GB509325A - - Google Patents

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Publication number
GB509325A
GB509325A GB509325DA GB509325A GB 509325 A GB509325 A GB 509325A GB 509325D A GB509325D A GB 509325DA GB 509325 A GB509325 A GB 509325A
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United Kingdom
Prior art keywords
catalyst
potassium carbonate
sulphur
carbonate
dried
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
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Publication of GB509325A publication Critical patent/GB509325A/en
Expired legal-status Critical Current

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  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

5 0 9 , 3 2 5. Catalysts; motor fuel. MYDDLETON, W. W. Jan. 22, 1938, No. 2167. [Classes 1 (i) and 91] [Also in Group IV] In the synthesis of hydrocarbon oils from carbon-monoxide and hydrogen, an alkali metal carbonate is added to the catalyst and sulphur is introduced with the gases into the reaction chamber. Blue water gas freed from H2S, but still containing organic sulphur compounds equivalent, for example, to 25 grains of sulphur per 100 c. ft., may be passed at 180-210‹ C. over a cobalt catalyst to which potassium carbonate has been added. The motor spirit fraction of the product may be blended with, for example, 20 per cent by volume of benzol and lead tetraethyl. The catalyst may be prepared by mixing a hot solution of cobalt and thorium nitrates with kieselguhr, and adding to a hot solution of potassium carbonate. The precipitate is washed and dried, granulated or pelleted, impregnated with aqueous or aqueous-alcoholic potassium or sodium carbonate and dried. The product may contain, for example, 1.7 or 10 per cent potassium carbonate and is reduced in hydrogen at 350- 400‹ C. Specification 322,284, [Class 1 (i)], is referred to.
GB509325D Expired GB509325A (en)

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GB509325A true GB509325A (en) 1900-01-01

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ID=1747743

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GB509325D Expired GB509325A (en)

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GB (1) GB509325A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446426A (en) * 1946-03-01 1948-08-03 Hydrocarbon Research Inc Synthesis of hydrocarbons with sulfur containing catalyst
US2455419A (en) * 1944-10-11 1948-12-07 Standard Oil Co Synthesis of hydrocarbons and regeneration of synthesis catalyst
DE918223C (en) * 1950-05-25 1954-09-20 Metallgesellschaft Ag Process for the detoxification of gases containing carbon oxide and hydrogen
US2717260A (en) * 1952-01-17 1955-09-06 Union Carbide & Carbon Corp Hydrocarbon synthesis

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2455419A (en) * 1944-10-11 1948-12-07 Standard Oil Co Synthesis of hydrocarbons and regeneration of synthesis catalyst
US2446426A (en) * 1946-03-01 1948-08-03 Hydrocarbon Research Inc Synthesis of hydrocarbons with sulfur containing catalyst
DE918223C (en) * 1950-05-25 1954-09-20 Metallgesellschaft Ag Process for the detoxification of gases containing carbon oxide and hydrogen
US2717260A (en) * 1952-01-17 1955-09-06 Union Carbide & Carbon Corp Hydrocarbon synthesis

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