GB407379A - A process for improving the temperature-viscosity curves of lubricating oils - Google Patents
A process for improving the temperature-viscosity curves of lubricating oilsInfo
- Publication number
- GB407379A GB407379A GB16445/32A GB1644532A GB407379A GB 407379 A GB407379 A GB 407379A GB 16445/32 A GB16445/32 A GB 16445/32A GB 1644532 A GB1644532 A GB 1644532A GB 407379 A GB407379 A GB 407379A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- wax
- hydrocarbons
- products
- paraffin wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/08—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/20—Natural rubber; Natural resins
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/22—Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
- C10N2040/253—Small diesel engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Oily to solid polymerization or condensation products of m.w.500--10,000, S.G. about 0.86, viscosity 3--150 DEG Engler at 99 DEG C., viscosity index 120--150, and containing 16.0--16.3 parts of hydrogen per 100 parts of carbon, are obtained by treating paraffin waxy hydrocarbons and/or substances containing substantial amounts of such hydrocarbons with silent and preferably high frequency electric discharges, and removing unchanged wax and products of middle oil character from the products. The voltolization is carried out in known apparatus such as (1) Siemen's ozone tubes in which the foam produced is reconverted into the coherent liquid state and returned to the treatment zone; or (2) multiple alternating electrode and dielectric sheets over which thin layers of the material treated are caused to flow by pumps, scoops or sprayers, or by rotating the partially immersed sheets. Alternating currents of 4000--8000 volts and 50--50,000 or more cycles, and reduced pressures of 0.1--1.0 to 5--10 cm. of mercury may be used for as long as 100 hours. There may be present: (1) Gases or vapours, e.g. hydrogen, nitrogen, carbon monoxide, carbon dioxide, halogens, hydrogen halides, saturated or unsaturated gaseous hydrocarbons, coke-oven gas, natural gas, waste gases from destructive-hydrogenation processes, benzine vapours; these gases and vapours help to form foam and promote the condensation. (2) Foam-forming agents, e.g. saponine, sulphonic acids and their salts, oleic or other fatty acid of high m.w. (3) Substances promoting condensation, e.g. active carbon, active silica, Florida earth, metal powders, e.g. molybdenum, tungsten, vanadium, copper; oxides of zinc, cadmium, molybdenum, tungsten, chromium, vanadium, copper, or of other metal; iodides or other halogen compounds of sulphur, phosphorus, boron, copper, silver, magnesium, titanium, vanadium, molybdenum, tungsten, chromium nickel, cobalt, or other metal; organic halogen compounds, e.g. of benzene, toluene, xylene, naphthalene, and methyl, ethyl, methylene, or ethylene iodide, bromide, or chloride; or condensing agents such as aluminium chloride, zinc chloride or boron fluoride. (4) Solvents and diluents, e.g. di- or tetra-chlorethane, tetrachlorbenzene, aniline, hard or soft paraffin wax, paraffin oil, illuminating oil, aromatic hydrocarbons, e.g. naphthalene, tetra- or decahydronaphthalene, anthracene, phenanthrene; condensation or polymerization products of low m.w. unsaturated hydrocarbons; products obtained by condensing halogenated paraffin wax with naphthalene in presence of aluminium chloride. Where the diluent may polymerize or condense it is preferably not added until the last third of the treatment. The initial waxy materials are preferably paraffin wax hydrocarbons of m.w. above 330 or better over 350, or derivatives thereof, e.g. ceresine, ozokerite, neftgil, hatchettine, montan wax, mixed or not with paraffin wax or with hydrocarbon oils containing more than 13 or 14.5 parts of hydrogen per 100 parts of carbon, e.g. petrolatum, crude paraffin wax, petroleum jelly, crude lubricating oils containing paraffin wax, paraffin oil, spindle oil, machine oil, tar oil, cylinder oil, hydrogenated naphthalenes, montan wax, aromatic oils, high boiling oils from destructive hydrogenation. They may be prepared synthetically, e.g. by the electrolytic treatment of fatty acids, or by a destructive hydrogenation of waxy hydrocarbons followed by condensation in presence of aluminium chloride or like condensing agent, or by condensing halogenated paraffin