GB367817A - Improvements in the manufacture and production of firmly adherent coatings - Google Patents

Improvements in the manufacture and production of firmly adherent coatings

Info

Publication number
GB367817A
GB367817A GB2752930A GB2752930A GB367817A GB 367817 A GB367817 A GB 367817A GB 2752930 A GB2752930 A GB 2752930A GB 2752930 A GB2752930 A GB 2752930A GB 367817 A GB367817 A GB 367817A
Authority
GB
United Kingdom
Prior art keywords
cellulose
paper
mixed
swelling
layers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2752930A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB2752930A priority Critical patent/GB367817A/en
Publication of GB367817A publication Critical patent/GB367817A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Organic Insulating Materials (AREA)

Abstract

Relates to the production of firmly adherent coatings of cellulose derivatives on solid articles, and the coatings may consist of alternate layers of cellulose derivatives and of paper, silk, cotton, asbestos board or fabric, or of metal wires which may be covered with fabric. The process is particularly applicable for coating wires, rods or tubes, and in the manufacture of electric cables, condensers, and insulating layers for the groovings of dynamos and motors. The process consists in the use of certain mixed cellulose derivatives, and in subsequently treating the coated article with a difficulty volatile swelling agent, i.e. one which is non-volatile at ordinary temperatures and boils at 100 DEG C. or over under a pressure of 10mm. of mercury. The mixed cellulose derivatives capable of swelling with such agents are those containing at least one group which increases their solubility in water, and at least one group which increases their solubility in hydrocarbons. The group increasing the solubility in water may be a fatty acid radicle with less than 5 carbon atoms, the nitric acid radicle, a methyl group, or an hydroxy-alkyl group; the group which increases the solubility in hydrocarbons may be a fatty acid radicle with more than 10 carbon atoms or an alkyl group with two or more carbon atoms; the mixed cellulose derivatives may therefore be mixed esters, ether esters, hydroxy-ether esters, or mixed ethers, provided the groups present comply with these requirements. Mixed fatty acid esters, and hydroxy-ether esters should contain 5-30 per cent by weight of the higher fatty acid. Swelling agents specified are transformer oils, and soft or hard paraffin wax, montan wax, bitumen or asphalt, solutions of colophony in transformer oils, polymerization products of propylene or of other olefines, linseed or castor or other vegetable oils either raw or blown, and propyl-naphthalene. The wax, bitumen, or asphalt may be used alone or with mineral oils. The coating of cellulose derivative may be formed in any thickness from the dissolved, thermo-plastic, or fused coating material, or it may be applied in the form of ribbon. The swelling treatment may be effected at 120 DEG C. under increased or reduced pressure, or in a vacuum, e.g. at a pressure of 2-50 mm. of mercury, or the pressure may be alternately increased and reduced. The coated wire may be wound into finished coils, e.g. for transformers, and afterwards subjected to the swelling treatment. In order to produce layers having different dielectric constants several layers of different cellulose derivative may be employed having different capacities for swelling, and different swelling agents may be used one after another. For example, a conductor may be coated with successive layers of a cellulose butyrate laurate containing 4 lauric to 1 butyric radicle and of paper, and then with successive layers of a similar ester containing 1 lauric to 1 butyric radicle and of paper, and treated at 80-120 DEG C. under reduced pressure with transformer oil or with polymerized propylene, or with rosin oil. The inner layers are capable of swelling more strongly than the outer layers. In a modification of this process, the inner layers are treated with ordinary or blown castor oil as swelling agent, and the outher layers with transformer oil with or without rosin, this swelling agent having a lower dielectric constant than the castor oil. In making condensers, paper may be combined with films of the mixed cellulose derivative, or coated with it, or the cellulose derivative may be incorporated with the paper during manufacture by the use of a suspension or emulsion; the prepared paper is dried and built up into a condenser, and the finished windings or layers then submitted to the swelling process. In further examples, (1) a cable is coated by repeated lacquering with cellulose butyrate laurate, or cellulose acetate butyrate laurate and immersed for 48 hours in transformer oil at 100 DEG C. under a pressure of 10 mm. mercury or less; (2) a cable is wound with a strip of film made from the same esters, or from an ether-ester such as ethyl cellulose nitrate, or from a mixed ether containing one or more methyl or hydroxy-alkyl groups and one or more ethyl or higher alkyl group, and treated for 1 or 2 days with transformer oil or propylnaphthalene at about 100 DEG C. under raised and reduced pressure alternately; (3) a copper wire is wound with a film of cellulose butyrate laurate containing 2 lauric to 1 butyric radicle, then with paper, and again with cellulose ester and with paper, and the coiled wire is treated with transformer oil first under a pressure of 2-25 mm. of mercury to remove air and moisture, and then