GB522366A - A process for preparing cyclic hydrocarbons from aliphatic hydrocarbons - Google Patents
A process for preparing cyclic hydrocarbons from aliphatic hydrocarbonsInfo
- Publication number
- GB522366A GB522366A GB35561/38A GB3556138A GB522366A GB 522366 A GB522366 A GB 522366A GB 35561/38 A GB35561/38 A GB 35561/38A GB 3556138 A GB3556138 A GB 3556138A GB 522366 A GB522366 A GB 522366A
- Authority
- GB
- United Kingdom
- Prior art keywords
- gasolines
- hydrocarbons
- cracking
- aliphatic hydrocarbons
- atmos
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
- C07C5/412—Catalytic processes with metal oxides or metal sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
522,366. Cracking and hydrogenating oils. NAAMLOOZE VENNOOTSCHAP DE BATAAFSCHE PETROLEUM MAATSCHAPPIJ. Dec. 6, 1938, No. 35561. Convention date, Dec. 17, 1937. [Class 32] [Also in Group IV] Cyclic hydrocarbons are prepared by contacting aliphatic hydrocarbons, both paraffinic and olefinic, having from 6 to 12 carbon atoms, or mixtures containing them at temperatures of about 400-600‹C. with heavy metal salts of molybdic or tungstic acid such as the iron, nickel, cobalt, copper, chromium, and manganese salts. The conversion is preferably effected under a hydrogen pressure exceeding 10, e.g. about 50 atmos. The catalysts may be employed with other catalysts or promoters or on carriers. Aliphatic hydrocarbons of non- branched or only slightly branched structure are particularly suitable starting materials. Gasolines, including hydrogenation, cracking or polymer gasolines or those obtained from carbon monoxide and hydrogen may also be used. The cyclic products have increased octane numbers and are used as gasolines or blending agents therefor. In an example, an octene fraction, obtained by vapour phase cracking of paraffin wax, is passed at 540‹C. and under a hydrogen pressure of 50 atmos over nickel tungstate with a contact time of 40 secs. The liquid product contains 29 per cent. aromatics and 31 per cent. naphthenes by weight. Specifications 400,628 and 483,189 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL522366X | 1937-12-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB522366A true GB522366A (en) | 1940-06-17 |
Family
ID=19787020
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB35561/38A Expired GB522366A (en) | 1937-12-17 | 1938-12-06 | A process for preparing cyclic hydrocarbons from aliphatic hydrocarbons |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB522366A (en) |
-
1938
- 1938-12-06 GB GB35561/38A patent/GB522366A/en not_active Expired
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