GB357527A - Improvements in the manufacture of artificial threads or other products from cellulose compounds - Google Patents
Improvements in the manufacture of artificial threads or other products from cellulose compoundsInfo
- Publication number
- GB357527A GB357527A GB842930A GB842930A GB357527A GB 357527 A GB357527 A GB 357527A GB 842930 A GB842930 A GB 842930A GB 842930 A GB842930 A GB 842930A GB 357527 A GB357527 A GB 357527A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cellulose
- threads
- coagulating
- caustic soda
- plasticizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B13/00—Preparation of cellulose ether-esters
- C08B13/02—Cellulose ether xanthates
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
Abstract
Artificial threads, films, and other products are obtained from xanthates of alkyl or aralkyl cellulose derivatives, or of cellulose ethers of oxyalkyl monocarboxylic acids by bringing the product into the appropriate shape and acting thereon with a coagulating agent, or an agent which has both a coagulating and plasticizing effect, or first with an agent having a coagulating effect and then with an agent having a plasticizing effect. The xanthates may be mixed with cellulose xanthate. This may be effected by mixing solutions of the ingredients or dissolving one in a solution of the other, or by xanthating a mixture of the cellulose compound with unchanged alkali cellulose. Alkali soluble cellulose hydrate, cellulose compounds, proteins, gelatine, and softening agents such as glycerine, glycol, soap, glucose, Turkey red oil, drying oil, non-drying oil, and agents such as halogen derivatives of polyhydric alcohols may be added to the solutions of the xanthates. In an example, wood pulp or cotton linters are steeped in caustic soda solution and the mass is pressed, comminuted, and shredded. Di-methyl sulphate is added slowly with continuous kneading of the mass. When the first reaction has ceased a further quantity of caustic soda solution and then of dimethyl sulphate is added. The product is washed with water, and pressed. It is then treated with caustic soda, shredded, and treated with carbon bisulphide. The xanthated product is dissolved in caustic soda solution, filtered through cloth and cottonwool, aged, and spun into a coagulating or plasticizing bath. In other examples diethyl sulphate, or benzyl chloride is used instead of dimethyl sulphate. In the case of benzyl chloride, reaction with alkali cellulose is assisted by heating the mass. The crude benzyl cellulose is extracted several times with alcohol and then washed with water. It is then xanthated and converted into artificial threads. Purification of the benzyl cellulose may, however, be dispensed with. In other examples a cellulose ether of glycollic acid is dissolved in caustic soda solution and treated with carbon bisulphide. Homologues of ethyl or benzyl cellulose such as propyl- or amyl-cellulose may be employed. Cellulose ethers, lactic acid or oxybutyric acid may also be employed. When strong acid plasticizing baths are used, the threads on leaving the bath may be subjected to low temperatures before being washed, for example they may be collected on hollow spools containing solid carbon dioxide, or a freezing mixture. The threads may be desulphurized in the ordinary manner, or by treatment with hot and strong sodium sulphide solutions. In another example, cotton material is impregnated, filled or coated with a solution of the xanthated cellulose compound containing filling material such as talc, china clay or zinc white, or a pigment such as mica or lampblack. The material with or without drying, and if desired in a state of tension is passed through a coagulating or plasticizing bath, and then washed and dried. The process is applicable to the manufacture of artificial silk and other threads, films, coatings, layers; dressings for textiles, paper, and leather; adhesives and cements; plates and plastic compositions; thickening or fixing agents for pigments in textile printing. Specifications 177,810, 203,346, 203,347, 335,993, [all in Class 2 (ii), Cellulose &c.], 341,899, and 357,167 are referred to.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB842930A GB357527A (en) | 1930-03-15 | 1930-03-15 | Improvements in the manufacture of artificial threads or other products from cellulose compounds |
ES0122124A ES122124A2 (en) | 1930-03-15 | 1931-03-14 | IMPROVEMENTS MADE WITH THE PURPOSE OF THE PATENT |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB842930A GB357527A (en) | 1930-03-15 | 1930-03-15 | Improvements in the manufacture of artificial threads or other products from cellulose compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB357527A true GB357527A (en) | 1931-09-15 |
Family
ID=9852333
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB842930A Expired GB357527A (en) | 1930-03-15 | 1930-03-15 | Improvements in the manufacture of artificial threads or other products from cellulose compounds |
Country Status (2)
Country | Link |
---|---|
ES (1) | ES122124A2 (en) |
GB (1) | GB357527A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1904151B (en) * | 2006-05-08 | 2010-04-14 | 宜宾丝丽雅股份有限公司 | Composite cellulose viscose filament using composite cellulose pulp as raw material made from cotton, wood, hemp and bamboo and its preparation method |
-
1930
- 1930-03-15 GB GB842930A patent/GB357527A/en not_active Expired
-
1931
- 1931-03-14 ES ES0122124A patent/ES122124A2/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1904151B (en) * | 2006-05-08 | 2010-04-14 | 宜宾丝丽雅股份有限公司 | Composite cellulose viscose filament using composite cellulose pulp as raw material made from cotton, wood, hemp and bamboo and its preparation method |
Also Published As
Publication number | Publication date |
---|---|
ES122124A2 (en) | 1931-07-01 |
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