GB467571A - Improvements in the manufacture and production of condensation products - Google Patents

Improvements in the manufacture and production of condensation products

Info

Publication number
GB467571A
GB467571A GB3486435A GB3486435A GB467571A GB 467571 A GB467571 A GB 467571A GB 3486435 A GB3486435 A GB 3486435A GB 3486435 A GB3486435 A GB 3486435A GB 467571 A GB467571 A GB 467571A
Authority
GB
United Kingdom
Prior art keywords
product
ethylene oxide
further reacted
dihydroabietinol
heated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3486435A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB3486435A priority Critical patent/GB467571A/en
Publication of GB467571A publication Critical patent/GB467571A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Condensation products are obtained by reacting resin alcohols, e.g. abietinol, di- and tetrahydroabietinol, or resin amines, e.g. abietinylmethylamine or their acyl derivatives, e.g. acetyl-abietinylamine, containing the groups --NH-- or NH2, with alkylene oxides, e.g. ethylene-, propylene- or butylene oxides, epichlorhydrin, glycide or glycidic acid. The process is preferably carried out while heating and, if desired, with the addition of alkalinereacting or reactive substances having catalytic action, e.g. sodium hydroxide, potassium hydroxide, sodium acetate, sodium ethylate, bleaching earth, e.g. tonsil, or active carbon. The products may be used as alcohol-soluble resins, softening-agents for lacquers &c., carriers for perfumes and dispersing agents. Products with free terminal hydroxyl groups may be further reacted, e.g. with sulphonating agents, e.g. sulphuric or chlorsulphonic acids, or condensed with carboxylic acids, e.g. chloracetic acid, glycocoll or maleic acids. In examples: (1) dihydroabietinol is heated with potassium hydroxide to 120--160 DEG C. in a stirring autoclave and ethylene oxide is pressed into the melt in portions under a pressure of 2--10 atmospheres to produce a sticky resin soluble in alcohol, which may be further reacted with phthalic or maleic anhydrides; (2) dihydroabietinol is heated with potassium ethylate to 150--160 DEG C. and ethylene oxide is led in a little at a time in the gas phase to produce a wax-like product which may be further reacted with succinic anhydride to yield a product having good adhesive properties; (3) a resinous, adhesive product is obtained from dihydroabietinol and epichlorhydrin which product may be further reacted with trimethylamine; (4) a mixture of di- and tetra-hydroabietinol, heated with sodium hydroxide to 170 DEG C. is treated with ethylene oxide under pressure to produce a wax-like product or, with increased quantities of ethylene oxide, a water-soluble product useful as a non-foaming levelling agent for dyeing.
GB3486435A 1935-12-16 1935-12-16 Improvements in the manufacture and production of condensation products Expired GB467571A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3486435A GB467571A (en) 1935-12-16 1935-12-16 Improvements in the manufacture and production of condensation products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3486435A GB467571A (en) 1935-12-16 1935-12-16 Improvements in the manufacture and production of condensation products

Publications (1)

Publication Number Publication Date
GB467571A true GB467571A (en) 1937-06-16

Family

ID=10370851

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3486435A Expired GB467571A (en) 1935-12-16 1935-12-16 Improvements in the manufacture and production of condensation products

Country Status (1)

Country Link
GB (1) GB467571A (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2519780A (en) * 1949-08-11 1950-08-22 Monsanto Chemicals Herbicidal formulations
US2555901A (en) * 1949-12-01 1951-06-05 Hercules Powder Co Ltd Reaction products of petroleum hydrocarbon-insoluble pine-wood resin and ethylene oxide
US2610966A (en) * 1949-10-17 1952-09-16 Hollingshead Corp Process for treating tall oil with alkylene oxides
US2623870A (en) * 1950-01-10 1952-12-30 Gen Aniline & Film Corp Quaternary ammonium salts
US2666017A (en) * 1950-07-14 1954-01-12 Monsanto Chemicals Nutrient media containing antifoaming agents
US2683088A (en) * 1952-06-10 1954-07-06 American Cyanamid Co Soft bibulous sheet
US2683089A (en) * 1952-06-10 1954-07-06 American Cyanamid Co Bibulous sheet
US2703797A (en) * 1949-12-15 1955-03-08 Gen Aniline & Film Corp Surface-active compositions
US2724700A (en) * 1951-07-03 1955-11-22 Atlas Powder Co Solid compositions containing urea and polyoxyethylene ethers of resin alcohols
US2742455A (en) * 1951-09-24 1956-04-17 Gen Aniline & Film Corp Production of n, n-polyoxyethylated rosin amines
US2744888A (en) * 1950-08-04 1956-05-08 American Cyanamid Co Ethenoxy n-monoethanolamides of tall oil
US2775528A (en) * 1950-04-08 1956-12-25 Int Paper Canada Manufacture of cellulose
US2778814A (en) * 1957-01-22 Alkyl aryl sulfonic acid amine salt
GB2172005A (en) * 1985-03-04 1986-09-10 Union Camp Corp Alkoxylated rosin amides

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2778814A (en) * 1957-01-22 Alkyl aryl sulfonic acid amine salt
US2519780A (en) * 1949-08-11 1950-08-22 Monsanto Chemicals Herbicidal formulations
US2610966A (en) * 1949-10-17 1952-09-16 Hollingshead Corp Process for treating tall oil with alkylene oxides
US2555901A (en) * 1949-12-01 1951-06-05 Hercules Powder Co Ltd Reaction products of petroleum hydrocarbon-insoluble pine-wood resin and ethylene oxide
US2703797A (en) * 1949-12-15 1955-03-08 Gen Aniline & Film Corp Surface-active compositions
US2623870A (en) * 1950-01-10 1952-12-30 Gen Aniline & Film Corp Quaternary ammonium salts
US2775528A (en) * 1950-04-08 1956-12-25 Int Paper Canada Manufacture of cellulose
US2666017A (en) * 1950-07-14 1954-01-12 Monsanto Chemicals Nutrient media containing antifoaming agents
US2744888A (en) * 1950-08-04 1956-05-08 American Cyanamid Co Ethenoxy n-monoethanolamides of tall oil
US2724700A (en) * 1951-07-03 1955-11-22 Atlas Powder Co Solid compositions containing urea and polyoxyethylene ethers of resin alcohols
US2742455A (en) * 1951-09-24 1956-04-17 Gen Aniline & Film Corp Production of n, n-polyoxyethylated rosin amines
US2683089A (en) * 1952-06-10 1954-07-06 American Cyanamid Co Bibulous sheet
US2683088A (en) * 1952-06-10 1954-07-06 American Cyanamid Co Soft bibulous sheet
GB2172005A (en) * 1985-03-04 1986-09-10 Union Camp Corp Alkoxylated rosin amides

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