GB520505A - Plasticising of polymeric organic sulphides - Google Patents
Plasticising of polymeric organic sulphidesInfo
- Publication number
- GB520505A GB520505A GB30754/38A GB3075438A GB520505A GB 520505 A GB520505 A GB 520505A GB 30754/38 A GB30754/38 A GB 30754/38A GB 3075438 A GB3075438 A GB 3075438A GB 520505 A GB520505 A GB 520505A
- Authority
- GB
- United Kingdom
- Prior art keywords
- disulphide
- disulphides
- thio
- diphenyl
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/14—Polysulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
520,505. Synthetic resins. IMPERIAL CHEMICAL INDUSTRIES, Ltd. Oct. 24, 1938, No. 30754. Convention date, Oct. 22, 1937. [Class 2 (iii)] Polymeric organic sulphides of the type obtained by reacting in an organic sulphide with an organic dihalide in which the halogen atoms are on different carbon atoms are plasticized by treatment before or after curing with an organic mercaptan and an unpolymerisable organic disulphide. There are specified : mercaptansthiophenols, e.g. thio-α- and thio-#-naphthol and their homologues, thiophenol, thiocresol, monothiocatechol, dithioresorcinol, thiosalicylic acid, m-chlorothiophenol, p-phenyethiophenol, nuclear-stearyl thiophenol,- p-mercaptodiphenylmethane, 2:3-dimercaptonaphthalene, 2-mercaptoanthracene, nitrothionaphthol, chlorthionaphthol, and bromthionaphthol ; aliphatic mercaptans, e.g. ethyl, propyl, butyl, amyl, octyl, dodecyl, and oleyl mercaptans and thiocyclohexanol ; disulphides-thiuram disulphides, e.g. tetramethyl-, tetraethyl-, tetrapropyl-, tetrabutyl-, tetraphenyl-, tetranaphthyl-, diphenyl-dimethyl-, diphenyl-diethyl, phenyl-ethyl-dimethyl phenyl-methyl-diethyl-, methylene-dimethyl-, methylene-diphenyl-, ethylidene - dibenzyl - , propylidene - diethyl - , butylidene-dimethyl, butylidene-di-o-tolyl, dipentamethylene-, butylidene-diethyl-, propylidene-dimethyl-, di-(phenyl-methyl)-, and di- (phenyl-ethyl)-thiuram disulphides; diaryl disulphides, e.g. diphenyl, ditolyl, and dinaphthyl disulphides; arylene-thiazyl disulphides, e.g. benzothiazyl disulphide. The polymeric organic sulphides may be prepared by reacting inorganic mono- or poly-sulphides, e.g. sodium polysulphide, with #-#<SP>1</SP>-dichlordiethyl ether, glycerol α:γ-dichlorhydrin, α:#-dichlorethyl ether, dichlormethyl ether, ethylene dichloride or dibromide, propylene dichloride, 1:4-dichlor- 2-butene, di-#-chlorethyl acetal. The quantity of mercaptan and disulphide used may be 0.05 to 1 per cent. of the polymer, which may be milled with them, or treated with them in solution, e.g. in benzene, with or without mixing, or in a dispersion which is afterwards coagulated, between 10 and 60‹C.- The products, which may be compounded with rubber, or with usual rubber mix ingredients, e.g. zinc oxide; carbon or channel black, benzoylperoxide, zinc chloride, or zinc propionate, may be used in coating and impregnating compositions, adhesives, or elastic articles. In examples : the reaction product of sodium polysulphide and #:#<SP>1</SP>-dichlordiethyl ether is treated with thio-#-naphthol and tetramethyl-thiuram, diphenyl, or benzothiazyl disulphide or octyl mercaptan and tetramethylthiuram disulphide in a rubber mill ; the reaction product of sodium polysulphide and glycerol α-γ-dichlorhydrin is likewise treated with thio-#-naphthol and tetramethyl-thiuram disulphide ; a cured mix of the reaction product of sodium polysulphide and #-#<SP>1</SP>-dichlordiethyl ether, zinc oxide, diphenylguanidine, benzothiazyl disulphide, stearic acid and carbon black was treated with thio-#-naphthol and tetramethyl thiuram disulphide in benzene. Specifications 446,173 and 453,850 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US520505XA | 1937-10-22 | 1937-10-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB520505A true GB520505A (en) | 1940-04-25 |
Family
ID=21975110
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30754/38A Expired GB520505A (en) | 1937-10-22 | 1938-10-24 | Plasticising of polymeric organic sulphides |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB520505A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2510808A (en) * | 1945-03-21 | 1950-06-06 | Standard Oil Dev Co | Plasticizing isobutylene-diolefin rubber |
-
1938
- 1938-10-24 GB GB30754/38A patent/GB520505A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2510808A (en) * | 1945-03-21 | 1950-06-06 | Standard Oil Dev Co | Plasticizing isobutylene-diolefin rubber |
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