GB431487A - A method of producing substituted phenols - Google Patents

A method of producing substituted phenols

Info

Publication number
GB431487A
GB431487A GB8040/34A GB804034A GB431487A GB 431487 A GB431487 A GB 431487A GB 8040/34 A GB8040/34 A GB 8040/34A GB 804034 A GB804034 A GB 804034A GB 431487 A GB431487 A GB 431487A
Authority
GB
United Kingdom
Prior art keywords
acid
ethers
diisobutylene
employed
examples
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8040/34A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB431487A publication Critical patent/GB431487A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Nuclear a -a -g -g -tetramethylbutyl substitution products of polyhydric phenols and ethers thereof are manufactured by condensing a polyhydric phenol having at least one nuclear position o- or pto a hydroxyl group available for substitution, or ethers thereof, with at least one molar equivalent of diisobutylene in the presence of a kationoid condensing agent, e.g. acids or acidic salts, such as sulphuric acid, sodium bisulphite, phosphoric acid, monosodium phosphate, zinc chloride, aluminium chloride, boron trifluoride, benzenesulphonic acid, toluenesulphonic acid, hydrochloric acid and sodium acid sulphate. The products can be used as disinfectants and insecticides. The polyhydric phenols and ethers employed may be substituted by halogen or sulphonic, alkyl, aryl, aralkyl, nitro, carboxylic or azo groups. In examples, diisobutylene is reacted in the presence of sulphuric acid with: (1) resorcinol; (2) catechol; (3) hydroquinone; (4) pyrogallol; (5) guaiacol. In examples (1) to (4) the reaction is effected in solution in glacial acetic acid, which may be replaced by sulphuric acid itself, higher fatty acids, e.g. propionic acid, or alkyl sulphates, or mixtures of solvents. In (5) no solvent is employed. Specifications 398,218 and 415,715 are referred to.
GB8040/34A 1933-03-28 1934-03-14 A method of producing substituted phenols Expired GB431487A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US431487XA 1933-03-28 1933-03-28

Publications (1)

Publication Number Publication Date
GB431487A true GB431487A (en) 1935-07-09

Family

ID=21925737

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8040/34A Expired GB431487A (en) 1933-03-28 1934-03-14 A method of producing substituted phenols

Country Status (1)

Country Link
GB (1) GB431487A (en)

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