GB456359A - Process for the manufacture of high molecular products - Google Patents

Process for the manufacture of high molecular products

Info

Publication number
GB456359A
GB456359A GB13583/35A GB1358335A GB456359A GB 456359 A GB456359 A GB 456359A GB 13583/35 A GB13583/35 A GB 13583/35A GB 1358335 A GB1358335 A GB 1358335A GB 456359 A GB456359 A GB 456359A
Authority
GB
United Kingdom
Prior art keywords
cresol
ether
acid
ethers
methyl ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13583/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Publication of GB456359A publication Critical patent/GB456359A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F12/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/36—Polymerisation in solid state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/28—Chemically modified polycondensates
    • C08G8/30—Chemically modified polycondensates by unsaturated compounds, e.g. terpenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Lubricants (AREA)

Abstract

Aromatic vinyl hydrocarbons are reacted with aromatic hydroxy compounds or ethers thereof in the presence of such acid-reacting substances or compounds capable of splitting off acid as are capable of accelerating the polymerization of pure styrene to yield polymeric products. Aromatic vinyl hydrocarbons specified include styrene, divinylbenzene and vinylnaphthalene, aromatic hydroxy compounds or ethers include phenol, o - cresol, m - cresol, 2-hydroxydiphenyl, 2 : 2<1>-dihydroxydiphenyl, naphthols, anisol, phenetol, cresol methyl ethers, xylene methyl ethers, resorcin dimethyl ether, glycerine phenyl ethers, hydroxyalkylphenylethers or aryloxyacetic acid ethers. Suitable polymerizing agents, which may be removed by treating the product with quicklime, barium oxide or other metallic oxide, include tin tetrachloride or borofluor acetic acid. The polymerization may be effected in an indifferent solvent such as benzine, benzene or carbon tetrachloride. The products, which may be oily to resinous bodies soluble in benzene, turpentine, and oils, or which may be soluble in caustic soda lye, may be used as softeners, intermediates in the preparation of synthetic resins, as artificial masses, and in the manufacture of lacquers containing oil, cellulose derivatives, chlorinated rubber or alkyd resins. In examples (1) styrene is polymerized with (a) m-cresol methyl ether or a crude cresol ethyl ether in the presence of borofluoroacetic acid or tin tetrachloride or (b) phenol, m-cresol, p-cresol, guaiacol, 2 : 2<1>-dihydroxydiphenyl, anisol, phenetol, m-cresol methyl ether, o-cresol methyl ether or crude cresol methyl ether, m-xylenyl methyl ether, resorcinol dimethyl ether, phenoxyethanol, b -naphthol amyl-ether, glycerine phenyl or diphenyl ether, or ethyl cresoxyacetate in the presence of borofluoroacetic acid or tin tetrachloride and of benzine or carbon tetrachloride or (21) divinylbenzene in polymerized with crude cresol, m-cresol or b -naphthol ethyl ether in the presence of borofluoroacetic acid or tin tetrachloride and of carbon tetrachloride.
GB13583/35A 1937-02-08 1935-05-08 Process for the manufacture of high molecular products Expired GB456359A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB3759/37A GB489973A (en) 1937-02-08 1937-02-08 Process for the manufacture of new polymeric products derived from aromatic vinyl hydrocarbons
DE804891X 1937-07-17

Publications (1)

Publication Number Publication Date
GB456359A true GB456359A (en) 1936-11-09

Family

ID=62527938

Family Applications (3)

Application Number Title Priority Date Filing Date
GB13583/35A Expired GB456359A (en) 1937-02-08 1935-05-08 Process for the manufacture of high molecular products
GB3759/37A Expired GB489973A (en) 1935-04-13 1937-02-08 Process for the manufacture of new polymeric products derived from aromatic vinyl hydrocarbons
GB20933/38A Expired GB516936A (en) 1937-02-08 1938-07-14 Process for the manufacture of new reaction products from aromatic hydrocarbons

Family Applications After (2)

Application Number Title Priority Date Filing Date
GB3759/37A Expired GB489973A (en) 1935-04-13 1937-02-08 Process for the manufacture of new polymeric products derived from aromatic vinyl hydrocarbons
GB20933/38A Expired GB516936A (en) 1937-02-08 1938-07-14 Process for the manufacture of new reaction products from aromatic hydrocarbons

Country Status (3)

Country Link
DE (3) DE695178C (en)
FR (2) FR804891A (en)
GB (3) GB456359A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE754590C (en) * 1939-03-30 1953-08-03 Bakelite Ges M B H Process for the production of oil-soluble synthetic resins
US3544519A (en) * 1967-03-30 1970-12-01 Ici Ltd Sulfonated styrene-phenol resins

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE967600C (en) * 1939-10-30 1957-11-28 Metallgesellschaft Ag Process for the thermal treatment of polymers and copolymers of butadiene
US2374316A (en) * 1940-05-15 1945-04-24 Bakelite Corp Oil soluble resins
DE891744C (en) * 1940-06-26 1953-10-01 Chemische Werke Huels Ges Mit Process for the production of high molecular weight products
US2486831A (en) * 1945-04-07 1949-11-01 Socony Vacuum Oil Co Inc Homopolymerization of benzyl compounds
US2558812A (en) * 1947-10-24 1951-07-03 Universal Oil Prod Co Resin and process for its manufacture by condensation of a phenol, an alkyl aromatic hydrocarbon, and a polyenic hydrocarbon
BE489024A (en) * 1948-05-22
DE964441C (en) * 1953-10-03 1957-05-23 Degussa Anti-aging agent for rubber
US3228899A (en) * 1961-07-10 1966-01-11 Monsanto Co Phenolic resins from styrene, phenol and a vegetable drying oil

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE754590C (en) * 1939-03-30 1953-08-03 Bakelite Ges M B H Process for the production of oil-soluble synthetic resins
US3544519A (en) * 1967-03-30 1970-12-01 Ici Ltd Sulfonated styrene-phenol resins

Also Published As

Publication number Publication date
DE696109C (en) 1940-09-11
DE695178C (en) 1940-08-19
FR804891A (en) 1936-11-04
GB489973A (en) 1938-08-08
DE674984C (en) 1939-04-26
GB516936A (en) 1940-01-16
FR49620E (en) 1939-05-16

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