GB467901A - Improvements in or relating to moistureproofing compositions and articles produced tberefrom - Google Patents

Improvements in or relating to moistureproofing compositions and articles produced tberefrom

Info

Publication number
GB467901A
GB467901A GB35470/35A GB3547035A GB467901A GB 467901 A GB467901 A GB 467901A GB 35470/35 A GB35470/35 A GB 35470/35A GB 3547035 A GB3547035 A GB 3547035A GB 467901 A GB467901 A GB 467901A
Authority
GB
United Kingdom
Prior art keywords
ether
carbon atoms
ester
moisture
thio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35470/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Cellophane Ltd
Original Assignee
British Cellophane Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Cellophane Ltd filed Critical British Cellophane Ltd
Publication of GB467901A publication Critical patent/GB467901A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/046Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/043Improving the adhesiveness of the coatings per se, e.g. forming primers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/048Forming gas barrier coatings

Abstract

The moisture-proofing constituent of the coating applied to transparent wrapping foils &c. consists of a solid alcohol, carboxylic acid, ketone, ether, poly-ether, ether-ester, organometallic compound, thio compound, amide, or halogen hydrocarbon derivative. The compound must have a melting-point not less than 37 DEG C., and must conform to a prescribed test for moisture-proofness; and it must also have a minimum hydrocarbon carbon content which in the case of one substituting group is for an alcohol, 20 carbon atoms, for a ketone 20 carbon atoms, for an amide 17 carbon atoms, for an halogen hydrocarbon 18 carbon atoms, and for a thio compound 16 carbon atoms; when a second substituting group which may be the same as or different from the first, is present, the minimum value of the ratio of hydrocarbon carbon to substituting group may be decreased to say 55--65 per p cent of the above-stated values, and so on with further substituting groups, there being a limiting value of 30 per cent; in the case of a poly-ester the molecule must contain at least 11 hydrocarbon carbon atoms per ether oxygen atom, with an ether-ester at least 10 carbon atoms in the ether part and at least 13 carbon atoms in the ester part, and with an organo-metallic compound at least 8 carbon atoms per valence of the metallic constituent, these minimum values being subject to the above-stated adjustments when substituting groups are present. The following are specified moisture-proofing compounds; ceryl alcohol, montanyl alcohol, diheptadecyl carbinol, methylphenyl stearyl carbinol, cerotic acid, montanic acid, melissic acid, dicetyl ether, distearyl ether, beta-naphthyl stearyl ether, diphenyl lignoceryl ether, diphenoxydecane, ethylene glycol di-betanaphthyl ether, naphthyl stearyl ether of ethylene glycol, dinaphthoxydiethyl ether, diethylene glycol diceryl ether, phenoxyethylstearate, naphthoxyethylstearate, distearate of diphenylolpropane glycol ether, dicerotate of bis-hydroxyethyl ether of resorcinol, stearoxyethyl stearate, ceroxyethyl benzoate, diethylene glycol dicerotate, laurone, stearone, myristone, cerotone, stearamide, n-butyl stearamide, stearanilide, chloro-triacontane, ceryl bromide, di-heptadecylmethyl chloride, distearyl mecury, tetralauryl tin, tetracetyl lead, diceryl mercury, stearyl mercaptan, ceryl mercaptan, dinaphthyl thio-ether, and dicetyl thio-ether. The coating also contains a film-forming substance, for instance, a cellulose ester or ether, a natural or synthetic resin, rubber, guttapercha, balata, synthetic rubber, halogenated rubber &c., or a mixture of such substances; and it may contain a softener or plasticizer, and in the case of cellulose ester &c. compositions a blending-agent to obviate haziness, such agent being for example gums, resins, hydrogenated ester gum, halogenated diphenyl, a natural balsam or a synthetic balsam such as diethylene glycol hydrorosinate, lanum, hydrogenated castor oil, dilauryl phthalate, retene, and glycerol diricinoleate. The constituents may be dissolved in an appropriate solvent and so applied, or they may be used in the form of a melt, in which case, a blending-agent to prevent crystallization may be added, suitable agents being hydrogenated rubber, and ester gum, rosin, gum, dammar, and diethylene glycol hydrorosinate. The base film or foil to be coated may be of regenerated cellulose, glycol cellulose, cellulose glycollic acid, low esters or ethers of cellulose, cellulose acetate and nitrate, ethyl or benzyl cellulose, gelatine, casein, rubber and rubber derivatives. Specifications 283,109, [Class 140], 344,833, [Group XVII], and 401,534 are referred to. The Specification as open to inspection under Sect. 91, refers to the addition of the moisture-proofing compounds to the compositions used for making the films &c., to the use of the compositions for coating steel and other corrodible metals, paper, leather, fabrics &c. This subject-matter does not appear in the Specification as accepted.ALSO:Moisture-proofing compositions having a basis of resins, rubber, guttapercha, balata, halogenated rubber, &c. contain as the moisture-proofing constituent a solid alcohol, carboxylic acid, ketone, ether, poly-ether, ether-ester, organo-metallic compound, thio compound, amide or halogen hydrocarbon derivative. The compound must have a melting point not less than 37 DEG C., and must conform to a prescribed test for moisture-proofness; and it must also have a minimum hydrocarbon carbon content