GB506593A - Oil-soluble bismuth salts and process for their production - Google Patents
Oil-soluble bismuth salts and process for their productionInfo
- Publication number
- GB506593A GB506593A GB3327137A GB3327137A GB506593A GB 506593 A GB506593 A GB 506593A GB 3327137 A GB3327137 A GB 3327137A GB 3327137 A GB3327137 A GB 3327137A GB 506593 A GB506593 A GB 506593A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radicle
- oil
- bismuth
- ethyl
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001621 bismuth Chemical class 0.000 title abstract 3
- -1 Bismuth carboxylates Chemical class 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 239000008159 sesame oil Substances 0.000 abstract 2
- 235000011803 sesame oil Nutrition 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 125000003764 2,4-dimethylpentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 abstract 1
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000005916 2-methylpentyl group Chemical group 0.000 abstract 1
- HWSISDHAHRVNMT-UHFFFAOYSA-N Bismuth subnitrate Chemical compound O[NH+]([O-])O[Bi](O[N+]([O-])=O)O[N+]([O-])=O HWSISDHAHRVNMT-UHFFFAOYSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 1
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 abstract 1
- 229930195725 Mannitol Natural products 0.000 abstract 1
- 241000387514 Waldo Species 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- 150000001622 bismuth compounds Chemical class 0.000 abstract 1
- 229940049676 bismuth hydroxide Drugs 0.000 abstract 1
- 229960001482 bismuth subnitrate Drugs 0.000 abstract 1
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003240 coconut oil Substances 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 235000012343 cottonseed oil Nutrition 0.000 abstract 1
- 239000002385 cottonseed oil Substances 0.000 abstract 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000004494 ethyl ester group Chemical group 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 abstract 1
- 229940093471 ethyl oleate Drugs 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000000594 mannitol Substances 0.000 abstract 1
- 235000010355 mannitol Nutrition 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 abstract 1
- 239000004006 olive oil Substances 0.000 abstract 1
- 235000008390 olive oil Nutrition 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000002167 spirocheticidal effect Effects 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
- Lubricants (AREA)
Abstract
506,593. Bismuth carboxylates. LILLY & CO., E., SHONLE, H. A., and WALDO, J. H. Dec. 1, 1937, No. 33271. [Class 1 (iii)] Oil-soluble basic bismuth salts of acids of the formula where R represents a monovalent primary aliphatic radicle having at least 5 carbon atoms and R<1> represents an alkoxy group having not more than 4 carbon atoms, are obtained by reacting the acid or an alkali metal salt thereof with a freshly prepared bismuth compound which is soluble in a water solution of glycol, such as the hydroxide or subnitrate. The term monovalent primary aliphatic radicle is defined as a noncyclic radicle in which the attaching carbon atom is joined to only one other carbon atom of the radicle. It may be the iso-amyl, 2-ethyl-butyl, 2-methylpentyl, 2, 4-dimethyl-pentyl, 2-ethyl-hexyl, decyl, do-decyl (lauryl), octadecyl, or 9, 10- octadecenyl radicle, and the radicle R<1> is preferably the ethyl radicle, though it may be methyl, propyl, or butyl. In carrying out the invention, a solution of bismuth subnitrate in aqueous glycerine or mannitol may be reacted in the cold with the sodium salt of the acid ; or bismuth hydroxide be heated with the acid under reflux in the presence of a little water. In either case the reaction product is extracted with ether or benzene, and then recovered by distilling off the solvent. Solutions in oil of the basic bismuth salts are effective spirocheticidal agents, and may be injected intramuscularly. Bland mineral oils may be used for those compounds wherein R has at least 8 carbon atoms, or vegetable oils such as olive oil, cottonseed oil, coconut oil, or sesame oil, or ethyl oleate or the ethyl ester of the fatty acids of sesame oil may be employed. Specifications 356,550 and 397,249 are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3327137A GB506593A (en) | 1937-12-01 | 1937-12-01 | Oil-soluble bismuth salts and process for their production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3327137A GB506593A (en) | 1937-12-01 | 1937-12-01 | Oil-soluble bismuth salts and process for their production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB506593A true GB506593A (en) | 1939-06-01 |
Family
ID=10350761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3327137A Expired GB506593A (en) | 1937-12-01 | 1937-12-01 | Oil-soluble bismuth salts and process for their production |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB506593A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2796531A4 (en) * | 2011-12-22 | 2015-08-12 | G C Dental Ind Corp | Agent for imparting fluorescence to ceramic |
| US11103085B2 (en) | 2017-09-15 | 2021-08-31 | Guangzhou Lianrou Machinery and Equipment Co., Ltd. | Inclined pocketed spring string and pocketed spring bed core |
-
1937
- 1937-12-01 GB GB3327137A patent/GB506593A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2796531A4 (en) * | 2011-12-22 | 2015-08-12 | G C Dental Ind Corp | Agent for imparting fluorescence to ceramic |
| US11103085B2 (en) | 2017-09-15 | 2021-08-31 | Guangzhou Lianrou Machinery and Equipment Co., Ltd. | Inclined pocketed spring string and pocketed spring bed core |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2623900A (en) | Method for the preparation of polyether acetic acids | |
| GB506593A (en) | Oil-soluble bismuth salts and process for their production | |
| US2759953A (en) | Addition of organic acids to the double bond of unsaturated fatty compounds | |
| US1942827A (en) | Tertiary alkyl substituted orthodihydroxy benzenes | |
| US3169144A (en) | Anticholesterinemic and antilipaemic agents | |
| DE2642670A1 (en) | SYNTHESIS PROCESS FOR 6-POSITION SUBSTITUTED 2,3-DIMETHOXY-5-METHYL-1,4-BENZOQUINONE | |
| DE1793264A1 (en) | Substituted phenylacetic acids and process for their preparation | |
| DE2363464C3 (en) | Process for the preparation of p-alkenylphenols | |
| US2153513A (en) | Reaction products of 2-methyl-1, 3-dichloropropane and alcohols | |
| US2501649A (en) | Benzotriazole compound | |
| SILVERMAN et al. | The synthesis of some indene and dihydronaphthalene derivatives related to stilbestrol | |
| US2198357A (en) | Bismuth alpha ethyl-n-caproate and a process of making it | |
| US3344168A (en) | N, n-diethyl-2-aminoethyl 2-substituted oxyisobutyrate | |
| US2122409A (en) | Esters of para-hydroxyphenyliminodiacetic acid | |
| DE711069C (en) | Process for the preparation of basic esters | |
| US2142957A (en) | Oil-soluble bismuth salt and process of producing it | |
| DE2240298A1 (en) | LUBRICANT MIXTURE | |
| US2219543A (en) | Tmobarbituric acm derivatives | |
| DE1237104B (en) | Process for the preparation of 2, 6- or 2, 7-di- (tert-butyl) -naphthalene-4-sulfonic acid esters | |
| US3535374A (en) | Preparation of amino carboxylic acid salts | |
| US2207612A (en) | Ethers of substituted acyl-phenols | |
| US2476165A (en) | Alpha, alpha'-trithiocarbonodialiphatic acids | |
| GB402762A (en) | Process for the manufacture of new organic salts of bismuth and oleaginous solutions thereof | |
| DE1134385B (en) | Process for producing a borazole derivative | |
| US3853928A (en) | Process for preparing tertiary phosphoric esters of phenolated fatty acid esters |