains at least two hydrogen atoms attached to the unsaturated carbon atoms and where the ethylenic linkage is within two carbon atoms of the end of the carbon chain, and a compound of the formula wherein R is hydrogen or alkyl and wherein A is a negative substituent. Suitable hydrocarbons include ethylene, propylene, n-butylene, isobutylene, 1-pentene, 2-pentene, 1-hexene, 1- octene, 1-nonene, cyclohexene, 3-methylcyclohexene ; suitable other compounds include methacrylic nitrile, methacrylic acid, methacrylic esters such as methyl methacrylate, acrylic esters such as methyl acrylate, vinyl acetate, methyl vinyl ketone and styrene ; suitable catalysts include ultra-violet light, hydrogen peroxide, dibenzoyl peroxide, ascaridol, acetyl benzoyl peroxide, dibutyryl peroxide, dilauryl peroxide, acetone peroxide, urea peroxide, succinic acid peroxide. In examples (1) propylene, sulphur dioxide and methyl methacrylate, vinyl acetate, vinyl methyl ketone, methacrylic nitrile, methyl acrylate or styrene are reacted in the presence of benzoyl peroxide, ascaridol and ethanol (7) n-butylene, sulphur dioxide and methacrylic acid or methyl methacrylate are reacted in the presence of benzoyl peroxide and ethanol (9) n-butylene, sulphur dioxide and vinyl acetate are reacted in the presence of ascaridol. The products may be used in the manufacture of coating compositions.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB528051A true GB528051A (en) |
Family
ID=1748121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB528051D Active GB528051A (en) |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB528051A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2432686A (en) * | 1943-08-23 | 1947-12-16 | Phillips Petroleum Co | Manufacture of resins from sulfur dioxide and unsaturated organic compounds |
| US2453039A (en) * | 1943-08-23 | 1948-11-02 | Phillips Petroleum Co | Manufacture of resins from sulfur dioxide and unsaturated organic compounds |
| US2485454A (en) * | 1945-09-27 | 1949-10-18 | Standard Oil Dev Co | Low-temperature catalytic process for polymerizing olefinic materials in the presence of an inorganic diluent |
| US2999238A (en) * | 1954-10-28 | 1961-09-05 | Henry H George | Automatic error sensitivity control for radar receiver |
| US3684778A (en) * | 1970-04-28 | 1972-08-15 | Du Pont | Polymers of ethylene, sulfur dioxide and ethylenic monomers |
-
0
- GB GB528051D patent/GB528051A/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2432686A (en) * | 1943-08-23 | 1947-12-16 | Phillips Petroleum Co | Manufacture of resins from sulfur dioxide and unsaturated organic compounds |
| US2453039A (en) * | 1943-08-23 | 1948-11-02 | Phillips Petroleum Co | Manufacture of resins from sulfur dioxide and unsaturated organic compounds |
| US2485454A (en) * | 1945-09-27 | 1949-10-18 | Standard Oil Dev Co | Low-temperature catalytic process for polymerizing olefinic materials in the presence of an inorganic diluent |
| US2999238A (en) * | 1954-10-28 | 1961-09-05 | Henry H George | Automatic error sensitivity control for radar receiver |
| US3684778A (en) * | 1970-04-28 | 1972-08-15 | Du Pont | Polymers of ethylene, sulfur dioxide and ethylenic monomers |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Pryor et al. | Ethylene formation from methional | |
| US3852302A (en) | Diacrylic acid ester derivatives of hydantoin compounds | |
| US3705196A (en) | Synthesis of aliphatic and alicyclic ethers | |
| US6235857B1 (en) | Control of molecular weight and end-group functionality in polymers | |
| GB694772A (en) | Improvements in phosphonic acid esters | |
| GB528051A (en) | ||
| BR0104555A (en) | Process for the preparation of highly pure ii refine and methyl tert-butyl ether | |
| WO2000031149A1 (en) | Radical-curable adhesive compositions, reaction products of which demonstrate superior resistance to thermal degradation | |
| US20030073861A1 (en) | Peroxides, their preparation process and use | |
| RU2000128637A (en) | PEROXIDES, METHOD FOR PRODUCING AND USE | |
| DE60013155T2 (en) | PROCESS FOR THE PREPARATION OF PEROXIDES USING MIXED ANHYDRIDES | |
| JP3866659B2 (en) | Production method of ethylene polymer by high pressure method | |
| GB1031089A (en) | Norbornyl derivatives of acrylic and methacrylic acid | |
| US3458557A (en) | Peroxides and peroxy esters and their preparation in the presence of triphenyl phosphine oxide | |
| EP1260500A1 (en) | Process for the production of a sulphur-containing organic compound | |
| US2241900A (en) | Preparation of modified olefin-sul-phur dioxide polysulphones | |
| US5612430A (en) | Process for molecular weight regulation in (co)polymers | |
| US2776319A (en) | Monoperoxyacetals | |
| US2626279A (en) | Thiolesters and their preparation | |
| GB985737A (en) | New organic peroxides and their use in the preparation of copolymers of ethylene and ethylenically unsaturated monomers | |
| US2775615A (en) | Polyhalogenated polycarboxylates | |
| US2484501A (en) | Copolymers of enol esters of diketones | |
| EP1134237B1 (en) | Process for the preparation of polyethylene waxes | |
| US3907903A (en) | Organic peroxides | |
| JPS5949236B2 (en) | 2-Hydroxyethylphosphine |