wax with naphthalene in presence of aluminium chloride, or by polymerizing olefines or other unsaturated hydrocarbons of low m.w., or by treating low m.w. hydrocarbons with high frequency electric currents. They may be obtained by distillation from petroleum, extraction from brown coal, or by destructive hydrogenation. They may be improved by preliminary treatment consisting of one or more of the following, usually to remove the lower m.w. hydrocarbons and/or asphaltic and/or resinous impurities:--(1) Fractional distillation, advantageously with steam, hydrogen, nitrogen, carbon-dioxide, or benzine vapour. (2) Hydrogenation at elevated temperature and preferably pressure by hydrogen or gases containing it, usually in the presence of catalysts and so that little splitting occurs. The hydrogen content is raised and the colour improved. (3) Extraction with solvents to separate fractions rich in hydrogen from those poor, including asphaltic and resinous matters. Solvents specified are liquefied ethane and/or propane, liquefied sulphur dioxide, phenol, aniline, nitrobenzene, furfurol, ketones, ketonic acids, and mixtures of cyclohexane with methanol. (4) Treatment with refining agents, e.g. sulphuric acid, bleaching earths, boron fluoride, chromic acid. (5) Fractional precipitation from a solution, e.g. dissolving in ether, chloroform, or chlorinated ethylene, and precipitating by adding acetone or alcohol, with or without cooling. (6) Fractional crystallization by cooling a solution in stages. (7) Strongly cooling a solution, e.g. to -40 DEG C., and fractionally sweating the precipitate; or by direct fractional sweating if the initial material be sufficiently pure. (8) Mildly cracking, advantageously in presence of hydrogen under pressure and of dehydrogenating catalysts, and then cooling, maybe fractionally, to 10 DEG C. or even to - 40 DEG C. the product or its solution, and centrifuging or filtering. (9) Petrolatum and similar products may be mixed with light benzine, cooled to low temperatures, e.g. - 25 DEG C., and filtered or centrifuged, if desired in stages, to obtain high quality solid paraffin wax; the wax may then be freed from gums or asphalts as by distillation in vacuo up to 400 DEG C. while employing scavenging gases. The unchanged wax and middle oil-like substances are separated from the crude voltolized product by one or more of the following methods:--(1) Distillation up to 280 DEG C., preferably under reduced pressure and with water or benzine vapours, or hydrogen, nitrogen, carbon dioxide, coke oven gases, or waste gases from destructive hydrogenation. Bleaching or Florida earth or other adsorbent may be present. (2) Extraction, preferably by liquefied gaseous hydrocarbons, e.g. methane, ethane, propane, butane, ethylene, propylene, or mixtures thereof. (3) Dissolving the crude product in e.g. gasoline, kerosene, benzine, trichlorethane or other halogenated hydrocarbon, cooling to between - 8 and - 30 C., filtering or centrifuging to remove the precipitated wax, and then distilling off the solvent and the lower boiling voltolization products. (4) Dissolving the crude product, e.g. in kerosene, trichlorethane, or ether, and precipitating out the pure product, maybe in stages, as by acetone or alcohol. The wax may be precipitated afterwards from the solution by lowering the temperature. The crude product may also be purified and the iodine no. reduced, before or after the removal of unchanged wax, by catalytic hydrogenation without splitting, e.g. by treatment with hydrogen at 100--450 C. at 20--1000 atmos. pressure in presence of nickel or cobalt and maybe of a diluent. Distillation, or solution and precipitation, may follow. In all cases the purified and/or wax-free product may be treated with Florida earth or other adsorbent; and it may be submitted to condensation in presence of aluminium chloride or similar condensing agent whereby the viscosity is increased, e.g. from 25--30 DEG to 100 DEG Engler at 99 DEG C. The products mixed or not with water or with pour point depressants, e.g. the product of halogenated paraffin wax condensed with naphthalene in presence of aluminium chloride, are used as lubricants. They are also used as additions:--to hydrocarbon oils for coating protecting, or impregnating, especially tar oils containing paraffin wax or products obtained by extracting tars with alcohol or