GB460725A - Manufacture of dyestuffs - Google Patents
Manufacture of dyestuffsInfo
- Publication number
- GB460725A GB460725A GB2336435A GB2336435A GB460725A GB 460725 A GB460725 A GB 460725A GB 2336435 A GB2336435 A GB 2336435A GB 2336435 A GB2336435 A GB 2336435A GB 460725 A GB460725 A GB 460725A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dyestuffs
- dyestuff
- sulphonic
- carboxylic acid
- free
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
Conversion products of dyestuffs containing metal in complex union are manufactured by reacting an o-oxyazo dyestuff containing metal in complex union and free from sulphonic or carboxylic acid groups with a basic dyestuff, e.g. of the arylmethane series, containing no groups capable of being chromed and preferably free from sulphonic or carboxylic acid groups, e.g. by heating in an aqueous medium, if desired under pressure. The metal compounds of o-oxyazo dyestuffs may be made by treating the dyestuffs in acid, neutral or alkaline medium in an open vessel or under pressure, in the presence or absence of additional substances such as salts of organic or inorganic acids or the free acids, e.g. sodium formate, benzenesulphonate, naphthalenesulphonates, sodium acetate, sodium chloride, sodium sulphate, formic, acetic or tartaric acid. The products may be used for colouring masses, or solutions thereof, of the kinds enumerated in Specification 455,320, if desired with the further additions specified therein. In examples : (1) the cobalt compound of the dyestuff 4-nitro-2-aminophenol --> acetoacetic anilide is refluxed in aqueous solution with Rhodamine 6G extra; the product is dissolved in a nitrocellulose lacquer to produce an orange coating; (2) the cobalt compound of the dyestuff 4 - nitro - 2 - aminophenol --> 1 - phenyl - 3 - methyl - 5 - pyrazolone is similarly treated, and the product is similarly employed; (3) the metalliferous dyestuff of (2) is refluxed in dilute caustic soda solution with Rhodamine B extra; a solution of the product in a nitrocellulose lacquer yields a bluish-red coating; (4) the metalliferous dyestuff of (1) is refluxed in aqueous solution with Brilliant Glacier Blue; the product is dissolved in a nitrocellulose lacquer to yield yellowish-green coatings. Specification 408,492 also is referred to. The Provisional Specification comprises the manufacture of conversion products from dyestuffs in general containing metal in complex union and free from sulphonic or carboxylic acid groups. Chromium, copper, iron, cobalt, nickel, aluminium, manganese, vanadium and titanium compounds of dyestuffs of the anthraquinone, triarylmethane, azine, thiazine and oxazine series, and of natural dyestuffs, e.g. logwood and catechu, are specified. Basic dyes of the azo, thiazine, azine and oxazine series are referred to.ALSO:Masses, or solutions thereof, containing natural polymerization products such as caoutchouc, balata or guttapercha are coloured by means of the products obtained by reacting an o-oxyazo dyestuff containing metal in complex union and free from sulphonic or carboxylic acid groups with a basic dyestuff, e.g. of the arylmethane series, containing no groups capable of being chromed and preferably free from sulphonic or carboxylic acid groups. Specification 408,492 is referred to. The Provisional Specification refers also to metal compounds of dyestuffs of the anthraquinone, triarylmethane, azine, thiazine and oxazine series and of natural dyestuffs, e.g. logwood and catechin, and to basic dyes of the azo, thiazine, azine and oxazine series.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2336435A GB460725A (en) | 1935-08-20 | 1935-08-20 | Manufacture of dyestuffs |
DE1935G0091070 DE693431C (en) | 1935-08-20 | 1935-08-25 | Manufacture of conversion products containing dyes containing complexed metal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2336435A GB460725A (en) | 1935-08-20 | 1935-08-20 | Manufacture of dyestuffs |
Publications (1)
Publication Number | Publication Date |
---|---|
GB460725A true GB460725A (en) | 1937-02-03 |
Family
ID=10194446
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2336435A Expired GB460725A (en) | 1935-08-20 | 1935-08-20 | Manufacture of dyestuffs |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE693431C (en) |
GB (1) | GB460725A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE746839C (en) * | 1939-01-12 | 1944-08-25 | Ig Farbenindustrie Ag | Process for the preparation of metal-containing dye mixtures |
US2901473A (en) * | 1957-05-17 | 1959-08-25 | Sandoz Ltd | Oxazoline and dihydro oxazine monoazo dyestuffs and their metal complex compounds |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1043548B (en) * | 1955-04-21 | 1958-11-13 | Ciba Geigy | Process for the preparation of conversion products of metal-containing azo dyes |
DE1111142B (en) * | 1956-04-18 | 1961-07-20 | Basf Ag | Process for dyeing fiber mixtures which contain fibers made from polyacrylonitrile and / or from its copolymers and fibers which can be colored with anionic dyes |
-
1935
- 1935-08-20 GB GB2336435A patent/GB460725A/en not_active Expired
- 1935-08-25 DE DE1935G0091070 patent/DE693431C/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE746839C (en) * | 1939-01-12 | 1944-08-25 | Ig Farbenindustrie Ag | Process for the preparation of metal-containing dye mixtures |
US2901473A (en) * | 1957-05-17 | 1959-08-25 | Sandoz Ltd | Oxazoline and dihydro oxazine monoazo dyestuffs and their metal complex compounds |
Also Published As
Publication number | Publication date |
---|---|
DE693431C (en) | 1940-07-09 |
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