GB472170A - Manufacture of substitution products of diphenylene oxide - Google Patents
Manufacture of substitution products of diphenylene oxideInfo
- Publication number
- GB472170A GB472170A GB800036A GB800036A GB472170A GB 472170 A GB472170 A GB 472170A GB 800036 A GB800036 A GB 800036A GB 800036 A GB800036 A GB 800036A GB 472170 A GB472170 A GB 472170A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diphenylene oxide
- nitro
- methoxy
- diphenylene
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/91—Dibenzofurans; Hydrogenated dibenzofurans
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The 2-nitro-3-alkoxy derivatives of diphenylene oxide are prepared by the action of nitrating agents upon 3-alkoxy diphenylene oxides which may also contain substituents in the 5-, 6-, 7- or 8-position. The starting materials are obtainable by the process described in Specification 470,021. By reduction of the 2-nitro-3-alkoxy compounds in known manner, the corresponding 2-amino-3-alkoxy compounds are obtained. Examples are given of the preparation of (1) 2-nitro-3-methoxy-diphenylene oxide from 3-methoxy-diphenylene oxide, obtained by methylation of the corresponding hydroxy compound; (2) 2-nitro-3-ethoxy-diphenylene oxide from 3-ethoxy-diphenylene oxide, obtained by ethylation of the corresponding hydroxy compound; (3) 2-nitro-3-methoxy-7-methyl-diphenylene oxide from 3-methoxy-7-methyl-diphenylene oxide, obtained by methylation of 3-hydroxy-7-methyl-diphenylene oxide; (4) 2 - nitro - 3 - methoxy - 7 - chloro - diphenylene oxide from 3 - hydroxy - 7 - chloro - diphenylene oxide by the same steps as in (3); (5) 2-nitro-3 : 7-dimethoxy-diphenylene oxide from 3 : 7-dimethoxy-diphenylene oxide, obtained by methylation of the 3 : 7-dimethoxy- or the 3-hydroxy-7-methoxy-derivatives; (6) 2-nitro-3-methoxy-6-methyl-diphenylene oxide from 3-hydroxy-6-methyl-diphenylene oxide. The preparation of the corresponding amino-derivatives is described in each case.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB800036A GB472170A (en) | 1936-03-17 | 1936-03-17 | Manufacture of substitution products of diphenylene oxide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB800036A GB472170A (en) | 1936-03-17 | 1936-03-17 | Manufacture of substitution products of diphenylene oxide |
Publications (1)
Publication Number | Publication Date |
---|---|
GB472170A true GB472170A (en) | 1937-09-17 |
Family
ID=9843856
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB800036A Expired GB472170A (en) | 1936-03-17 | 1936-03-17 | Manufacture of substitution products of diphenylene oxide |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB472170A (en) |
-
1936
- 1936-03-17 GB GB800036A patent/GB472170A/en not_active Expired
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