GB459334A - Manufacture of coloured masses from cellulose derivatives, natural or artificial resins or waxes - Google Patents

Manufacture of coloured masses from cellulose derivatives, natural or artificial resins or waxes

Info

Publication number
GB459334A
GB459334A GB3652/36A GB365236A GB459334A GB 459334 A GB459334 A GB 459334A GB 3652/36 A GB3652/36 A GB 3652/36A GB 365236 A GB365236 A GB 365236A GB 459334 A GB459334 A GB 459334A
Authority
GB
United Kingdom
Prior art keywords
acid
compound
logwood extract
parts
coloured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3652/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gesellschaft fuer Chemische Industrie in Basel CIBA filed Critical Gesellschaft fuer Chemische Industrie in Basel CIBA
Publication of GB459334A publication Critical patent/GB459334A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041Optical brightening agents, organic pigments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Coloring (AREA)

Abstract

In a coloured plastic mass or coloured mass capable of conversion into plastic condition made from cellulose derivatives, natural or artificial resins or waxes, free from oil and containing if desired solvents which are not water-soluble alcohols, there is incorporated a complex metal compound of logwood extract. Suitable metals are chromium, copper, iron, cobalt, nickel, aluminium, manganese, zinc, vanadium, titanium, tungsten, or molybdenum. The metal may be used as hydrate or as salt with an inorganic or organic acid, or as a complex compound with ammonia or pyridine, or as a complex metal compound of logwood extract, and the treatment of the logwood extract may be effected in acid, neutral or alkaline medium. Oxycarboxylic acid, e.g. tartaric acid, formic acid, pyridine, or a salt of an inorganic or organic acid may be present during the formation of the metal compound. More than one metal may be used. The base of the plastic mass may be a cellulose ester or ether, copal, amber, shellac, colophony, carnauba wax, ozokerite, rubber, balata, guttapercha, casein, condensation products of aldehydes with phenols or aromatic amines, or with acid amides, or of polybasic acids with polyhydric alcohols, or polymerization products such as vinyl resin, styrene resin, or acrylic acid resin. The colouring matter may be incorporated by grinding solids together, and may, if desired, be produced in the sheet to be coloured. A fatty acid of high molecular weight, a filler such as barium sulphate, zinc oxide, or titanium oxide, or a softening agent or plasticizer, e.g. tricresyl or triphenyl phosphate, glycerine or castor may be added. In an example, 3 parts of the chromium compound of a highly oxidized logwood extract are ground during 4 hours in a roller mill with 8 parts of tricresyl phosphate and 2 parts of butyl acetate. 90 parts of commercial nitrocellulose lacquer are added and grinding is continued until dispersion is homogeneous. The complex compounds may be made by boiling under a reflux condenser highly oxidized logwood extract and water with potassium bichromate, a mixture of copper sulphate and potassium bichromate or ferric chloride. Other examples describe the colouring of (1) a moulding powder of phenolformaldehyde condensation product with the chromium compound of highly oxidized logwood extract; (2) a lacquer from a phenol-formaldehyde condensation product with the chromiumcopper compound of an oxidized logwood extract; (3) a moulding powder of ureaformaldehyde condensation product with the iron compound of a non-oxidized logwood extract; (4) a nitrocellulose lacquer containing tricresyl phosphate and butyl acetate with the nickel compound obtained by metallizing a mixture of 30 parts of logwood extract and 10 parts of Persian berries; (5) a nitrocellulose lacquer with the copper compound of logwood extract.ALSO:In a coloured plastic mass or coloured mass capable of conversion into plastic condition made from natural or artificial waxes, free from oil and containing, if desired, solvents which are not water-soluble alcohols, there is incorporated a complex metal compound of logwood extract. Suitable metals are chromium, copper, iron, cobalt, nickel, aluminium, manganese, zinc, vanadium, titanium, tungsten, or molybdenum. The metal may be used as hydrate or as salt with an inorganic or organic acid, or as a complex compound with ammonia or pyridine, or as a complex metal compound of logwood extract, and the treatment of the logwood extract may be effected in acid, neutral or alkaline medium. Oxycarboxylic acid, e.g. tartaric acid, formic acid, pyridine, or a salt of an inorganic or organic acid may be present during the formation of the metal compound. More than one metal may be used. The base of the plastic mass may be carnauba wax, or ozokerite. The colouring matter may be incorporated by grinding solids together, and may, if desired, be produced in the sheet to be coloured. A fatty acid of high molecular weight, a filler such as barium sulphate, zinc oxide, or titanium oxide, or a softening agent or plasticizer, e.g. tricresyl or triphenyl phosphate, glycerine or castor oil may be added. The complex chromium compound is made by boiling under a reflux condenser 50 parts of highly oxidized logwood extract and 800 parts of water with 15 parts of potassium bichromate in 50 parts of water. 50 parts of common salt are added to bring the compound into filterable form.ALSO:In a coloured plastic mass or coloured mass capable of conversion into plastic condition, free from oil and containing if desired solvents which are not water-soluble alcohols, there is incorporated a complex metal compound of logwood extract. The base of the plastic mass may be copal, amber, shellac, colophony, carnauba wax, ozokerite, casein, rubber, balata, or guttapercha. Suitable metals are chromium, copper, iron, cobalt, nickel, aluminium, manganese, zinc, vanadium, titanium, tungsten, or molybdenum. The metal may be used as hydrate or as salt with an inorganic or organic acid, or as a complex compound with ammonia or pyridine, or as a complex metal compound of logwood extract, and the treatment of the logwood extract may be effected in acid, neutral or alkaline medium. Oxycarboxylic acid e.g. tartaric acid, formic acid, pyridine, or a salt of an inorganic or organic acid may be present during the formation of the metal compound. More than one metal may be used. The colouring matter may be incorporated by grinding solids together, and may, if desired, be produced in the sheet to be coloured. A fatty acid of high molecular weight, a filler such as barium sulphate, zinc oxide, or titanium oxide, or a softening agent or plasticizer e.g. tricresyl or triphenyl phosphate, glycerine or castor oil may be added.
GB3652/36A 1935-02-06 1936-02-06 Manufacture of coloured masses from cellulose derivatives, natural or artificial resins or waxes Expired GB459334A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH459334X 1935-02-06

Publications (1)

Publication Number Publication Date
GB459334A true GB459334A (en) 1937-01-06

Family

ID=4515683

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3652/36A Expired GB459334A (en) 1935-02-06 1936-02-06 Manufacture of coloured masses from cellulose derivatives, natural or artificial resins or waxes

Country Status (2)

Country Link
DE (1) DE686060C (en)
GB (1) GB459334A (en)

Also Published As

Publication number Publication date
DE686060C (en) 1939-12-30

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