GB498874A - Improvements in colour photographic elements - Google Patents

Improvements in colour photographic elements

Info

Publication number
GB498874A
GB498874A GB34977/38A GB3497738A GB498874A GB 498874 A GB498874 A GB 498874A GB 34977/38 A GB34977/38 A GB 34977/38A GB 3497738 A GB3497738 A GB 3497738A GB 498874 A GB498874 A GB 498874A
Authority
GB
United Kingdom
Prior art keywords
developed
red
layer
infra
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34977/38A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kodak Ltd
Original Assignee
Kodak Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kodak Ltd filed Critical Kodak Ltd
Publication of GB498874A publication Critical patent/GB498874A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09CCIPHERING OR DECIPHERING APPARATUS FOR CRYPTOGRAPHIC OR OTHER PURPOSES INVOLVING THE NEED FOR SECRECY
    • G09C5/00Ciphering apparatus or methods not provided for in the preceding groups, e.g. involving the concealment or deformation of graphic data such as designs, written or printed messages
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/26Silver halide emulsions for subtractive colour processes

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Color Television Image Signal Generators (AREA)

Abstract

498,874. Colour photography. KODAK, Ltd. May 10, 1937, No. 34977/38. Convention date, May 9, 1936. Divided out of 500,826. [Class 98 (ii)] A sensitive photographic element has three silver halide emulsions respectively sensitized to three separate colours covering substantially the whole of the visible spectrum, and one of the emulsions sensitized to yellow-green or to orange-red by means of a sensitizer is also sensitized to another region, for example the infra-red, by means of another sensitizer, for example neocyanine or cryptocyanine resistant to developing or developing and oxidizing baths. The element may have blue-sensitive, yellow-green sensitive, and redsensitive emulsion layers superimposed on a support, the blue-sensitive layer being uppermost, or the middle emulsion layer may be orange-red-sensitive and the lowermost emulsion layer yellow-green sensitive. The red or the yellow green-sensitive emulsion layer may be on one side of the support and the other two layers on the other side. Alternatively, the element may have two layers on the same or different sides of the support, one containing two sets of silver halide grains respectively sensitized for red and green, while the other consists of not specially sensitized silver halide. The lowest layer in a three-layer element may contain a colour sensitizer resistant to development and the middle layer an additional infra-red sensitizer resistant to development. After exposure, the superimposed latent images are developed by an ordinary non-tanning developer such as ferrous oxalate, amidol and diamido-o-cresol. Organic developers containing sodium carbonate may be used and colour sensitivity restored by treatment with alkali sulphite or bisulphite. All three layers may first be saturated in a strong solution of the developing agent and development effected in solutions of sodium carbonate, ammonia, alkali bicarbonate, borax, trisodium phosphate, or sodium aminoacetate. Alternatively, concentrated developing solution may be allowed to diffuse into all the layers at a low temperature and development started or accelerated by warming. The residual silver halide may be used for reversal development or converted in one or more layers to silver chloride in a fine state of subdivision by treatment with potassium ferricyanide and sodium chloride or with lead chloride or with mercuric chloride. The removal of the initially reduced silver may be effected with oxidizing agents. The lower layer is exposed to red light and developed blue-green, and the middle layer is exposed through the uniformly blackened lower layer to infra-red light. The upper layer is exposed to blue or ultra-violet light or soft-X-rays and colour developed and the silver finaly removed from all the layers. If two ultra-violet filter layers are arranged on both sides of the middle layer, and the latter contains an infra-red sensitizer, the outer layers are exposed to ultra-violet light and colour developed and then the middle layer exposed to infra-red light and colour developed. The middle layer may be of silver chloride and contain an infra-red sensitizer, and is then developed black with a weak developer, exposed to infra-red light and colour developed. The latent images in the outer layers are developed and then successively exposed and colour developed, the developed silver in the middle layer acting as a screen. The upper or middle emulsion may be of silver chloride and this or the bottom emulsion may contain an infra-red sensitizer stable to the developer and to mild oxidizing agents. The residual silver halide of such an emulsion is made developable by infra-red light. Any other sensitizer for which the middle emulsion is insensitive may be added to the lower emulsion. An infra-red sensitizer stable to the developer may be added to the red-sensitized lowermost emulsion, the element developed, the residual silver bromide of the lowermost layer exposed to infra-red light and colour developed, and the other two emulsions made developable with thiourea or other fogging agent. The silver chloride and bromide emulsions are then selectively colour developed. A two layer element may comprise a blue-sensitive silver chloride emulsion layer and a mixed grain layer comprising green-sensitive grains and grains both red and infra-red sensitized, the infra-red sensitizer being stable to development. After general black development, the mixed grain layer is exposed to infra-red light and developed blue-green. The residual silver halide is made developable by thiourea or other fogging agent and the silver chloride developed yellow. The silver bromide of the other grains is developed purple and all silver removed. If the blue-sensitive emulsion is of silver bromide, the green-sensitizer is stable to development and the residual silver bromide of the green-sensitized layer developed purple after exposure to yellow-green light. The blue-sensitive emulsion is exposed to ultra-violet light and developed yellow. If the blue-sensitive emulsion is on the other side of the film, the image in the red-sensitized grains is developed to blue-green after the second exposure, and the images in the bluesensitive emulsion and the yellow-green sensitized grains rendered developable by thiourea or other fogging 'agent and selectively colour developed. Specification 427,519 is referred to.
GB34977/38A 1936-05-09 1937-05-10 Improvements in colour photographic elements Expired GB498874A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT498874X 1936-05-09

Publications (1)

Publication Number Publication Date
GB498874A true GB498874A (en) 1939-01-10

Family

ID=3675279

Family Applications (1)

Application Number Title Priority Date Filing Date
GB34977/38A Expired GB498874A (en) 1936-05-09 1937-05-10 Improvements in colour photographic elements

Country Status (1)

Country Link
GB (1) GB498874A (en)

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