GB469022A - New fungicidal and bactericidal agents - Google Patents
New fungicidal and bactericidal agentsInfo
- Publication number
- GB469022A GB469022A GB136036A GB136036A GB469022A GB 469022 A GB469022 A GB 469022A GB 136036 A GB136036 A GB 136036A GB 136036 A GB136036 A GB 136036A GB 469022 A GB469022 A GB 469022A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ether
- mercuric
- parts
- mercury
- ethyleneglycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003899 bactericide agent Substances 0.000 title abstract 2
- 230000000855 fungicidal effect Effects 0.000 title abstract 2
- 239000000417 fungicide Substances 0.000 title abstract 2
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 abstract 12
- 229940101209 mercuric oxide Drugs 0.000 abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 5
- 229940100892 mercury compound Drugs 0.000 abstract 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 239000000454 talc Substances 0.000 abstract 4
- 229910052623 talc Inorganic materials 0.000 abstract 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 3
- 239000005977 Ethylene Substances 0.000 abstract 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 3
- BRMYZIKAHFEUFJ-UHFFFAOYSA-L mercury diacetate Chemical compound CC(=O)O[Hg]OC(C)=O BRMYZIKAHFEUFJ-UHFFFAOYSA-L 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 244000075850 Avena orientalis Species 0.000 abstract 2
- 235000007319 Avena orientalis Nutrition 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 229960000583 acetic acid Drugs 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 239000012362 glacial acetic acid Substances 0.000 abstract 2
- 235000011187 glycerol Nutrition 0.000 abstract 2
- 150000002431 hydrogen Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical group O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 abstract 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 abstract 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical group COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 abstract 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 abstract 1
- CUZKCNWZBXLAJX-UHFFFAOYSA-N 2-phenylmethoxyethanol Chemical compound OCCOCC1=CC=CC=C1 CUZKCNWZBXLAJX-UHFFFAOYSA-N 0.000 abstract 1
- XHMWPVBQGARKQM-UHFFFAOYSA-N 3-ethoxy-1-propanol Chemical compound CCOCCCO XHMWPVBQGARKQM-UHFFFAOYSA-N 0.000 abstract 1
- 208000003643 Callosities Diseases 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 206010020649 Hyperkeratosis Diseases 0.000 abstract 1
- 240000008042 Zea mays Species 0.000 abstract 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract 1
- WRYNUJYAXVDTCB-UHFFFAOYSA-M acetyloxymercury Chemical compound CC(=O)O[Hg] WRYNUJYAXVDTCB-UHFFFAOYSA-M 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000012267 brine Substances 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 235000005822 corn Nutrition 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 abstract 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 229940093476 ethylene glycol Drugs 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000002649 immunization Methods 0.000 abstract 1
- 230000003053 immunization Effects 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Organo-mercury compounds of the formula R--[O--Alk]n--O--C2H2R<1>2--Hg--X in which R represents alkyl or aralkyl, R<1> signifies hydrogen, alkyl or aryl, n is 1 or 2, Alk stands for an alkylene residue and X represents hydroxyl or a salt-forming group, are prepared by reacting a mercuric salt, or mercuric oxide and a mercuric acid, with an olefinic compound C2H2R<1>2 in the presence of an ether-alcohol R--[O--Alk]n--OH containing no halogen. The mercuric salt may be formed in situ from yellow mercuric oxide and an acid, and the residue X may be exchanged by double decomposition. The products are useful as fungicidal and bactericidal agents and may be applied, either as dusts in admixture with carriers such as talc or in the form of aqueous solutions or dispersions. Examples are given of the interaction of (1) ethyleneglycol monoethyl ether, ethylene, and mercury acetate; instead of the said ether, ethyleneglycol monomethyl or monobutyl ether or diethyleneglycol monoethyl ether may be used and yellow mercuric oxide may be employed in addition to mercuric acetate; treatment of the product with sodium chloride yields the corresponding mercury chloride compound; (2) ethyleneglycol monoethyl ether, ethylene, yellow mercuric oxide and glacial acetic acid; (3) ethyleneglycol monomethyl or monoethyl ether, propylene, mercuric acetate and yellow mercuric oxide; addition of brine forms the chloride of the product; (4) ethyleneglycol monobenzyl ether, ethylene, yellow mercuric oxide and glacial acetic acid; the product is treated with brine; (5) ethyleneglycol monoethyl ether, styrene and mercuric acetate, and reaction of the product with oxalic acid. Other olefines mentioned are butylene and phenylethylene, and as ether alcohols diethyleneglycol monomethyl ether and trimethyleneglycol monoethyl ether are also specified. Reference is made to a dust composition for treating oats comprising 3 parts by weight of the organo-mercury compound, 3 parts of glycerine and 94 parts of talc. Specifications 335,527, [Class 81 (i)], 411,507, and 427,974 are referred to.ALSO:Compositions for the immunization or preservation of seeds, bulbs, tubers, corns, &c. consist of organo-mercury compounds of the formula R-[O-Alk]n-O-C2H2R12-Hg-X in which R represents alkyl or aralkyl, R1 signifies hydrogen, alkyl or aryl, n is 1 or 2, Alk stands for an alkylene residue and X represents hydroxyl or a salt-forming group, together with an inert carrier such as talc, or comprise an aqueous solution or dispersion of the organo-mercury compound containing wetting and spreading agents. Thus, a mixture of 3 parts by weight of organo-mercury compound, 3 parts of glycerine and 94 parts of talc may be used for the treatment of oat seed infected with leaf stripe.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB136036A GB469022A (en) | 1936-01-15 | 1936-01-15 | New fungicidal and bactericidal agents |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB136036A GB469022A (en) | 1936-01-15 | 1936-01-15 | New fungicidal and bactericidal agents |
Publications (1)
Publication Number | Publication Date |
---|---|
GB469022A true GB469022A (en) | 1937-07-15 |
Family
ID=9720661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB136036A Expired GB469022A (en) | 1936-01-15 | 1936-01-15 | New fungicidal and bactericidal agents |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB469022A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3058877A (en) * | 1960-09-09 | 1962-10-16 | Chicopee Mfg Corp | Germicidal, bactericidal and fungicidal compositions |
-
1936
- 1936-01-15 GB GB136036A patent/GB469022A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3058877A (en) * | 1960-09-09 | 1962-10-16 | Chicopee Mfg Corp | Germicidal, bactericidal and fungicidal compositions |
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