GB341408A - Colouration of textile and other materials - Google Patents

Colouration of textile and other materials

Info

Publication number
GB341408A
GB341408A GB3917930A GB3917930A GB341408A GB 341408 A GB341408 A GB 341408A GB 3917930 A GB3917930 A GB 3917930A GB 3917930 A GB3917930 A GB 3917930A GB 341408 A GB341408 A GB 341408A
Authority
GB
United Kingdom
Prior art keywords
anthraquinone
derivatives
dyes
compounds
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3917930A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Priority to GB3917930A priority Critical patent/GB341408A/en
Publication of GB341408A publication Critical patent/GB341408A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • D06P1/225General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo using acid vat method

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

Cellulose esters or ethers, dyeing; vat and sulphur dyes, dyeing with; printing; dye preparations.-Materials made of or containing cellulose esters or ethers are dyed, printed, or stencilled by the application of free leuco compounds of vat or sulphur dyestuffs including substituted or unsubstituted aminoanthraquinones. The following types of vat and sulphur dyes are specified:- 1. Indigo and allied colouring matters; (a) indigo and its derivatives, e.g. N.N1-dimethyl indigo and halogenated indigos, such as Ciba Blue 2B, (b) halogenated indirubines, e.g. Ciba Heliotrope B, (c) thioindigo and its derivatives, e.g. halogenated thioindigoid dyes, such as Ciba Bordeaux B, (d) dinaphthindigoid dyes, e.g. Ciba Green G, (e) indigoid dyes obtainable by condensing isatins or thioisatins with a -oxy-naphthalenes or a -oxy-anthracenes or derivatives thereof and if desired subsequently halogenating, e.g. Alizarin Indigo 3R and Helindone Blue 3GN. 2. Anthraquinone colouring matters; (a) simple amino derivatives, e.g. 1-hydroxy-4-amino-anthraquinone, 1 : 5-diamino -4 : 8 - dihydroxy-anthraquinone, 1 - methyl-amino-anthraquinone, 1 : 4-dianilido-anthraquinone, (b) anthraquinone-quinolines, e.g. 1 : 2-dihydroxy-anthraquinone-quinoline, (c) acylamino anthraquinones, e.g. 1-acetylamino-anthraquinone, 1 : 4-dipropionylaminoanthraquinone (obtainable by the action of propionic anhydride on 1 : 4-diaminoanthraquinone), 1 : 5-dibenzoylaminoanthraquinone, succinyl-a -amino anthraquinone, 1 : 5-dibenzoylamino-4 : 8-dihydroxy-anthraquinone, (d) anthrapyridones, e.g. 4-methylaminoanthrapyridone, (e) anthraquinone-mercaptans including their derivatives substituted in the nucleus and/or the mercapto groups, (f) benzanthrones and dibenzanthrones, e.g. violanthrone, iso-violanthrone, amino-violanthrone, dimethoxy-dibenzanthrone, (g) pyranthrone and its derivatives, (h) anthraflavone, (i) anthraquinone acridones, e.g. anthraquinone 1 (NH)-2 (CO)-naphthacridone, (j) dianthraquinonyls and acidylamino derivatives, (k) dianthraquinonylamines and derivatives, e.g. acidylamino derivatives, (l) anthraquinone azines and hydroazines, e.g. dianthraquinone-dihydroazines and their halogenated derivatives such as 1 : 2 : 11 : 21-dianthraquinone azine an its dichlor derivatives, (m) anthraquinone oxazines, (n) anthraquinone dioxides, (o) anthraquinone thiazines, (p) anthraquinone disulphides, (q) anthraquinone xanthones, (r) anthraquinone thioxanthones, (s) anthraquinone carbazoles, (t) anthraquinone thiazoles. 3. Derivatives of benzoquinone and naphthoquinones, e.g. those mentioned in Specifications 321,401, and 327,860, [both in Class 2 (iii), Dyes &c.]. 4. Indophenols and their derivatives, e.g. halogen derivatives. 5. Perylene quinones and their amino, halogen and other derivatives. 6. Dyestuffs obtainable by alkali fusion of imides and substituted imides of naphthalene peridicarboxylic acids and the dyestuffs obtainable by condensing naphthalene 1 : 4 : 5 : 8-tetracarboxylic acids with mono- or di-amines. 7. Sulphur dyestuffs commonly applicable from sulphide, hydrosulphite, or other vats, e.g. the dyes obtained by sulphurizing indophenols derived from carbazol. The free leuco compounds may be applied in solution, e.g. in organic solvents, but are preferably applied as aqueous dispersions or suspensions obtainable by mechanical treatment or by treatment with dispersing agents and/or protective colloids, or by liberating the leuco compounds in presence of dispersing agents and/or protective colloids. Specified dispersing agents are sulphoaromatic fatty acid compounds, e.g. sulphobenzene palmitic acid compounds (see Specification 242,393, [Class 2 (iii), Dyes &c.]), sulphoaromatic