GB397852A - Improvements in or relating to the carrying out of chemical reactions with carbon monoxide - Google Patents

Improvements in or relating to the carrying out of chemical reactions with carbon monoxide

Info

Publication number
GB397852A
GB397852A GB6088/32A GB608832A GB397852A GB 397852 A GB397852 A GB 397852A GB 6088/32 A GB6088/32 A GB 6088/32A GB 608832 A GB608832 A GB 608832A GB 397852 A GB397852 A GB 397852A
Authority
GB
United Kingdom
Prior art keywords
carbon monoxide
hydrogen
reactions
halides
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6088/32A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB397852A publication Critical patent/GB397852A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/40—Carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Acid chlorides; amines; aldehydes; acids; esters; alcohols and ethers.--Reactions in the gaseous phase involving carbon monoxide, other than the catalytic decomposition of carbon monoxide to form carbon black, are accelerated by the use of small amounts of halogens, hydrogen halides, alkyl halides, or nitrogen oxides, e.g. 0,1-5 per cent by volume. Preferably solid catalysts or inert materials which act as catalysts in the presence of the above bodies are also employed. The halogens and hydrogen halides are suitable for use in reactions between alcohols and carbon monoxide to form acids, esters and ethers; hydrogen halides may be used to accelerate the formation of esters from alkyl ethers and carbon monoxide, or organic acids from paraffin hydrocarbons and carbon monoxide, or organic amines from ammonia and carbon monoxide. Alkyl halides are suitable for the preparation of acyl chlorides from alkyl chlorides and carbon monoxide. Other reactions include the formation of acyl chlorides from hydrocarbons, chlorine and carbon monoxide, alcohols and aldehydes from carbon monoxide and steam, and aldehydes from hydrocarbons and carbon monoxide. According to an example, a mixture of carbon monoxide, hydrogen chloride, methanol vapour; hydrogen and water vapour is passed under a pressure of 700 atmospheres through a reaction chamber containing copper chloride supported on charcoal and maintained at 350 DEG C. Acetic acid and methyl acetate are obtained. Pressures from 100-1000 atmospheres may be used in the above reactions.ALSO:Reactions in the gaseous phase involving carbon monoxide, other than the catalytic decomposition of carbon monoxide to form carbon black, are accelerated by the use of small amounts of halogen, hydrogen halides, alkyl halides or nitrogen oxides, e.g. 0,1-5 per cent by volume. Preferably solid catalysts or inert materials which act as catalysts in the presence of the above bodies are also employed. The halogens and hydrogen halides are suitable for use in reactions between alcohols and carbon monoxide to form acids, esters and ethers; hydrogen halides may be used to accelerate the formation of esters from alkyl ethers and carbon monoxide, or organic acids from paraffin hydrocarbons and carbon monoxide, or organic amines from ammonia and carbon monoxide. Alkyl halides are suitable for the preparation of acyl chlorides from alkyl chlorides and carbon monoxide; and the oxides of nitrogen for the reaction between ammonia and carbon monoxide to give hydrocyanic acid. Other reactions include the formation of acyl chlorides from hydrocarbons, chlorine and carbon monoxide; alcohols and aldehydes from carbon monoxide and steam, and aldehydes from hydrocarbons and carbon monoxide. According to examples, (1) Hydrocyanic acid is obtained by passing equal volumes of carbon monoxide and ammonia together with 0,5 per cent of nitric oxide under pressure through a reaction tube lined with an inert material such as aluminium and filled with a thoria catalyst, the temperature of the catalyst being maintained at 200-750 DEG C., preferably 400-500 DEG C. (2) A mixture of carbon monoxide, hydrogen chloride, methanol vapour, hydrogen and water vapour is passed under a pressure of 700 atmospheres through a reaction chamber containing copper chloride supported on charcoal and maintained at 350 DEG C. Acetic acid and methyl acetate being obtained. (3) Carbon dioxide and hydrogen are obtained from a mixture of carbon monoxide and steam containing 0,1 per cent of bromine which is passed over a catalyst at a temperature of 325-400 DEG C. Pressures from 100-1000 atmospheres may be used in the above reactions.
GB6088/32A 1931-02-28 1932-02-29 Improvements in or relating to the carrying out of chemical reactions with carbon monoxide Expired GB397852A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US397852XA 1931-02-28 1931-02-28

Publications (1)

Publication Number Publication Date
GB397852A true GB397852A (en) 1933-08-29

Family

ID=21907327

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6088/32A Expired GB397852A (en) 1931-02-28 1932-02-29 Improvements in or relating to the carrying out of chemical reactions with carbon monoxide

Country Status (1)

Country Link
GB (1) GB397852A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4218398A (en) * 1976-11-01 1980-08-19 Mitsubishi Gas Chemical Company, Inc. Process for producing dimethylformamide
US4244889A (en) 1979-12-19 1981-01-13 Union Carbide Corporation Production of acetamides with rhodium-manganese catalysts
EP0078162A1 (en) * 1981-10-23 1983-05-04 Toa Nenryo Kogyo Kabushiki Kaisha Process for producing methyl methoxyacetate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4218398A (en) * 1976-11-01 1980-08-19 Mitsubishi Gas Chemical Company, Inc. Process for producing dimethylformamide
US4244889A (en) 1979-12-19 1981-01-13 Union Carbide Corporation Production of acetamides with rhodium-manganese catalysts
EP0078162A1 (en) * 1981-10-23 1983-05-04 Toa Nenryo Kogyo Kabushiki Kaisha Process for producing methyl methoxyacetate

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