at 100 DEG C. for 24 hours under atmospheric pressure or in vacuo; (4) condenser paper is coated with a solution of a similar cellulose butyrate laurate in benzene, butanol, and acetone, with or without polymerized indene, and is built up with tinfoil into a coiled condenser which is then immersed in castor oil at 80 DEG C. for 12 hours at a pressure of 2-10 mm. of mercury. Specifications 21293/00, [Class 36, Electricity, Conducting &c.], 259,131, [Class 38 (ii), Electric currents, Converting &c.], 288,221, and 319,371, [both in Class 95, Paints &c.], are referred to.ALSO:A coating process consists in the use of certain mixed cellulose derivatives, and in subsequently treating the coated article with a difficultly volatile swelling agent, i.e. one which is non-volatile at ordinary temperatures and boils at 100 DEG C. or over under a pressure of 10 mm. of mercury. The mixed cellulose derivatives capable of swelling with such agents are those containing at least one group which increases their solubility in water, and at least one group which increases their solubility in hydrocarbons. The group increasing the solubility in water may be a fatty acid radicle with less than 5 carbon atoms, the nitric acid radicle, a methyl group, or an hydroxy-alkyl group; the group which increases the solubility in hydrocarbons may be a fatty acid radicle with more than 10 carbon atoms or an alkyl group with two or more carbon atoms; the mixed cellulose derivatives may therefore be mixed esters, ether esters, hydroxy-ether esters, or mixed ethers, provided the groups present comply with these requirements. Mixed fatty acid esters, and hydroxy-ether esters should contain 5 to 30 per cent by weight of the higher fatty acid. Swelling agents specified are transformer oils, and soft or hard paraffin wax, montan wax, bitumen or asphalt, solutions of colophony in transformer oils, polymerization products of propylene or of other olefines, linseed or castor or other vegetable oils either raw or blown, and propyl-naphthalene. The wax, bitumen, or asphalt may be used alone or with mineral oils. The coating of cellulose derivatives may be formed in any thickness from the dissolved, thermoplastic, or fused coating material, or it may be applied in the form of ribbon. In one example, a conductor is coated with successive layers of a cellulose butyrate laurate containing 4 lauric to 1 butyric radicle and of paper, and then with successive layers of a similar ester containing 1 lauric to 1 butyric radicle and of paper, and treated at 80-120 DEG C. under reduced pressure with transformer oil or with polymerized propylene, or with rosin oil. The inner layers are capable of swelling more strongly than the outer layers. In a modification of this process, the inner layers are treated with ordinary or blown castor oil as swelling agent, and the outer layers with transformer oil with or without rosin. In further examples, (1) a cable is coated by repeated lacquering with cellulose butyrate laurate, or cellulose acetate butyrate laurate and immersed for 48 hours in transformer oil; (2) a cable is wound with a strip of film made from the same esters, or from an ether-ester such as ethyl cellulose nitrate, or from a mixed ether containing one or more methyl or hydroxy-alkyl groups and one or more ethyl or higher alkyl group, and treated for 1 or 2 days with transformer oil or propylnaphthalene; (3) a copper wire is wound with a film of cellulose butyrate laurate containing 2 lauric to 1 butyric radicle, then with paper, and again with cellulose ester and with paper, and the coiled wire is treated with transformer oil; (4) condenser paper is coated with a solution of a similar cellulose butyrate laurate in benzene, butanol, and acetone, with or without polymerized indene, and is built up with tinfoil into a coiled condenser. Specifications 21293/00, [Class 36, Electricity, Conducting &c.], 259,131, [Class 38 (ii), Electric currents, Converting &c.], 288,221, [Class 95, Paints &c.], and 319,371, [Class 2 (ii), Cellulose &c.], are referred to.
GB2752930A 1930-09-15 1930-09-15 Improvements in the manufacture and production of firmly adherent coatings Expired GB367817A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2752930A GB367817A (en) 1930-09-15 1930-09-15 Improvements in the manufacture and production of firmly adherent coatings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2752930A GB367817A (en) 1930-09-15 1930-09-15 Improvements in the manufacture and production of firmly adherent coatings

Publications (1)

Publication Number Publication Date
GB367817A true GB367817A (en) 1932-02-15

Family

ID=10261066

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2752930A Expired GB367817A (en) 1930-09-15 1930-09-15 Improvements in the manufacture and production of firmly adherent coatings

Country Status (1)

Country Link
GB (1) GB367817A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117230539A (en) * 2023-11-14 2023-12-15 江苏中鲈科技发展股份有限公司 Mechanical sensitive material for resistance type pressure sensor and preparation method and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117230539A (en) * 2023-11-14 2023-12-15 江苏中鲈科技发展股份有限公司 Mechanical sensitive material for resistance type pressure sensor and preparation method and application thereof
CN117230539B (en) * 2023-11-14 2024-03-19 江苏中鲈科技发展股份有限公司 Mechanical sensitive material for resistance type pressure sensor and preparation method and application thereof

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