ricinoleic acid compounds, e.g. sulphonaphthalenericinoleic acid (see Specification 273,819, [Class 2 (iii), Dyes &c.]), naphthenic acids or other carbocyclic compounds containing salt-forming groups or salts of such acids or compounds (see Specification 224,925, [Class 2 (iii), Dyes &c.]), sulphonated oil compounds, e.g. sulphonated castor oil, furfural-naphthalene sulphonic acid compounds (see Specification 322,737, [Class 2 (iii), Dyes &c.]), resino-naphthalene sulphonic acid compounds (see Specification 323,788, [Class 2 (iii), Dyes &c.]), formaldehyde naphthalene sulphonic acid compounds, alkyl-, cycloalkyl-, and aralkylnaphthalene sulphonic acids, sulphite cellulose waste liquor or its constituents or products of transformation, e.g. lignin sulphonic acid compounds, sulphonic acid compounds of mineral oils, tar oils, brown coal tar oils, and the like, and their products of condensation with alcohols, and sulphonic acid compounds of distillation residues of benzaldehyde. Specified protective colloids are carbohydrates (including gums), glue, and gelatine. Aqueous dispersions or suspensions of the free leuco compounds may be acid, neutral or even slightly alkaline, e.g. they may have hydrogen ion concentrations corresponding to pH values between 3 and 9. The free leuco compounds may be applied in conjunction with swelling agents for the cellulose esters or ethers. Materials containing wool or silk in admixture with the cellulose esters or ethers may be dyed in solid or contrasting shades according to the relative affinities for the free leuco compounds, and, in view of the small affinity of cotton, linen, regenerated cellulose, and like cellulosic fibres for the free leuco compounds, cross dyed effects are obtainable on materials containing such fibres in admixture with the cellulose esters or ethers, in which case the cellulosic fibres may be dyed by other methods. The following examples are specified. (1) Hanks of cellulose acetate yarn are dyed by treatment at 75-80 DEG C. in a bath containing Ciba blue G powder dispersed with sodium sulphonaphthalene ricinoleate prepared according to Example A of Specification 242,393, caustic soda, hydrosulphite, and sufficient acetic acid to make the bath slightly acid to litmus, followed by rinsing, hydroextraction, and air oxidation. (2) Hanks of cellulose acetate yarn are dyed by a similar process using Caledon jade green, Caledon red BN, or 21 : 51-dichloro-1 : 2-anthraquinone thioxanthone dispersed with sulphonated castor oil. (3) A cellulose acetate woven fabric is dyed by a similar process using the indophenol obtained by oxidation of p-aminodimethylaniline and a -naphthol, dispersed with sulphite cellulose liquor. (4) A cellulose acetate-wool woven fabric is dyed by treatment at 75-80 DEG C. in a bath, made slightly acid with acetic acid, containing the leuco compound of 1-benzoylamino-4-oxyanthraquinone and gelatine, followed by rinsing and oxidation at 60 DEG C. in a bath containing sodium bichromate and sulphuric acid. (5) A cellulose p acetate-cotton woven fabric is dyed, the cotton first with Caledon jade green from a sodium phenate-hydrosulphite vat by the method of Specification 262,506, [Class 2 (iii), Dyes &c.], the cellulose acetate afterwards by treatment at 75 DEG C. in a bath containing the leuco compound of 1-amino-2-methylanthraquinone, dispersed with neutral or faintly acid turkey red oil, and hydrosulphite, followed by rinsing and oxidation at 60 DEG C. in a bath containing sodium perborate. (6) A cellulose acetate woven fabric dyed violet with the azo dyestuff 3 : 5-dinitro-2-aminoanisol --> a -naphthylamine is printed with an aqueous paste containing gum arabic, Ciba pink B, sodium sulphonaphthalene ricinoleate, caustic soda, and hydrosulphite made neutral or faintly acid with a mixture of formic acid and formosul; the fabric is then dried, steamed, and oxidized at 60 DEG C. in a bath containing sodium bichromate and sulphuric acid. The Provisional Specification also refers to the use of molasses as dispersing agent or protective colloid. 1 : 4-Dipropionylaminoanthraquinone is obtained by the action of propionic anhydride on 1 : 4-diaminoanthraquinone.
GB3917930A 1929-07-04 1929-07-04 Colouration of textile and other materials Expired GB341408A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3917930A GB341408A (en) 1929-07-04 1929-07-04 Colouration of textile and other materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3917930A GB341408A (en) 1929-07-04 1929-07-04 Colouration of textile and other materials

