GB425433A - Process for dyeing leather - Google Patents

Process for dyeing leather

Info

Publication number
GB425433A
GB425433A GB11966/34A GB1196634A GB425433A GB 425433 A GB425433 A GB 425433A GB 11966/34 A GB11966/34 A GB 11966/34A GB 1196634 A GB1196634 A GB 1196634A GB 425433 A GB425433 A GB 425433A
Authority
GB
United Kingdom
Prior art keywords
dioxybenzene
aminophenol
nickel
cobalt
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11966/34A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gesellschaft fuer Chemische Industrie in Basel CIBA filed Critical Gesellschaft fuer Chemische Industrie in Basel CIBA
Publication of GB425433A publication Critical patent/GB425433A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/32Material containing basic nitrogen containing amide groups leather skins
    • D06P3/326Material containing basic nitrogen containing amide groups leather skins using metallisable or mordant dyes

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

Azo dyes, soluble metal compounds of; mordant or acid wool dyes, dyeing with.--Fast dyeings on leather, other than alumina-chrome tanned leather, are obtained with the use of a water-soluble complex metal compound of a monoazo dye of the general formula <FORM:0425433/IV/1> wherein x is a lake-forming group in o-position to the azo group, R1 is an aryl residue containing no carboxy group in o-position to x and R2 is a residue of the benzene series. The use of the metal compounds described in Specification 401,544 (chromium, copper, iron, cobalt, nickel, manganese, vanadium and titanium compounds of azo dyes of the general formula <FORM:0425433/IV/2> wherein R is the residue of any coupling component carrying no --SO2.NH.Aryl group) is excluded. Specified metals are aluminium, titanium, vanadium, chromium, copper, manganese, iron, cobalt, nickel and uranium. The parent azo dyestuffs are those obtainable by coupling diazotized o-oxy-, o-alkoxy- or o-carboxysubstituted aminobenzenes or aminonaphthalenes further substituted, if desired, e.g. by chloro, bromo, nitro, sulpho, carboxy, methoxy or ethoxy groups, with a dioxybenzene, e.g. 1 : 3 - dioxybenzene, 1 : 3 - dioxybenzene - 4 or 5 - carboxylic acid, 1 : 2 : 3 - trioxybenzene - 5 - carboxylic acid or their sulpho, nitro, alkyl or halogen substitution products. The following examples are specified. (1) Neutralized chrome leather is dyed brown throughout by tumbling it for 40 minutes in a drum with water at 60 DEG C. containing the nickel compound of the dyestuff, 4 - nitro - 2 - aminophenol - 6 - sulphonic acid --> 1 : 3 - dioxybenzene, and fatliquoring. (2) Vegetable tanned sheep or goat leather is dyed a level full brown-olive very fast to light, by similarly tumbling it with a solution of the iron compound of the dyestuff, 4 - chloro - 2 - aminophenol --> 1 - 3 - dioxybenzene, adding formic acid and continuing the dyeing for 10--15 minutes; the dyeing may also be effected by brushing the leather with a neutral cold dyeing liquor. A table is also given showing the colours obtainable with the following dyestuffs, viz. the uranium, iron, manganese and cobalt compound of 4 - nitro - 2 - aminophenol - 6 - sulphonic acid --> 1 : 3 - dioxybenzene, the manganese, chromium (80 per cent) and nickel (20 per cent), chromium (50 per cent) and nickel (50 per cent), iron, cobalt and nickel compounds of 4 - nitro - 2 - aminophenol --> 1 - 3 - dioxybenzene, the nickel, cobalt and chromium compounds of 4-chloro - 2 - aminophenol --> 1 : 3 - dioxybenzene, the iron, cobalt, nickel, manganese and chromium compounds of 5-nitro-2-aminophenol --> 1 : 3 - dioxybenzene and 6 - nitro - 2 - aminophenol - 4 - sulphonic acid --> 1 : 3 - dioxybenzene, the cobalt, nickel, iron and manganese compounds of 4-chloro-2-aminophenol - 5 - sulphonic acid --> 1 : 3 - dioxy benzene, the iron, manganese, cobalt, nickel and chromium (67 per cent) and cobalt (33 per cent) compounds of 2 - aminophenol - 4 - sulphonic acid --> 1 : 3 - dioxybenzene, the cobalt, uranium, nickel, iron and manganese compounds of 4-methyl-2-aminophenol-6-sulphonic acid --> 1 : 3 - dioxybenzene and 4 - chloro 2-aminophenol - 6 - sulphonic acid --> 1 : 3 - dioxybenzene, the iron compound of 5 - chloro - 2 - aminophenol - 3 - sulphonic acid --> 1 : 3 - dioxybenzene, the copper compound of 6-nitro-2 - aminophenol - 4 - sulphonic acid --> 1 : 3 - dioxybenzene and the chromium (50 per cent) and copper (50 per cent) compound of 4-chloro-2 - aminophenol - 6 - sulphonic acid --> 1 : 3 - dioxybenzene. Specification 305,949, [Class 15 (ii)], also is referred to. The Specification as open to inspection under Sect. 91 comprises also the use of the metal compounds of the corresponding dyestuffs in which R2 is an aryl residue in general. This subject-matter does not appear in the Specification as accepted.
GB11966/34A 1933-04-22 1934-04-20 Process for dyeing leather Expired GB425433A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH425433X 1933-04-22

Publications (1)

Publication Number Publication Date
GB425433A true GB425433A (en) 1935-03-14

Family

ID=4514810

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11966/34A Expired GB425433A (en) 1933-04-22 1934-04-20 Process for dyeing leather

Country Status (1)

Country Link
GB (1) GB425433A (en)

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