other solvent; to hydrocarbon oils containing naphthalene, anthracene, carbazole, or other cyclic hydrocarbons to prevent crystallizing out at low temperatures; to mineral oils, tars, and extraction and destructive-hydrogenation products to facilitate the separation therefrom of paraffin wax by chilling processes; to paraffin wax to increase the viscosity of the melt and to prevent cracks and white crystal centres and so render the wax suitable for candles; to benzine, gas oil, illuminating oil, and other liquid hydrocarbons to increase viscosity, facilitate pumping, and reduce consumption; to motor fuels to lubricate the valves and seal the piston rings; to paraffinum liquidum or other white oil for pharmaceutical or cosmetic purposes, preferably after stirring with water or after purification; and alone or mixed with lubricating oils of high viscosity index to lubricants to improve the viscosity, viscosity index, pour point, and colour, and impart fluorescence. There may also be added to the lubricants:--metal soaps, e.g. lead, sodium, ammonium, oleates or stearates; condensation products of high m.w. organic acids; oxidized oil distillates of high B.P.; paraffin wax; pour-point depressants; hydrocarbons of m.w. above 1000 or 2000, e.g. hydrogenated rubber or balata or guttapercha, hydrogenated oxygen-free resins soluble in oil, hydrogenated polymerization products of butadiene or other diolefine, cyclocaoutchouc, polymerized styrene or indene, hydrogenated polymerized styrene, oil-soluble polymerization products of isobutylene or other olefine; and oil-soluble cellulose derivatives, e.g. cellulose laurate, and their hydrogenated products. In examples:--(1) Ceresin M.P. 73 DEG C. is treated at 80--100 DEG C. in a Siemen's ozone tube at 5--10 m.m. with discharges of 7000 volts and 1000 cycles for 25--30 hours, an equal weight of paraffin wax M.P. 50 DEG C. being added after 20--22 p hours; the product
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB16445/32A GB407379A (en) | 1932-06-10 | 1932-06-10 | A process for improving the temperature-viscosity curves of lubricating oils |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB16445/32A GB407379A (en) | 1932-06-10 | 1932-06-10 | A process for improving the temperature-viscosity curves of lubricating oils |
Publications (1)
Publication Number | Publication Date |
---|---|
GB407379A true GB407379A (en) | 1934-03-12 |
Family
ID=10077441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB16445/32A Expired GB407379A (en) | 1932-06-10 | 1932-06-10 | A process for improving the temperature-viscosity curves of lubricating oils |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB407379A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1023805B1 (en) * | 2016-06-30 | 2017-07-26 | Green Frix | DEVICE FOR THE ELECTRICAL TREATMENT OF A FATTY BODY OF VEGETABLE ORIGIN |
WO2022112458A1 (en) | 2020-11-24 | 2022-06-02 | Agc Glass Europe | Device for electrical discharge processing of non-conducting liquids |
-
1932
- 1932-06-10 GB GB16445/32A patent/GB407379A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1023805B1 (en) * | 2016-06-30 | 2017-07-26 | Green Frix | DEVICE FOR THE ELECTRICAL TREATMENT OF A FATTY BODY OF VEGETABLE ORIGIN |
WO2018002329A1 (en) | 2016-06-30 | 2018-01-04 | Green Frix | Device for electrically processing a fatty substance of plant origin |
CN109565922A (en) * | 2016-06-30 | 2019-04-02 | 格林弗利克斯 | The equipment for carrying out electric treatment for the fatty material to plant origin |
JP2019531359A (en) * | 2016-06-30 | 2019-10-31 | グリーン フリックスGreen Frix | Equipment for the electrical treatment of fatty substances of plant origin |
RU2726944C1 (en) * | 2016-06-30 | 2020-07-17 | Грин Фрикс | Device for electrical treatment of fatty substance of vegetable origin |
CN109565922B (en) * | 2016-06-30 | 2020-10-23 | 格林弗利克斯 | Device for the electrical treatment of fatty substances of vegetable origin |
US11053453B2 (en) | 2016-06-30 | 2021-07-06 | Green Frix | Device for an electrical processing of a fatty substance of plant origin |
US11795415B2 (en) | 2016-06-30 | 2023-10-24 | Green Frix | Device for an electrical processing of a fatty substance of plant origin |
WO2022112458A1 (en) | 2020-11-24 | 2022-06-02 | Agc Glass Europe | Device for electrical discharge processing of non-conducting liquids |
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