which in the case of one substituting group is for an alcohol and a ketone 20 carbon atoms, for an amide 17 carbon atoms, for an halogen hydrocarbon 18 carbon atoms, and for a thio compound 16 carbon atoms; when a second substituting group, which may be the same as or different from the first, is present, the minimum value of the ratio of hydrocarbon carbon to substituting group may be decreased to say 55--65 per cent of the above-stated values, and so on with further substituting groups, there being a limiting value of 30 per cent; and in the case of a poly-ether the molecule must contain at least 11 hydrocarbon carbon atoms per ether oxygen atom, with an ether-ester at least 10 carbon atoms in the ether part and at least 13 carbon atoms in the ester part, and with an organo-metallic compound at least 8 carbon atoms per valence of the metallic constituent, these minimum values being subject to the above-stated adjustments when substituting groups are present. The following are specified moisture-proofing compounds:-- ceryl alcohol, montanyl alcohol, diheptadecyl carbinol, methylphenyl stearyl carbinol, cerotic acid, montanic acid, melissic acid, dicetyl ether, distearyl ether, beta-naphthylstearyl ether, diphenyl lignoceryl ether, diphenoxydecane, ethylene glycol di-betanaphthyl ether, naphthylstearyl ether of ethylene glycol, dinaphthoxydiethyl ether, diethylene glycol diceryl ether, phenoxyethyl stearate, naphthoxyethyl stearate, distearate of diphenylolpropane glycol ether, dicerotate of bis-hydroxyethyl ether of resorcinol, stearoxyethyl stearate, ceroxyethyl benzoate, diethylene glycol dicerotate, laurone, myristone, cerotone, stearamide, n-butyl stearamide, stearanilide, chlorotriacontane, ceryl bromide, diheptadecylmethyl chloride, distearyl mercury, tetralauryl tin, tetracetyl lead, diceryl mercury, stearyl mercaptan, ceryl mercaptan, di-naphthyl thio-ether and dicetyl thio-ether. The composition may contain a softener or plasticizer, and substances such as gums, hydrogenated rubber or ester gum, rosin, gum dammar, and diethylene glycol hydrorosinate. The constituents of the composition may be dissolved and applied as a solution, or they may be used in the form of a melt. The Specification as open to inspection under Sect. 91 refers to the use of the compositions for coating steel and other metal articles, paper, leather, fabrics, &c. This subject-matter does not appear in the Specification as accepted.ALSO:The moisture-proofing constituent of the coating applied to transparent indiarubber films &c. consists of a solid alcohol, carboxylic acid, ketone, ether, poly-ether, ether-ester, organo-metallic compound, thio compound, amide, or halogen hydrocarbon derivative. The compound must have a melting point not less than 37 DEG C., and must conform to a prescribed test for moisture-proofness; and it must also have a minimum hydrocarbon carbon content which in the case of one substituting group is for an alcohol 20 carbon atoms, for a ketone 20 carbon atoms, for a halogen hydro-carbon 18 carbon atoms, for an amide 17 carbon atoms, and for a thio compound 16 carbon atoms; when a second substituting group, which may be the same as or different from the first, is present, the minimum value of the ratio of hydrocarbon carbon to substituting group may be decreased to say 55-65 per cent of the above-stated values, and so on with further substituting groups there being a limiting value of 30 per cent; in the case of a poly-ether, the molecule must contain at least 11 hydrocarbon carbon atoms per ether oxygen atom, with an etherester at least 10 carbon atoms in the ether part and at least 13 in the ester part, and with an organo-metallic compound at least 8 carbon atoms per valence of the metallic constituent, these minimum values being subject to the above-stated adjustments when substituting groups are present. The following are specified moisture-proofing compounds: ceryl alcohol, montanyl alcohol, diheptadecylcarbinol, methylphenyl stearyl carbinol, cerotic acid, montanic acid, melissic acid, dicetyl ether, distearyl ether, beta-naphthyl stearyl ether, diphenyl lignoceryl ether, diphenoxydecane, ethylene glycol di-betanaphthyl ether, naphthylstearyl ether of ethylene glycol, dinaphthoxy diethyl ether, diethylene glycol diceryl ether, phenoxyethyl stearate, naphthoxyethyl stearate, distearate of diphenylolpropane glycol ether, dicerotate of bis-hydroxyethyl ether of resorcinol, stearoxyethyl stearate, ceroxyethyl benzoate, diethylene glycol dicerotate, laurone, stearone, myristone, cerotone, stearamide, n-butyl stearamide, stearanilide, chlorotriacontane, ceryl bromide, di-heptadecylmethyl chloride, distearyl mercury, tetralauryl tin, tetracetyl lead, diceryl mercury, stearyl mercaptan, ceryl mercaptan, di-naphthyl thio-ether, and dicetyl thio-ether. The coating also contains a film-forming substance, for instance, a cellulose ester or ether, a natural or synthetic resin, rubber, guttapercha, balata, synthetic rubber, halogenated rubber, &c., or a mixture of such substances; and it may contain a softener or plasticizer and agents which have the effect of preventing haziness or inhibit crystallization. The coating may be applied as a solution or in the form of a melt. The Specification as open to inspection under Sect. 91, refers to the addition of the moisture-proofing compounds to the compositions used for ma
GB35470/35A 1934-12-21 1935-12-21 Improvements in or relating to moistureproofing compositions and articles produced tberefrom Expired GB467901A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US467901XA 1934-12-21 1934-12-21