Publications (1)

Publication Number Publication Date
GB341408A true GB341408A (en) 1931-01-05

Family

ID=10408115

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3917930A Expired GB341408A (en) 1929-07-04 1929-07-04 Colouration of textile and other materials

Country Status (1)

Country Link
GB (1) GB341408A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003016614A2 (en) * 2001-08-21 2003-02-27 E. I. Du Pont De Nemours And Company Vat acid dyeing of textile fibers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003016614A2 (en) * 2001-08-21 2003-02-27 E. I. Du Pont De Nemours And Company Vat acid dyeing of textile fibers
WO2003016614A3 (en) * 2001-08-21 2003-12-24 Du Pont Vat acid dyeing of textile fibers

Similar Documents

Publication Publication Date Title
US1900172A (en) Treatment oe textile and other materials
US2428835A (en) Dyeing of fabrics comprising cellulose acetate with an alcohol-thiocyanate swelling mixture
US2107526A (en) Treatment of textile and other materials
US1688553A (en) Dyeing of materials made with or containing cellulose derivatives
GB341408A (en) Colouration of textile and other materials
GB361362A (en) Improvements in or relating to the colouration of materials
US2798788A (en) Vat dyeing of cellulose ethers and esters
GB355363A (en) Colouration of textile and other materials
Krug Thiourea dioxide (formamidinesulphinic acid) a new reducing agent for textile printing
US2681845A (en) Acid vat dyeing of animal fibers
US1716720A (en) Treatment of yarns and fabrics
US1816766A (en) Process of dyeing and printing cellulose esters
US3894838A (en) Process for dyeing unmodified polyolefin fibers with vat dyestuffs, leuco esters of vat dyestuffs or sulfur dyestuffs
USRE27470E (en) Iii iv
US2524073A (en) Dyeing cellulose esters and ethers with alkaline aqueous solutions of leuco vat dyes containing diacetone alcohol
US2476287A (en) Method for producing watersoluble leuco vat dyestuff
US2147635A (en) Dyestuff pastes and process for applying the same
US2074150A (en) Vat dye assistants and method of using
US3083068A (en) Process for dyeing and printing cellulose textile materials with soluble leuco ester vat dyestuffs
GB934391A (en) Dyeing, printing and/or fluorescent brightening of textile materials
US2020675A (en) Dyeing of textile materials
US2620257A (en) Vat dye pigment pad process for cellulose ester textiles using a water-miscible organic swelling agent in the alkaline hydrosulfite reducing bath
US2528614A (en) Vat dyeing process for cellulose acetate textile material
US1972137A (en) Treatment of textile materials
GB376797A (en) Improvements in the colouration or treatment of textile materials made of or containing cellulose esters or ethers