GB387381A - Process for the manufacture of vulcanisation products resembling rubber - Google Patents

Process for the manufacture of vulcanisation products resembling rubber

Info

Publication number
GB387381A
GB387381A GB2214431A GB2214431A GB387381A GB 387381 A GB387381 A GB 387381A GB 2214431 A GB2214431 A GB 2214431A GB 2214431 A GB2214431 A GB 2214431A GB 387381 A GB387381 A GB 387381A
Authority
GB
United Kingdom
Prior art keywords
butadiene
emulsion
polymerized
products
chlorobutadiene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2214431A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB2214431A priority Critical patent/GB387381A/en
Publication of GB387381A publication Critical patent/GB387381A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon

Abstract

Mixed polymerisates from hydrocarbons of the butadiene type and polymerizable unsaturated substances not being hydrocarbons, but containing in addition to carbon and hydrogen one or more different atoms, e.g. oxygen, nitrogen or halogen when vulcanized in the presence of finely divided carbon such as gas carbon or soot yield rubber-like products of high elasticity and strength. The quantities of the components are selected such that the butadiene hydrocarbon component is used in excess. The mixed polymerization products yield good results when the monomeric compounds are wholly or partly replaced by incompletely polymerized products. In examples, (a) butadiene and sorbic acid ethyl ester are polymerized in emulsion, or butadiene or isoprene may be polymerized with sorbic acid methyl ketone; (b) butadiene and cinnamic acid ethyl ester are polymerized in emulsion; (c) butadiene and b -methyl-g -chlorobutadiene polymerized in emulsion, the emulsifying agent in each case being diethylaminoethoxy oleic acid anilide; (d) butadiene and b -chlorobutadiene in emulsion; (e) butadiene and 3-chlorostyrene in emulsion. All the products are vulcanized in the presence of soot, and figures are given to show the qualities of the product. Specifications 349,976, 360,821, and 360,822 are referred to.ALSO:Mixed polymerizates from hydrocarbons of the butadiene type and polymerizable unsaturated substances not being hydrocarbons, but containing in addition to carbon and hydrogen one or more different atoms, e.g. oxygen, nitrogen or halogen, are prepared in emulsion form, the quantities of the components being selected such that the butadiene hydrocarbon component is used in excess. The monomeric compounds may be wholly or partly replaced by incompletely polymerized products. In examples, mixed polymerizates of the following are prepared in emulsion : (a) butadiene and sorbic acid ethyl ester, (b) butadiene or isoprene and sorbic acid methyl ketone (c) butadiene and cinnamic acid ethyl ester, (d) butadiene and b -methyl-y-chlorobutadiene, (e) butadiene and b -chlorobutadiene, (f) butadiene and 3-chlorostyrene; diethylaminoethoxy-oleic acid anilide may be employed as the emulsifying agent. Specifications 349,976, [Group IV], 360,821, and 360,822, are referred to.ALSO:Mixed polymerizates from hydrocarbons of the butadiene type and polymerizable unsaturated substances not being hydrocarbons, but containing in addition to carbon and hydrogen one or more different atoms, e.g. oxygen, nitrogen or halogen when vulcanized in the presence of finely divided carbon such as gas carbon or soot yield rubber-like products of high elasticity and strength. The quantities of the components are selected such that the butadiene hydrocarbon component is used in excess. The mixed polymerization products yield good results when the monomeric compounds are wholly or partly replaced by incompletely polymerized products. In examples (a) butadiene and sorbic acid ethyl ester are polymerized in emulsion, or butadiene or isoprene may be polymerized with sorbic acid methyl ketone, (b) butadiene and cinnamic acid ethyl ester are polymerized in emulsion (c) butadiene and b -methyl-g -chlorobutadiene polymerized in emulsion in each case diethylaminoethoxy oleic acid anilide is the emulsifying agent, (d) butadiene and b -chlorobutadiene in emulsion, (e) butadiene and 3-chloro-styrene in emulsion. All the products are vulcanized in the presence of soot, and figures are given to show the qualities of the product. Specifications 349,976, [Group IV], 360,821, and 360,822 are referred to.
GB2214431A 1931-08-04 1931-08-04 Process for the manufacture of vulcanisation products resembling rubber Expired GB387381A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2214431A GB387381A (en) 1931-08-04 1931-08-04 Process for the manufacture of vulcanisation products resembling rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2214431A GB387381A (en) 1931-08-04 1931-08-04 Process for the manufacture of vulcanisation products resembling rubber

