GB402393A - Colouration of cellulose ester and ether materials - Google Patents

Colouration of cellulose ester and ether materials

Info

Publication number
GB402393A
GB402393A GB469332A GB469332A GB402393A GB 402393 A GB402393 A GB 402393A GB 469332 A GB469332 A GB 469332A GB 469332 A GB469332 A GB 469332A GB 402393 A GB402393 A GB 402393A
Authority
GB
United Kingdom
Prior art keywords
compounds
amino
dyeing
class
residue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB469332A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Priority to GB469332A priority Critical patent/GB402393A/en
Publication of GB402393A publication Critical patent/GB402393A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/32Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

Cellulose esters and ethers, dyeing.--Filaments of cellulose esters or ethers are coloured by applying aqueous suspensions or dispersions of unsulphonated arylaminoanthraquinone compounds having an ether group as a substituent in o-position in the arylamino residue. The arylamino residue may be of the benzene, naphthalene or other series, and the ether substituent may be a phenyl-, substituted phenyl- or other aryl-ether,--but preferably is a residue of low mass, such as methoxy, ethoxy, o -hydroxyethoxy. Other substituents such as nitro-, halogen- or alkylgroups may be present in the aryl residue and also in the anthraquinone nucleus; particularly va uable dyes are those containing the o-ether substituted arylamino residue in an a -position and an amino or aliphatically substituted amino or a hydroxy group in para position thereto. Specific compounds suitable are 1-amino-4-o-methoxyphenylaminoanthraquinone, 1-o -oxyethylamino - 4 - o - methoxyphenylaminoanthraquinone, 1.5-diamino-4.8-di-o-methoxyphenylaminoanthraquinone, 1.8-dihydroxy-4-o-methoxyphenylaminoanthraquinone, and 1-amino-4-o-phenoxyphenylaminoanthraquinone. For the production of these compounds reactive groups such as nitro, hydroxy, amino, halogen or sulpho groups present as substituents in anthraquinone compounds may be replaced by arylamino residues by the action of appropriately substituted arylamines such as o-anisidine, o-phenetidine or o-aminodiphenylether. Or aminoanthraquinones may be suitably arylated. Suitable starting materials are 1-amino-4-hydroxy-, 4-alkoxy-, 4-nitro-, or 4-bromoanthraquinones, quinizarin, 1.5- or 1.8-dinitroanthraquinones, 1.5- or 1.8-dichloranthraquinones or their 4-amino derivatives, 4-nitro- and 4-chlorchrysazin, and 5.8-dichloro-1.2-benzanthraquinone. Alternative syntheses comprise the introduction of an o-ether residue into the arylamino group of an arylaminoanthraquinone, for example by etherifying an o-hydroxy group, or replacing an o-halogen atom by the action of sodium alcoholate. In addition to the above replacements other reactive groups may be replaced by desired substituents such as amino or alkylamino. For convenience the dyes are converted into preparations in which they are present in colloidal or dispersed form by grinding (for example, in colloid mills), or by dissolving in a solvent and mixing with water containing or not protective colloids and/or dispersators, or by treatment with dispersing agents alone or in the presence of protective colloids. Dispersing agents or protective colloids mentioned are sulphoaromatic fatty acid compounds (Specification 242,393, [Class 15 (ii), Dyeing, Processes &c. for]), sulphoaromatic ricinoleic acid compounds (Specification 273,819, [Class 15 (ii), Dyeing, Processes &c. for]), naphthenic acids or other carbocyclic compounds containing salt-forming groups or salts thereof (Specification 224,925, [Class 15 (ii), Dyeing, Processes &c. for],) sulphonated oil compounds, sulphuric esters of higher aliphatic alcohols, furfuralnaphthalene sulphonic acid compounds (Specification 322,737, [Class 2 (iii), Dyes &c.]), resino-naphthalene sulphonic acid compounds (Specification 323,788, [Class 2 (iii), Dyes &c.]), formaldehyde-naphthalene sulphonic acid compounds, alkyl-, cycloalkyl-, and aralkyl-naphthalene sulphonic acids, sulphite cellulose waste liquors, sulpho compounds of mineral oils, tar oils &c., and their condensation products with alcohols, sulpho compounds of distillation residues of benzaldehyde, carbohydrates (including gums), glue and gelatine and those described in Specifications 219,349, 273,820, [both in Class 15 (ii), Dyeing, Processes &c. for], and 365,170. Such preparations are used for application to the materials which may be admixed with other textile fibres, by dyeing, printing, stencilling or other method of local application, or they may be used for the colouration of stannous chloride discharges according to Specification 351,457. In an example cellulose acetate is dyed blue shades from a soap solution containing 1-amino-4-(2<1>-methoxyphenylamino-) -anthraquinone and Turkey Red oil; for printing purposes the dye paste is diluted, and thickened with a gum thickening paste which may also contain a swelling agent (methylated spirits).
GB469332A 1932-02-17 1932-02-17 Colouration of cellulose ester and ether materials Expired GB402393A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB469332A GB402393A (en) 1932-02-17 1932-02-17 Colouration of cellulose ester and ether materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB469332A GB402393A (en) 1932-02-17 1932-02-17 Colouration of cellulose ester and ether materials

Publications (1)

Publication Number Publication Date
GB402393A true GB402393A (en) 1933-11-17

Family

ID=9782012

Family Applications (1)

Application Number Title Priority Date Filing Date
GB469332A Expired GB402393A (en) 1932-02-17 1932-02-17 Colouration of cellulose ester and ether materials

Country Status (1)

Country Link
GB (1) GB402393A (en)

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