Publications (1)

Publication Number Publication Date
GB467901A true GB467901A (en) 1937-06-21

Family

ID=21945407

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35470/35A Expired GB467901A (en) 1934-12-21 1935-12-21 Improvements in or relating to moistureproofing compositions and articles produced tberefrom

Country Status (1)

Country Link
GB (1) GB467901A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3232791A (en) * 1961-12-22 1966-02-01 Du Pont Regenerated cellulose film having a moistureproof coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3232791A (en) * 1961-12-22 1966-02-01 Du Pont Regenerated cellulose film having a moistureproof coating

Similar Documents

Publication Publication Date Title
US1805458A (en) Oil composition and process of inhibiting oxidation thereof
US2311488A (en) Method of depositing rubber and composition employed therein
GB467901A (en) Improvements in or relating to moistureproofing compositions and articles produced tberefrom
GB450454A (en) Improvements in the manufacture of plastic and coating compositions having a basis of cellulose ester or ether
US2445374A (en) Stabilization of cellulose ethers
US2098538A (en) Moistureproof article
US2226823A (en) Cellulose ether composition
US2216827A (en) Cellulose derivative compositions of matter and articles produced therefrom
US2128652A (en) Transparent coated sheet material
US2471272A (en) Water-soluble cellulose ether plasticized with a cyclomethylene sulfone
US2311609A (en) Hot-melt coating composition
US1981141A (en) Cementing foil and thin film
US2098534A (en) Moistureproof article
US2561892A (en) Stabilization of ethyl cellulose
US1975179A (en) Coating material
US1930134A (en) Cellulose organic ester composition containing propylene chloride
US2073310A (en) Waterproofing composition
US1548932A (en) Cellulose-acetate composition
SE7605461L (en) AUTOXIDABLE COATING COMPOSITION AND WAY TO APPLY IT TO A SUPPORT MATERIAL
US1997337A (en) Cellulose higher acyl radical lacquers
US1886775A (en) Plastic cellulose compound
US1642766A (en) Waterproof abrasive fabric and method of making the same
US2194291A (en) Stencil coating compound and process of making the same
US1844714A (en) Cellulosic composition of matter containing an amide or derivative thereof
US1405490A (en) Cellulose-ether composition