Publications (1)

Publication Number Publication Date
GB387381A true GB387381A (en) 1933-02-06

Family

ID=10174605

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2214431A Expired GB387381A (en) 1931-08-04 1931-08-04 Process for the manufacture of vulcanisation products resembling rubber

Country Status (1)

Country Link
GB (1) GB387381A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2422932A (en) * 1944-09-06 1947-06-24 Du Pont Improved synthetic rubbers
US2479450A (en) * 1944-12-30 1949-08-16 Standard Oil Dev Co Chemical process for tripolymers
US2576968A (en) * 1945-02-28 1951-12-04 Ind Tape Corp Pressure-sensitive adhesives
US2637697A (en) * 1948-12-30 1953-05-05 Standard Oil Dev Co Lubricating oil additive
US2699577A (en) * 1949-05-23 1955-01-18 Armstrong Cork Co Textile roll covering

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2422932A (en) * 1944-09-06 1947-06-24 Du Pont Improved synthetic rubbers
US2479450A (en) * 1944-12-30 1949-08-16 Standard Oil Dev Co Chemical process for tripolymers
US2576968A (en) * 1945-02-28 1951-12-04 Ind Tape Corp Pressure-sensitive adhesives
US2637697A (en) * 1948-12-30 1953-05-05 Standard Oil Dev Co Lubricating oil additive
US2699577A (en) * 1949-05-23 1955-01-18 Armstrong Cork Co Textile roll covering

Similar Documents

Publication Publication Date Title
US1891203A (en) Polymerization of unsaturated organic compounds
US1938731A (en) Rubberlike mass containing styrene polymerizates
US2321693A (en) Emulsion polymerization of halogen-2-butadienes-1,3
US2338741A (en) Substituted styrene-polybutadiene copolymer
US2317858A (en) Styrene-polybutadiene copolymer
ES295384A1 (en) Polymerization procedure (Machine-translation by Google Translate, not legally binding)
US1938730A (en) Rubber-like mass containing styrol polymerizates
GB387381A (en) Process for the manufacture of vulcanisation products resembling rubber
GB492998A (en) Improvements in the manufacture and production of vulcanisable mixtures of organic film-forming substances
US2338427A (en) Regenerating of vulcanized rubber
GB360822A (en) Process for the manufacture of mixed rubber-like masses
US2546220A (en) Emulsion polymerization with a catalyst comprising a diazo thioether and a ferricyanide
Whitby et al. Synthetic rubber
US2105361A (en) Compounds of polymerized acrylic acid or its esters with sulphur or selenium and method of making the same
US2266794A (en) Rubberlike interpolymers of butadiene hydrocarbons and fumaric acid esters and process of producing the same
US2279293A (en) Copolymers of butadienes with unsaturated alcohol esters of acrylic acids
US2616875A (en) Shortstopping of butadiene-1,3 emulsion polymerization
US3068197A (en) Rubbery polymer and process
US2338742A (en) Substituted styrene-polyisoprene copolymer
GB364089A (en) Improvements in the manufacture and production of polymerisation products
US1950440A (en) Halogen-substituted chemical compounds and processes for preparing same
US2692255A (en) Modification of alkali metal catalyzed polymerization of conjugated diene hydrocarbons
US2444870A (en) Copolymers of butadienes-1, 3 and alpha aryl acrylonitriles
GB328812A (en) Improvements in the incorporation of lampblack into rubber and the like
Carothers et al. Acetylene Polymers and their Derivatives. V. The Polymerization of Bromoprene (Third Paper on New Synthetic Rubbers)